Phase transition in mayenite Ca12Al14O33

A. S. Tolkacheva; S. N. Shkerin; I. V. Korzun; S. V. Plaksin; V. R. Khrustov; D. P. Ordinartsev

doi:10.1134/S0036023612070182

Phase transition in mayenite Ca₁₂Al₁₄O₃₃

A. S. Tolkacheva^*
, S. N. Shkerin
, I. V. Korzun
, S. V. Plaksin
, V. R. Khrustov
, D. P. Ordinartsev

^*Corresponding author for this work

Institute of High Temperature Electrochemistry UB RAS
Institute of Electrophysics of the Ural Division of the Russian Academy of Sciences

Research output: Contribution to journal › Article › peer-review

19 Scopus citations

Abstract

A phase transition in Ca₁₂Al₁₄O₃₃ has been discovered and investigated by thermogravimetric analysis, differential scanning calorimetry, dilatometry, and high-temperature X-ray diffraction. The phase transition occurs at 922 ± 45 K (δH =-406 ± 13 kJ/mol, δS =-440 ± 14 J/(mol K)) and is presumably a first-order one. It does not change the symmetry of the cationic subsystem. The phase transition is difficult to reveal because the material changes its mass, probably by releasing water bound in several different ways.

Original language	English
Pages (from-to)	1014-1018
Number of pages	5
Journal	Russian Journal of Inorganic Chemistry
Volume	57
Issue number	7
DOIs	https://doi.org/10.1134/S0036023612070182
State	Published - Jul 2012
Externally published	Yes

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title = "Phase transition in mayenite Ca12Al14O33 ",

abstract = "A phase transition in Ca12Al14O33 has been discovered and investigated by thermogravimetric analysis, differential scanning calorimetry, dilatometry, and high-temperature X-ray diffraction. The phase transition occurs at 922 ± 45 K (δH =-406 ± 13 kJ/mol, δS =-440 ± 14 J/(mol K)) and is presumably a first-order one. It does not change the symmetry of the cationic subsystem. The phase transition is difficult to reveal because the material changes its mass, probably by releasing water bound in several different ways.",

author = "Tolkacheva, \{A. S.\} and Shkerin, \{S. N.\} and Korzun, \{I. V.\} and Plaksin, \{S. V.\} and Khrustov, \{V. R.\} and Ordinartsev, \{D. P.\}",

year = "2012",

month = jul,

doi = "10.1134/S0036023612070182",

language = "英语",

volume = "57",

pages = "1014--1018",

journal = "Russian Journal of Inorganic Chemistry",

issn = "0036-0236",

publisher = "Pleiades Publishing",

number = "7",

}

TY - JOUR

T1 - Phase transition in mayenite Ca12Al14O33

AU - Tolkacheva, A. S.

AU - Shkerin, S. N.

AU - Korzun, I. V.

AU - Plaksin, S. V.

AU - Khrustov, V. R.

AU - Ordinartsev, D. P.

PY - 2012/7

Y1 - 2012/7

N2 - A phase transition in Ca12Al14O33 has been discovered and investigated by thermogravimetric analysis, differential scanning calorimetry, dilatometry, and high-temperature X-ray diffraction. The phase transition occurs at 922 ± 45 K (δH =-406 ± 13 kJ/mol, δS =-440 ± 14 J/(mol K)) and is presumably a first-order one. It does not change the symmetry of the cationic subsystem. The phase transition is difficult to reveal because the material changes its mass, probably by releasing water bound in several different ways.

AB - A phase transition in Ca12Al14O33 has been discovered and investigated by thermogravimetric analysis, differential scanning calorimetry, dilatometry, and high-temperature X-ray diffraction. The phase transition occurs at 922 ± 45 K (δH =-406 ± 13 kJ/mol, δS =-440 ± 14 J/(mol K)) and is presumably a first-order one. It does not change the symmetry of the cationic subsystem. The phase transition is difficult to reveal because the material changes its mass, probably by releasing water bound in several different ways.

UR - https://www.scopus.com/pages/publications/84865337041

U2 - 10.1134/S0036023612070182

DO - 10.1134/S0036023612070182

M3 - 文章

AN - SCOPUS:84865337041

SN - 0036-0236

VL - 57

SP - 1014

EP - 1018

JO - Russian Journal of Inorganic Chemistry

JF - Russian Journal of Inorganic Chemistry

IS - 7

ER -

Phase transition in mayenite Ca₁₂Al₁₄O₃₃

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