Photo-induced intramolecular electron transfer and intramolecular vibrational relaxation of rhodamine 6G in DMSO revealed by multiplex transient grating spectroscopy

Li Lin Jiang; Wei Long Liu; Yun Fei Song; Shan Lin Sun

doi:10.1088/1674-1056/23/10/107802

Photo-induced intramolecular electron transfer and intramolecular vibrational relaxation of rhodamine 6G in DMSO revealed by multiplex transient grating spectroscopy

Li Lin Jiang^*
, Wei Long Liu
, Yun Fei Song
, Shan Lin Sun

^*Corresponding author for this work

School of Physics

Hezhou University
Harbin Institute of Technology
Guilin University of Aerospace Technology

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

Photo-induced intramolecular electron transfer (PIET) and intramolecular vibrational relaxation (IVR) dynamics of the excited state of rhodamine 6G (Rh6G⁺) in DMSO are investigated by multiplex transient grating. Two major components are resolved in the dynamics of Rh6G⁺. The first component, with a lifetime τPIET = 140 fs-260 fs, is attributed to PIET from the phenyl ring to the xanthene plane. The IVR process occurring in the range τIVR = 3.3 ps-5.2 ps is much slower than the first component. The PIET and IVR processes occurring in the excited state of Rh6G⁺ are quantitatively determined, and a better understanding of the relationship between these processes is obtained.

Original language	English
Article number	107802
Journal	Chinese Physics B
Volume	23
Issue number	10
DOIs	https://doi.org/10.1088/1674-1056/23/10/107802
State	Published - 1 Oct 2014

Keywords

Excited state
Intramolecular vibrational relaxation
Multiplex transient grating
Photo-induced intramolecular electron transfer

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10.1088/1674-1056/23/10/107802

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title = "Photo-induced intramolecular electron transfer and intramolecular vibrational relaxation of rhodamine 6G in DMSO revealed by multiplex transient grating spectroscopy",

abstract = "Photo-induced intramolecular electron transfer (PIET) and intramolecular vibrational relaxation (IVR) dynamics of the excited state of rhodamine 6G (Rh6G+) in DMSO are investigated by multiplex transient grating. Two major components are resolved in the dynamics of Rh6G+. The first component, with a lifetime τPIET = 140 fs-260 fs, is attributed to PIET from the phenyl ring to the xanthene plane. The IVR process occurring in the range τIVR = 3.3 ps-5.2 ps is much slower than the first component. The PIET and IVR processes occurring in the excited state of Rh6G+ are quantitatively determined, and a better understanding of the relationship between these processes is obtained.",

keywords = "Excited state, Intramolecular vibrational relaxation, Multiplex transient grating, Photo-induced intramolecular electron transfer",

author = "Jiang, \{Li Lin\} and Liu, \{Wei Long\} and Song, \{Yun Fei\} and Sun, \{Shan Lin\}",

note = "Publisher Copyright: {\textcopyright} 2014 Chinese Physical Society and IOP Publishing Ltd.",

year = "2014",

month = oct,

day = "1",

doi = "10.1088/1674-1056/23/10/107802",

language = "英语",

volume = "23",

journal = "Chinese Physics B",

issn = "1674-1056",

publisher = "Institute of Physics",

number = "10",

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TY - JOUR

T1 - Photo-induced intramolecular electron transfer and intramolecular vibrational relaxation of rhodamine 6G in DMSO revealed by multiplex transient grating spectroscopy

AU - Jiang, Li Lin

AU - Liu, Wei Long

AU - Song, Yun Fei

AU - Sun, Shan Lin

PY - 2014/10/1

Y1 - 2014/10/1

N2 - Photo-induced intramolecular electron transfer (PIET) and intramolecular vibrational relaxation (IVR) dynamics of the excited state of rhodamine 6G (Rh6G+) in DMSO are investigated by multiplex transient grating. Two major components are resolved in the dynamics of Rh6G+. The first component, with a lifetime τPIET = 140 fs-260 fs, is attributed to PIET from the phenyl ring to the xanthene plane. The IVR process occurring in the range τIVR = 3.3 ps-5.2 ps is much slower than the first component. The PIET and IVR processes occurring in the excited state of Rh6G+ are quantitatively determined, and a better understanding of the relationship between these processes is obtained.

AB - Photo-induced intramolecular electron transfer (PIET) and intramolecular vibrational relaxation (IVR) dynamics of the excited state of rhodamine 6G (Rh6G+) in DMSO are investigated by multiplex transient grating. Two major components are resolved in the dynamics of Rh6G+. The first component, with a lifetime τPIET = 140 fs-260 fs, is attributed to PIET from the phenyl ring to the xanthene plane. The IVR process occurring in the range τIVR = 3.3 ps-5.2 ps is much slower than the first component. The PIET and IVR processes occurring in the excited state of Rh6G+ are quantitatively determined, and a better understanding of the relationship between these processes is obtained.

KW - Excited state

KW - Intramolecular vibrational relaxation

KW - Multiplex transient grating

KW - Photo-induced intramolecular electron transfer

UR - https://www.scopus.com/pages/publications/84907638262

U2 - 10.1088/1674-1056/23/10/107802

DO - 10.1088/1674-1056/23/10/107802

M3 - 文章

AN - SCOPUS:84907638262

SN - 1674-1056

VL - 23

JO - Chinese Physics B

JF - Chinese Physics B

IS - 10

M1 - 107802

ER -

Photo-induced intramolecular electron transfer and intramolecular vibrational relaxation of rhodamine 6G in DMSO revealed by multiplex transient grating spectroscopy

Abstract

Keywords

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