Oxidative C-C bond cleavage of aldehydes via visible-light photoredox catalysis

Hongnan Sun; Chao Yang; Fei Gao; Zhe Li; Wujiong Xia

doi:10.1021/ol303437m

Oxidative C-C bond cleavage of aldehydes via visible-light photoredox catalysis

Hongnan Sun
, Chao Yang
, Fei Gao
, Zhe Li
, Wujiong Xia^*

^*Corresponding author for this work

School of Sciences

Harbin Institute of Technology
Lanzhou University

Research output: Contribution to journal › Article › peer-review

107 Scopus citations

Abstract

The visible-light mediated oxidative C-C bond cleavage of aldehydes has been achieved in good yields at ambient temperature and open to air using Ru(bpy)₃Cl₂ (bpy = 2,2′-bipyridine) as the photoredox catalyst. Moreover, we further demonstrated the application in a tandem Michael/oxidative C-C bond cleavage reaction.

Original language	English
Pages (from-to)	624-627
Number of pages	4
Journal	Organic Letters
Volume	15
Issue number	3
DOIs	https://doi.org/10.1021/ol303437m
State	Published - 1 Feb 2013

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@article{de98e3c56a384ba1bb27fb28776a7a32,

title = "Oxidative C-C bond cleavage of aldehydes via visible-light photoredox catalysis",

abstract = "The visible-light mediated oxidative C-C bond cleavage of aldehydes has been achieved in good yields at ambient temperature and open to air using Ru(bpy)3Cl2 (bpy = 2,2′-bipyridine) as the photoredox catalyst. Moreover, we further demonstrated the application in a tandem Michael/oxidative C-C bond cleavage reaction.",

author = "Hongnan Sun and Chao Yang and Fei Gao and Zhe Li and Wujiong Xia",

year = "2013",

month = feb,

day = "1",

doi = "10.1021/ol303437m",

language = "英语",

volume = "15",

pages = "624--627",

journal = "Organic Letters",

issn = "1523-7060",

publisher = "American Chemical Society",

number = "3",

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TY - JOUR

T1 - Oxidative C-C bond cleavage of aldehydes via visible-light photoredox catalysis

AU - Sun, Hongnan

AU - Yang, Chao

AU - Gao, Fei

AU - Li, Zhe

AU - Xia, Wujiong

PY - 2013/2/1

Y1 - 2013/2/1

N2 - The visible-light mediated oxidative C-C bond cleavage of aldehydes has been achieved in good yields at ambient temperature and open to air using Ru(bpy)3Cl2 (bpy = 2,2′-bipyridine) as the photoredox catalyst. Moreover, we further demonstrated the application in a tandem Michael/oxidative C-C bond cleavage reaction.

AB - The visible-light mediated oxidative C-C bond cleavage of aldehydes has been achieved in good yields at ambient temperature and open to air using Ru(bpy)3Cl2 (bpy = 2,2′-bipyridine) as the photoredox catalyst. Moreover, we further demonstrated the application in a tandem Michael/oxidative C-C bond cleavage reaction.

UR - https://www.scopus.com/pages/publications/84873389974

U2 - 10.1021/ol303437m

DO - 10.1021/ol303437m

M3 - 文章

AN - SCOPUS:84873389974

SN - 1523-7060

VL - 15

SP - 624

EP - 627

JO - Organic Letters

JF - Organic Letters

IS - 3

ER -

Oxidative C-C bond cleavage of aldehydes via visible-light photoredox catalysis

Abstract

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