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Phase transformation rate in hydrogen absorption of magnesium-based materials

  • Wen Cong Zhang*
  • , Wen Bin Fang
  • , Zhen Xing Yu
  • , Guo Liang Zhao
  • , Er De Wang
  • , Zhi Jie Sun
  • *Corresponding author for this work
  • Harbin Institute of Technology
  • Tsinghua University

Research output: Contribution to journalArticlepeer-review

Abstract

The hydrogen storage material Mg-Ni-MnO2 was prepared by mechanical alloying under the hydrogen atmosphere and its phase transformation rate in hydrogen absorption was studied using the self-designed measurement apparatus. The experimental results show that the phase transformation rate has a maximum value in the hydrogen absorption; and the milling time has great effect on the time of maximum value appearance and maximum value of phase transformation rate. At the early stage, the rate is controlled by particle surface effect, and at the smooth stage, the mechanism of phase transformation is influenced by the particle size.

Original languageEnglish
Pages (from-to)54-58
Number of pages5
JournalTransactions of Nonferrous Metals Society of China (English Edition)
Volume13
Issue numberSPEC. ISS.
StatePublished - May 2003

Keywords

  • Hydrogen storage material
  • Mechanical alloying
  • Phase transformation rate

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