Preparation and nonlinear optical studies of a novel thermal stable polymer containing azo chromophores in the side chain

Xingbo Chen; Jingjing Zhang; Haibo Zhang; Zhenhua Jiang; Guang Shi; Yunbo Li; Yinglin Song

doi:10.1016/j.dyepig.2007.05.006

Preparation and nonlinear optical studies of a novel thermal stable polymer containing azo chromophores in the side chain

Xingbo Chen
, Jingjing Zhang
, Haibo Zhang
, Zhenhua Jiang^*
, Guang Shi
, Yunbo Li
, Yinglin Song

^*Corresponding author for this work

School of Physics

Jilin University
Harbin Institute of Technology

Research output: Contribution to journal › Article › peer-review

74 Scopus citations

Abstract

A novel bisfluoro NLO chromophore monomer, 4-[(4-cyanophenyl)diazenyl]phenyl-2,6-difluorobenzoate was synthesized via a two-step synthetic procedure. Azobenzene-functionalized poly(aryl ether) (azo-PAE) was prepared via a nucleophilic aromatic substitution polycondensation based on this monomer. The obtained polymer was characterized and evaluated by FT-IR, UV-vis, ¹H NMR, DSC and TGA. The third-order NLO coefficient was measured by Z-scan technique. The results showed the azo-PAE has high glass transition temperature, good thermal stability and large third-order nonlinear susceptibility.

Original language	English
Pages (from-to)	223-228
Number of pages	6
Journal	Dyes and Pigments
Volume	77
Issue number	1
DOIs	https://doi.org/10.1016/j.dyepig.2007.05.006
State	Published - 2008

Keywords

Azo polymer
Chromophore
Poly(aryl ether)
Third-order nonlinear optics
Z-scan

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10.1016/j.dyepig.2007.05.006

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title = "Preparation and nonlinear optical studies of a novel thermal stable polymer containing azo chromophores in the side chain",

abstract = "A novel bisfluoro NLO chromophore monomer, 4-[(4-cyanophenyl)diazenyl]phenyl-2,6-difluorobenzoate was synthesized via a two-step synthetic procedure. Azobenzene-functionalized poly(aryl ether) (azo-PAE) was prepared via a nucleophilic aromatic substitution polycondensation based on this monomer. The obtained polymer was characterized and evaluated by FT-IR, UV-vis, 1H NMR, DSC and TGA. The third-order NLO coefficient was measured by Z-scan technique. The results showed the azo-PAE has high glass transition temperature, good thermal stability and large third-order nonlinear susceptibility.",

keywords = "Azo polymer, Chromophore, Poly(aryl ether), Third-order nonlinear optics, Z-scan",

author = "Xingbo Chen and Jingjing Zhang and Haibo Zhang and Zhenhua Jiang and Guang Shi and Yunbo Li and Yinglin Song",

year = "2008",

doi = "10.1016/j.dyepig.2007.05.006",

language = "英语",

volume = "77",

pages = "223--228",

journal = "Dyes and Pigments",

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publisher = "Elsevier B.V.",

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}

TY - JOUR

T1 - Preparation and nonlinear optical studies of a novel thermal stable polymer containing azo chromophores in the side chain

AU - Chen, Xingbo

AU - Zhang, Jingjing

AU - Zhang, Haibo

AU - Jiang, Zhenhua

AU - Shi, Guang

AU - Li, Yunbo

AU - Song, Yinglin

PY - 2008

Y1 - 2008

N2 - A novel bisfluoro NLO chromophore monomer, 4-[(4-cyanophenyl)diazenyl]phenyl-2,6-difluorobenzoate was synthesized via a two-step synthetic procedure. Azobenzene-functionalized poly(aryl ether) (azo-PAE) was prepared via a nucleophilic aromatic substitution polycondensation based on this monomer. The obtained polymer was characterized and evaluated by FT-IR, UV-vis, 1H NMR, DSC and TGA. The third-order NLO coefficient was measured by Z-scan technique. The results showed the azo-PAE has high glass transition temperature, good thermal stability and large third-order nonlinear susceptibility.

AB - A novel bisfluoro NLO chromophore monomer, 4-[(4-cyanophenyl)diazenyl]phenyl-2,6-difluorobenzoate was synthesized via a two-step synthetic procedure. Azobenzene-functionalized poly(aryl ether) (azo-PAE) was prepared via a nucleophilic aromatic substitution polycondensation based on this monomer. The obtained polymer was characterized and evaluated by FT-IR, UV-vis, 1H NMR, DSC and TGA. The third-order NLO coefficient was measured by Z-scan technique. The results showed the azo-PAE has high glass transition temperature, good thermal stability and large third-order nonlinear susceptibility.

KW - Azo polymer

KW - Chromophore

KW - Poly(aryl ether)

KW - Third-order nonlinear optics

KW - Z-scan

UR - https://www.scopus.com/pages/publications/35148818445

U2 - 10.1016/j.dyepig.2007.05.006

DO - 10.1016/j.dyepig.2007.05.006

M3 - 文章

AN - SCOPUS:35148818445

SN - 0143-7208

VL - 77

SP - 223

EP - 228

JO - Dyes and Pigments

JF - Dyes and Pigments

IS - 1

ER -

Preparation and nonlinear optical studies of a novel thermal stable polymer containing azo chromophores in the side chain

Abstract

Keywords

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