Abstract
A chameleon under pressure: The observed piezochromic behavior of the title compound (BP2VA) was found to depend on its molecular aggregation state and specifically on the strength of the π-π interaction between the anthracene rings of adjacent molecules. When BP2VA is ground or placed under pressure, its molecular aggregation state changes, and a red shift in the fluorescence emission from green via orange to red occurs (see picture).
| Original language | English |
|---|---|
| Pages (from-to) | 10782-10785 |
| Number of pages | 4 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 51 |
| Issue number | 43 |
| DOIs | |
| State | Published - 22 Oct 2012 |
| Externally published | Yes |
Keywords
- aggregation
- fluorescence
- piezochromic materials
- structure elucidation
- π interactions
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