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Performance of Pt/C catalysts prepared by microwave-assisted polyol process for methanol electrooxidation

  • Yuan Yuan Chu
  • , Zhen Bo Wang*
  • , Da Ming Gu
  • , Ge Ping Yin
  • *Corresponding author for this work
  • School of Chemistry and Chemical Engineering, Harbin Institute of Technology

Research output: Contribution to journalArticlepeer-review

Abstract

Pt nanoparticles catalysts supported on the Vulcan XC-72 carbon black with different mean sizes have been synthesized by microwave-assisted polyol process and characterized by energy dispersive analysis of X-ray (EDAX), X-ray diffraction (XRD), and transmission electron microscopy (TEM). The results of physical examinations show that Pt nanoparticles have a narrow size distribution and are highly dispersed on the surface of carbon support, and Pt loading in Pt/C catalyst is the similar with the theoretical value. The results of cyclic voltammetry and chronoamperometry demonstrate that the Pt/C catalyst prepared by microwave-assisted polyol process at the pH value of about 12 exhibits the highest catalytic activity for methanol electrooxidation. The activity of Pt/C catalyst is also related to the microwave heating time, and the optimal heating time is 40 s in this work.

Original languageEnglish
Pages (from-to)1799-1804
Number of pages6
JournalJournal of Power Sources
Volume195
Issue number7
DOIs
StatePublished - 2 Apr 2010
Externally publishedYes

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

  1. SDG 7 - Affordable and Clean Energy
    SDG 7 Affordable and Clean Energy

Keywords

  • Anode catalyst
  • Direct methanol fuel cell
  • Methanol electrooxidation
  • Microwave-assisted polyol process
  • Pt/C catalyst

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