A Ti/SnO2-Sb2O5 electrode has been prepared by a method of cathode electrodeposition. Sn and Sb (Sn:Sb=94:6) choride was electrodeposited on Ti substrate respectively several times and followed by thermal treatment at 450°C. The surface morphologies and crystal structure of the electrodes are examined by scanning electron microscopy and glancing angle X-ray diffraction. It can be clearly observed that granular aggregates together in the electrode surface. The electrode with the high specific surface area can be seen to be sphere shaped of various sizes amplified 10,000 times on SEM image. Electrocatalytic property studies using cyclic voltammetry (CV) and comparison of the ability in oxiding phenol with the electrode prepared by dip-coating show that the electrode is superior to the latter. The charge load needed was degraded from 3.4Ah/L to 2.2Ah/L.