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Perovskite SrVO3 as novel cathode materials for high-rate aqueous zinc-ion batteries

  • Ping Lei
  • , Jiehui Liu
  • , Shuyuan Zhuge
  • , Zhe Lü*
  • *Corresponding author for this work
  • School of Physics, Harbin Institute of Technology

Research output: Contribution to journalArticlepeer-review

Abstract

Aqueous Zinc ion batteries (AZIBs) is well considered as a potential candidate with green, safety and low cost for large-scale grid storage. Perovskite oxide SrVO3 can be used as the cathode material for AZIBs due to its high electrically conductive. Therefore, the SrVO3 as a novel cathode material by sol–gel route was prepared to investigate the electrochemical performance. The SrVO3 exhibits outstanding rate capability with high reversible capacities of 142.7 mA h g−1 at 200 mA g−1, 134.9 mA h g−1 at 300 mA g−1, and 105.3 mA h g−1 at 2000 mA g−1 are ascribed to the fast diffusion reaction kinetics. Moreover, the cycling performance of SrVO3 was delivered with capacity retention of 79 % after 3000 cycles at a current density of 2000 mA g−1 in the 0.4–1.8 V voltage window. This work provides a new prospect for the development of perovskite-type cathode materials for AZIBs.

Original languageEnglish
Article number133575
JournalMaterials Letters
Volume333
DOIs
StatePublished - 15 Feb 2023
Externally publishedYes

Keywords

  • Aqueous zinc-ion batteries
  • Cathode material
  • Diffusion
  • Perovskite-type
  • Sol–gel preparation
  • SrVO

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