Optical properties and transmittances of ZnO-containing nanofluids in spectral splitting photovoltaic/thermal systems

As ZnO nanoparticles had the advantages of high thermal conductivity and low cost, the possibility of using ZnO nanoparticles in spectral splitting photovoltaic/thermal (PV/T) systems was initially studied from the perspective of optical properties. Water–ZnO and glycol–ZnO nanofluids were prepared via a two-step method and used for model validation and stability testing. The scheme employed to investigate the optical properties and radiative transfer of the nanofluids was developed using Mie scattering theory combined with the Monte Carlo ray tracing (MCRT) method. The overall effective spectral transmittance coefficients of PV cells were utilized for comprehensive evaluation of the spectral transmittances of the nanofluids in spectral splitting PV/T systems. The overall effective spectral transmittance of a PV cell water-ZnO nanofluids was 21.54% higher than that those of cells containing water–polypyrrole and water–Cu₉S₅ nanofluids, respectively. The effects of the nanoparticle diameter, mass concentration and the optical length of the nanofluid on the spectral transmittance of glycol–ZnO nanofluid were also investigated.