Pb Segregation in SnPb eutectic solder alloy induced by gamma irradiation

Qilong Guan; Chunjin Hang; Wei Zhang; Shengli Li; Xiaojiu Tang; Dan Yu; Ying Ding; Xiuli Wang; Guangdong Wu; Gang Yao

doi:10.1016/j.corsci.2024.112249

Pb Segregation in SnPb eutectic solder alloy induced by gamma irradiation

Qilong Guan
, Chunjin Hang^*
, Wei Zhang
, Shengli Li
, Xiaojiu Tang
, Dan Yu
, Ying Ding
, Xiuli Wang
, Guangdong Wu
, Gang Yao^*

^*Corresponding author for this work

School of Materials Science and Engineering

Harbin Institute of Technology
CAS - Beijing Institute of Control Engineering
Heilongjiang Institute of Atomic Energy
Harbin Engineering University

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

Pb segregated and formed a Pb segregation area in SnPb eutectic solder joint after 100 h of gamma irradiation. With the irradiation time increased to 150 h, Pb segregating stopped. The Pb segregation was attributed to the oxidation of β-Sn to SnO₂ induced by the gamma irradiation. The Pb element content in the segregation area predicted by the segregation heat formulas is 53.5 %, which is consistent with the experimental result of 49.11 %. Density functional theory (DFT) calculation and Molecular dynamics (MD) simulation results were used to prove that the Pb segregation is caused by the oxidation of β-Sn.

Original language	English
Article number	112249
Journal	Corrosion Science
Volume	236
DOIs	https://doi.org/10.1016/j.corsci.2024.112249
State	Published - 1 Aug 2024

Keywords

DFT calculation
Gamma irradiation
MD simulation
Pb segregation
SnPb eutectic solder joint

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10.1016/j.corsci.2024.112249

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@article{f7443613ad1e491c9743e2e703980c10,

title = "Pb Segregation in SnPb eutectic solder alloy induced by gamma irradiation",

abstract = "Pb segregated and formed a Pb segregation area in SnPb eutectic solder joint after 100 h of gamma irradiation. With the irradiation time increased to 150 h, Pb segregating stopped. The Pb segregation was attributed to the oxidation of β-Sn to SnO2 induced by the gamma irradiation. The Pb element content in the segregation area predicted by the segregation heat formulas is 53.5 \%, which is consistent with the experimental result of 49.11 \%. Density functional theory (DFT) calculation and Molecular dynamics (MD) simulation results were used to prove that the Pb segregation is caused by the oxidation of β-Sn.",

keywords = "DFT calculation, Gamma irradiation, MD simulation, Pb segregation, SnPb eutectic solder joint",

author = "Qilong Guan and Chunjin Hang and Wei Zhang and Shengli Li and Xiaojiu Tang and Dan Yu and Ying Ding and Xiuli Wang and Guangdong Wu and Gang Yao",

note = "Publisher Copyright: {\textcopyright} 2024 Elsevier Ltd",

year = "2024",

month = aug,

day = "1",

doi = "10.1016/j.corsci.2024.112249",

language = "英语",

volume = "236",

journal = "Corrosion Science",

issn = "0010-938X",

publisher = "Elsevier Ltd",

}

TY - JOUR

T1 - Pb Segregation in SnPb eutectic solder alloy induced by gamma irradiation

AU - Guan, Qilong

AU - Hang, Chunjin

AU - Zhang, Wei

AU - Li, Shengli

AU - Tang, Xiaojiu

AU - Yu, Dan

AU - Ding, Ying

AU - Wang, Xiuli

AU - Wu, Guangdong

AU - Yao, Gang

PY - 2024/8/1

Y1 - 2024/8/1

N2 - Pb segregated and formed a Pb segregation area in SnPb eutectic solder joint after 100 h of gamma irradiation. With the irradiation time increased to 150 h, Pb segregating stopped. The Pb segregation was attributed to the oxidation of β-Sn to SnO2 induced by the gamma irradiation. The Pb element content in the segregation area predicted by the segregation heat formulas is 53.5 %, which is consistent with the experimental result of 49.11 %. Density functional theory (DFT) calculation and Molecular dynamics (MD) simulation results were used to prove that the Pb segregation is caused by the oxidation of β-Sn.

AB - Pb segregated and formed a Pb segregation area in SnPb eutectic solder joint after 100 h of gamma irradiation. With the irradiation time increased to 150 h, Pb segregating stopped. The Pb segregation was attributed to the oxidation of β-Sn to SnO2 induced by the gamma irradiation. The Pb element content in the segregation area predicted by the segregation heat formulas is 53.5 %, which is consistent with the experimental result of 49.11 %. Density functional theory (DFT) calculation and Molecular dynamics (MD) simulation results were used to prove that the Pb segregation is caused by the oxidation of β-Sn.

KW - DFT calculation

KW - Gamma irradiation

KW - MD simulation

KW - Pb segregation

KW - SnPb eutectic solder joint

UR - https://www.scopus.com/pages/publications/85198221264

U2 - 10.1016/j.corsci.2024.112249

DO - 10.1016/j.corsci.2024.112249

M3 - 文章

AN - SCOPUS:85198221264

SN - 0010-938X

VL - 236

JO - Corrosion Science

JF - Corrosion Science

M1 - 112249

ER -

Pb Segregation in SnPb eutectic solder alloy induced by gamma irradiation

Abstract

Keywords

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