Photoinduced intermolecular electron transfer and off-resonance Raman characteristics of Rhodamine 101/N,N-diethylaniline

Li Lin Jiang; Wei Long Liu; Yun Fei Song; Xing He; Yang Wang; Chang Wang; Hong Lin Wu; Fang Yang; Yan Qiang Yang

doi:10.1016/j.chemphys.2013.11.011

Photoinduced intermolecular electron transfer and off-resonance Raman characteristics of Rhodamine 101/N,N-diethylaniline

Li Lin Jiang
, Wei Long Liu
, Yun Fei Song
, Xing He
, Yang Wang
, Chang Wang
, Hong Lin Wu
, Fang Yang
, Yan Qiang Yang^*

^*Corresponding author for this work

School of Physics

Harbin Institute of Technology
Hezhou University
China Academy of Engineering Physics

Research output: Contribution to journal › Article › peer-review

17 Scopus citations

Abstract

The ultrafast photoinduced intermolecular electron transfer (PIET) reaction of Rhodamine 101 (Rh101⁺) in N,N-diethylaniline (DEA) was investigated using off-resonance Raman, femtosecond time-resolved multiplex transient grating (TG) and transient absorption (TA) spectroscopies. The Raman spectra indicate that the C=C stretching vibration of the chromophore aromatic ring is more sensitive to ET compared with the C-C stretching mode. The ultrafast photoinduced intermolecular forward ET (FET) from DEA to Rh101 ⁺* occurs on a time scale of τ_FET = 425-560 fs. The backward ET (BET) occurs in the inverted region with a time constant of τ_BET = 46.16-51.40 ps. The intramolecular vibrational relaxation (IVR) process occurs on the excited state potential energy surface with the time constant of τ_IVR = 2.77-5.39 ps.

Original language	English
Pages (from-to)	12-19
Number of pages	8
Journal	Chemical Physics
Volume	429
DOIs	https://doi.org/10.1016/j.chemphys.2013.11.011
State	Published - 31 Jan 2014

Keywords

Forward electron transfer
Intramolecular vibrational relaxation
Multiplex transient grating
Photoinduced intermolecular electron transfer
Rhodamine 101
Transient absorption

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10.1016/j.chemphys.2013.11.011

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@article{006dd0638f304b77b8663df52db589d0,

title = "Photoinduced intermolecular electron transfer and off-resonance Raman characteristics of Rhodamine 101/N,N-diethylaniline",

abstract = "The ultrafast photoinduced intermolecular electron transfer (PIET) reaction of Rhodamine 101 (Rh101+) in N,N-diethylaniline (DEA) was investigated using off-resonance Raman, femtosecond time-resolved multiplex transient grating (TG) and transient absorption (TA) spectroscopies. The Raman spectra indicate that the C=C stretching vibration of the chromophore aromatic ring is more sensitive to ET compared with the C-C stretching mode. The ultrafast photoinduced intermolecular forward ET (FET) from DEA to Rh101 +* occurs on a time scale of τFET = 425-560 fs. The backward ET (BET) occurs in the inverted region with a time constant of τBET = 46.16-51.40 ps. The intramolecular vibrational relaxation (IVR) process occurs on the excited state potential energy surface with the time constant of τIVR = 2.77-5.39 ps.",

keywords = "Forward electron transfer, Intramolecular vibrational relaxation, Multiplex transient grating, Photoinduced intermolecular electron transfer, Rhodamine 101, Transient absorption",

author = "Jiang, \{Li Lin\} and Liu, \{Wei Long\} and Song, \{Yun Fei\} and Xing He and Yang Wang and Chang Wang and Wu, \{Hong Lin\} and Fang Yang and Yang, \{Yan Qiang\}",

year = "2014",

month = jan,

day = "31",

doi = "10.1016/j.chemphys.2013.11.011",

language = "英语",

volume = "429",

pages = "12--19",

journal = "Chemical Physics",

issn = "0301-0104",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Photoinduced intermolecular electron transfer and off-resonance Raman characteristics of Rhodamine 101/N,N-diethylaniline

AU - Jiang, Li Lin

AU - Liu, Wei Long

AU - Song, Yun Fei

AU - He, Xing

AU - Wang, Yang

AU - Wang, Chang

AU - Wu, Hong Lin

AU - Yang, Fang

AU - Yang, Yan Qiang

PY - 2014/1/31

Y1 - 2014/1/31

N2 - The ultrafast photoinduced intermolecular electron transfer (PIET) reaction of Rhodamine 101 (Rh101+) in N,N-diethylaniline (DEA) was investigated using off-resonance Raman, femtosecond time-resolved multiplex transient grating (TG) and transient absorption (TA) spectroscopies. The Raman spectra indicate that the C=C stretching vibration of the chromophore aromatic ring is more sensitive to ET compared with the C-C stretching mode. The ultrafast photoinduced intermolecular forward ET (FET) from DEA to Rh101 +* occurs on a time scale of τFET = 425-560 fs. The backward ET (BET) occurs in the inverted region with a time constant of τBET = 46.16-51.40 ps. The intramolecular vibrational relaxation (IVR) process occurs on the excited state potential energy surface with the time constant of τIVR = 2.77-5.39 ps.

AB - The ultrafast photoinduced intermolecular electron transfer (PIET) reaction of Rhodamine 101 (Rh101+) in N,N-diethylaniline (DEA) was investigated using off-resonance Raman, femtosecond time-resolved multiplex transient grating (TG) and transient absorption (TA) spectroscopies. The Raman spectra indicate that the C=C stretching vibration of the chromophore aromatic ring is more sensitive to ET compared with the C-C stretching mode. The ultrafast photoinduced intermolecular forward ET (FET) from DEA to Rh101 +* occurs on a time scale of τFET = 425-560 fs. The backward ET (BET) occurs in the inverted region with a time constant of τBET = 46.16-51.40 ps. The intramolecular vibrational relaxation (IVR) process occurs on the excited state potential energy surface with the time constant of τIVR = 2.77-5.39 ps.

KW - Forward electron transfer

KW - Intramolecular vibrational relaxation

KW - Multiplex transient grating

KW - Photoinduced intermolecular electron transfer

KW - Rhodamine 101

KW - Transient absorption

UR - https://www.scopus.com/pages/publications/84896508135

U2 - 10.1016/j.chemphys.2013.11.011

DO - 10.1016/j.chemphys.2013.11.011

M3 - 文章

AN - SCOPUS:84896508135

SN - 0301-0104

VL - 429

SP - 12

EP - 19

JO - Chemical Physics

JF - Chemical Physics

ER -

Photoinduced intermolecular electron transfer and off-resonance Raman characteristics of Rhodamine 101/N,N-diethylaniline

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Keywords

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