Polymeric ionic liquid with carboxyl anchored on mesoporous silica for efficient fixation of carbon dioxide

The utilization of carbon dioxide (CO₂) has drawn much attention because of the increasing serious environmental problems. In order to promote the cycloaddition reaction of CO₂ to epoxides, a new synthesis strategy for friendly nonmetal catalyst to combine polymeric ionic liquid (PIL) with mesoporous silica (mSiO₂) was proposed. By thorough characterizations, those catalysts (mSiO₂-PIL-n, n = 1, 2, 3, 4) were verified that PIL with multiply catalytic active sites such as carboxyl group, imidazole ring and Br^–, was mainly anchored in mesoporous SiO₂ structures. Therefore, mSiO₂-PIL-n exhibited excellent catalytic activity for CO₂ cycloaddition reaction to epoxides under solventless and cocatalyst-free conditions. Typically, the appropriate PIL loading and specific surface area guaranteed mSiO₂-PIL-2 could efficiently catalyze the cycloaddition reaction with 96% yield and 99% selectivity to the target product of propylene carbonate under the conditions of 120 °C, 2 MPa and 6 h. Additionally, the mSiO₂-PIL-2 catalyst showed superior recyclability and there was no catalytic activity decrease for 10 runs of recycling due to the tightly anchored PIL on mesoporous SiO₂ by copolymerization. And the catalytic activity to other substituted epoxides over mSiO₂-PIL-2 was also expanded. Therefore, PIL anchored on mesoporous SiO₂ by copolymerization could be a promising synthetic strategy for the efficient catalyst to combine multiple active components in a single catalyst, meanwhile, mSiO₂-PIL-n exhibited an appealing catalyst candidate for the effective fixation and utilization of CO₂.