Photocatalytic activation of hydrogen peroxide via a novel CuFe2(PO4)2(OH)2 up-conversion material without rare-earth ions for doxycycline hydrochloride degradation

Yanan Dong; Jing Jiao; Zhihai Liu; Xu He; Panpan Wang; Qinghua Yan; Guocheng Liu; Chengzhi Zhou; Shuaishuai Xin; Yanjun Xin

doi:10.1016/j.cej.2024.156233

Photocatalytic activation of hydrogen peroxide via a novel CuFe₂(PO₄)₂(OH)₂ up-conversion material without rare-earth ions for doxycycline hydrochloride degradation

Yanan Dong
, Jing Jiao
, Zhihai Liu
, Xu He
, Panpan Wang
, Qinghua Yan
, Guocheng Liu
, Chengzhi Zhou
, Shuaishuai Xin^*
, Yanjun Xin

^*Corresponding author for this work

Qingdao Agricultural University
School of Environment, Harbin Institute of Technology
National Center of Technology Innovation for Comprehensive Utilization of Saline-Alkali Land

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

A novel CuFe₂(PO₄)₂(OH)₂ up-conversion material without rare-earth ions was fabricated for hydrogen peroxide (H₂O₂) activation to degrade doxycycline hydrochloride (DOH) under simulate sunlight irradiation. The CuFe₂(PO₄)₂(OH)₂ exhibited superior absorption performance in near-infrared (NIR) region and up-conversion property. The CuFe₂(PO₄)₂(OH)₂ can effectively activate H₂O₂ for DOH degradation under ultraviolet, visible and NIR irradiation. Although H₂O₂ was more easily adsorbed on monometallic Fe₃(PO₄)₂(OH)₂ surface according to the result of density functional theory calculations, the CuFe₂(PO₄)₂(OH)₂ showed more superior property for H₂O₂ activation than Fe₃(PO₄)₂(OH)₂ due to its higher photoconversion efficiency. Moreover, the redox cycles of Fe³⁺/Fe²⁺ and Cu²⁺/Cu⁺ on CuFe₂(PO₄)₂(OH)₂ surface further promoted H₂O₂ activation to degrade DOH with ^•OH was the main active species. The degradation process and evolution law of intermediates were determined by HPLC/MS/MS and DFT calculations. The Toxicity Estimation Software Tool based on quantitative structure–activity relationship prediction and antibacterial experiment showed that the overall toxicity and antibacterial activity gradually decreased with reaction. The CuFe₂(PO₄)₂(OH)₂ existed fine anti-interference property and universality for the removal of other antibiotic pollution.

Original language	English
Article number	156233
Journal	Chemical Engineering Journal
Volume	499
DOIs	https://doi.org/10.1016/j.cej.2024.156233
State	Published - 1 Nov 2024
Externally published	Yes

Keywords

CuFe(PO)(OH)
Doxycycline hydrochloride
HO activation
Near-infrared light

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10.1016/j.cej.2024.156233

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@article{d075d68d5de549aba52b27eb4524b8d8,

title = "Photocatalytic activation of hydrogen peroxide via a novel CuFe2(PO4)2(OH)2 up-conversion material without rare-earth ions for doxycycline hydrochloride degradation",

abstract = "A novel CuFe2(PO4)2(OH)2 up-conversion material without rare-earth ions was fabricated for hydrogen peroxide (H2O2) activation to degrade doxycycline hydrochloride (DOH) under simulate sunlight irradiation. The CuFe2(PO4)2(OH)2 exhibited superior absorption performance in near-infrared (NIR) region and up-conversion property. The CuFe2(PO4)2(OH)2 can effectively activate H2O2 for DOH degradation under ultraviolet, visible and NIR irradiation. Although H2O2 was more easily adsorbed on monometallic Fe3(PO4)2(OH)2 surface according to the result of density functional theory calculations, the CuFe2(PO4)2(OH)2 showed more superior property for H2O2 activation than Fe3(PO4)2(OH)2 due to its higher photoconversion efficiency. Moreover, the redox cycles of Fe3+/Fe2+ and Cu2+/Cu+ on CuFe2(PO4)2(OH)2 surface further promoted H2O2 activation to degrade DOH with •OH was the main active species. The degradation process and evolution law of intermediates were determined by HPLC/MS/MS and DFT calculations. The Toxicity Estimation Software Tool based on quantitative structure–activity relationship prediction and antibacterial experiment showed that the overall toxicity and antibacterial activity gradually decreased with reaction. The CuFe2(PO4)2(OH)2 existed fine anti-interference property and universality for the removal of other antibiotic pollution.",

keywords = "CuFe(PO)(OH), Doxycycline hydrochloride, HO activation, Near-infrared light",

author = "Yanan Dong and Jing Jiao and Zhihai Liu and Xu He and Panpan Wang and Qinghua Yan and Guocheng Liu and Chengzhi Zhou and Shuaishuai Xin and Yanjun Xin",

note = "Publisher Copyright: {\textcopyright} 2024",

year = "2024",

month = nov,

day = "1",

doi = "10.1016/j.cej.2024.156233",

language = "英语",

volume = "499",

journal = "Chemical Engineering Journal",

issn = "1385-8947",

publisher = "Elsevier B.V.",

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TY - JOUR

T1 - Photocatalytic activation of hydrogen peroxide via a novel CuFe2(PO4)2(OH)2 up-conversion material without rare-earth ions for doxycycline hydrochloride degradation

AU - Dong, Yanan

AU - Jiao, Jing

AU - Liu, Zhihai

AU - He, Xu

AU - Wang, Panpan

AU - Yan, Qinghua

AU - Liu, Guocheng

AU - Zhou, Chengzhi

AU - Xin, Shuaishuai

AU - Xin, Yanjun

PY - 2024/11/1

Y1 - 2024/11/1

N2 - A novel CuFe2(PO4)2(OH)2 up-conversion material without rare-earth ions was fabricated for hydrogen peroxide (H2O2) activation to degrade doxycycline hydrochloride (DOH) under simulate sunlight irradiation. The CuFe2(PO4)2(OH)2 exhibited superior absorption performance in near-infrared (NIR) region and up-conversion property. The CuFe2(PO4)2(OH)2 can effectively activate H2O2 for DOH degradation under ultraviolet, visible and NIR irradiation. Although H2O2 was more easily adsorbed on monometallic Fe3(PO4)2(OH)2 surface according to the result of density functional theory calculations, the CuFe2(PO4)2(OH)2 showed more superior property for H2O2 activation than Fe3(PO4)2(OH)2 due to its higher photoconversion efficiency. Moreover, the redox cycles of Fe3+/Fe2+ and Cu2+/Cu+ on CuFe2(PO4)2(OH)2 surface further promoted H2O2 activation to degrade DOH with •OH was the main active species. The degradation process and evolution law of intermediates were determined by HPLC/MS/MS and DFT calculations. The Toxicity Estimation Software Tool based on quantitative structure–activity relationship prediction and antibacterial experiment showed that the overall toxicity and antibacterial activity gradually decreased with reaction. The CuFe2(PO4)2(OH)2 existed fine anti-interference property and universality for the removal of other antibiotic pollution.

AB - A novel CuFe2(PO4)2(OH)2 up-conversion material without rare-earth ions was fabricated for hydrogen peroxide (H2O2) activation to degrade doxycycline hydrochloride (DOH) under simulate sunlight irradiation. The CuFe2(PO4)2(OH)2 exhibited superior absorption performance in near-infrared (NIR) region and up-conversion property. The CuFe2(PO4)2(OH)2 can effectively activate H2O2 for DOH degradation under ultraviolet, visible and NIR irradiation. Although H2O2 was more easily adsorbed on monometallic Fe3(PO4)2(OH)2 surface according to the result of density functional theory calculations, the CuFe2(PO4)2(OH)2 showed more superior property for H2O2 activation than Fe3(PO4)2(OH)2 due to its higher photoconversion efficiency. Moreover, the redox cycles of Fe3+/Fe2+ and Cu2+/Cu+ on CuFe2(PO4)2(OH)2 surface further promoted H2O2 activation to degrade DOH with •OH was the main active species. The degradation process and evolution law of intermediates were determined by HPLC/MS/MS and DFT calculations. The Toxicity Estimation Software Tool based on quantitative structure–activity relationship prediction and antibacterial experiment showed that the overall toxicity and antibacterial activity gradually decreased with reaction. The CuFe2(PO4)2(OH)2 existed fine anti-interference property and universality for the removal of other antibiotic pollution.

KW - CuFe(PO)(OH)

KW - Doxycycline hydrochloride

KW - HO activation

KW - Near-infrared light

UR - https://www.scopus.com/pages/publications/85205285875

U2 - 10.1016/j.cej.2024.156233

DO - 10.1016/j.cej.2024.156233

M3 - 文章

AN - SCOPUS:85205285875

SN - 1385-8947

VL - 499

JO - Chemical Engineering Journal

JF - Chemical Engineering Journal

M1 - 156233

ER -

Photocatalytic activation of hydrogen peroxide via a novel CuFe₂(PO₄)₂(OH)₂ up-conversion material without rare-earth ions for doxycycline hydrochloride degradation

Abstract

Keywords

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