Photocatalytic degradation of organophosphorus flame retardants in aqueous solutions: a review and future prospects

The widespread use of organophosphorus flame retardants (OPFRs) in industrial and household products increases the risk of their environmental exposure, posing a serious threat to ecosystems and human health. Photocatalytic technology has been widely used in wastewater treatment due to its high efficiency, mild reaction conditions, and robustness. This review summarizes the current status of research on photocatalytic degradation of OPFRs, focusing on the effect of different types of catalysts on the degradation efficiency, the effects of pH, and co-existing inorganic and organic ions. And pH and co-existing inorganic mainly affect the active oxygen and the active surface sites of the catalyst. In addition, toxicological calculations of the intermediates of the degradation pathway using T.E.S.T. and ECOSAR showed that photocatalysis could effectively reduce the toxicity of OPFRs. Development of new photocatalytic materials, in-depth study of the degradation mechanism of different catalysts and flame retardants, and attention to practical applications and toxicity issues can be the development direction of future research.