Abstract
Microarc oxidation (MAO) was used to produce oxide ceramic coatings on Ti 2 AlNb alloy. The influences of NaOH and NaF additives in the electrolyte on microstructure and high-temperature oxidation resistance of MAO ceramic coatings were investigated. MAO ceramic coatings formed on Ti 2 AlNb alloy exhibit a volcanic-like porous structure, and consist of Al 2 TiO 5 , R-TiO 2 , γ-Al 2 O 3 and small amounts of α-Al 2 O 3 , Nb 2 O 5 . NaOH additive in the electrolyte enhances the densification of ceramic coatings and the relative content of Al 2 TiO 5 . NaF additive in the electrolyte not only increases the thickness of coatings, but also promotes the formation of Al 2 TiO 5 . In the case of static oxidation at 800°C for 100 h, MAO coatings improve high temperature oxidation resistance of Ti 2 AlNb alloy. The oxidized products after thermal exposure to 800°C for 100 h in air exhibit a multiple-layered oxide structure, and are main composed of R-TiO 2 , γ-Al 2 O 3 and Al 2 TiO 5 .
| Original language | English |
|---|---|
| Pages (from-to) | 8946-8952 |
| Number of pages | 7 |
| Journal | Applied Surface Science |
| Volume | 258 |
| Issue number | 22 |
| DOIs | |
| State | Published - 1 Sep 2012 |
| Externally published | Yes |
Keywords
- High temperature oxidation
- Microarc oxidation
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