Performance and Microstructural Characteristics of Ultra-Early High-Strength Cement-Based Grouting Materials Modified with Accelerating and Retarding Agents

To balance ultra-early strength development and workable time in cement-based grouting materials for rapid repair applications, an ultra-early high-strength grout system was developed by regulating the dosage of an accelerating agent (CF), retarder content, and water-to-binder ratio (w/b). The effects of these parameters on setting behavior, workability, mechanical properties, volumetric stability, and durability were systematically investigated. X-ray diffraction (XRD) and scanning electron microscopy coupled with energy-dispersive spectroscopy (SEM/EDS) were further conducted to qualitatively evaluate the hydration characteristics and microstructural evolution of the optimized system. The results showed that CF accelerated early hydration and promoted the rapid formation of ettringite (AFt), which contributed to the development of ultra-early strength. The incorporation of a retarder effectively prolonged the workable time and improved slurry workability. Increasing the w/b ratio enhanced flowability and toughness, although excessive w/b reduced compressive strength. The optimal mixture contained 30% CF, 0.02% retarder, and a w/b ratio of 0.19. Under this condition, the grout exhibited a flowability of 312 mm and compressive strengths of 81.4 MPa at 1 h and 121.3 MPa at 28 d. In addition, low air shrinkage (0.027% at 28 d) and excellent chloride penetration resistance (12 C at 28 d) were achieved. Microstructural observations suggested that the dense structure formed by AFt and C–S–H gel contributed to the improved macroscopic performance. This study provides an engineering-oriented reference for the mix design and performance optimization of ultra-early high-strength cement-based grouting materials for rapid repair applications.