Optical limiting properties of W2Ag4S 8(PPh3)4 and Mo2Ag4S 8(PPh3)4

Qing Chang; Yan Wang; Hegen Zheng; Yinglin Song

doi:10.1016/j.physb.2010.05.076

Optical limiting properties of W₂Ag₄S ₈(PPh₃)₄ and Mo₂Ag₄S ₈(PPh₃)₄

Qing Chang^*
, Yan Wang
, Hegen Zheng
, Yinglin Song

^*Corresponding author for this work

School of Physics

Heilongjiang University
Nanjing University

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

Optical limiting (OL) properties of two hexagonal prism metal clusters, W₂Ag₄S₈(PPh₃)₄ and Mo₂Ag₄S₈(PPh₃)₄ doped in polymethyl methacrylate (PMMA) polymer and DMF solutions, respectively, were contrastively investigated by using nanosecond laser pulses at 532 nm with a repetition rate of 1 Hz. Experimental results show that the output fluence of DMF solutions for the two samples are both lower than that of their PMMA polymers at a given input fluence; this means DMF solutions of W ₂Ag₄S₈(PPh₃)₄ and Mo ₂Ag₄S₈(PPh₃)₄ have better OL properties than that of solid PMMA polymers. The reason is explained by a stimulated scattering theory. That is because the scattering degree of solutions is stronger than that of the corresponding solid polymers due to large density perturbations for solution samples.

Original language	English
Pages (from-to)	3732-3734
Number of pages	3
Journal	Physica B: Condensed Matter
Volume	405
Issue number	17
DOIs	https://doi.org/10.1016/j.physb.2010.05.076
State	Published - 1 Sep 2010

Keywords

Hexagonal prism metal cluster
Optical limiting
Polymers
Stimulated scattering

Access to Document

10.1016/j.physb.2010.05.076

Cite this

@article{073a4f491d534f7dbcadb31415564e21,

title = "Optical limiting properties of W2Ag4S 8(PPh3)4 and Mo2Ag4S 8(PPh3)4",

abstract = "Optical limiting (OL) properties of two hexagonal prism metal clusters, W2Ag4S8(PPh3)4 and Mo2Ag4S8(PPh3)4 doped in polymethyl methacrylate (PMMA) polymer and DMF solutions, respectively, were contrastively investigated by using nanosecond laser pulses at 532 nm with a repetition rate of 1 Hz. Experimental results show that the output fluence of DMF solutions for the two samples are both lower than that of their PMMA polymers at a given input fluence; this means DMF solutions of W 2Ag4S8(PPh3)4 and Mo 2Ag4S8(PPh3)4 have better OL properties than that of solid PMMA polymers. The reason is explained by a stimulated scattering theory. That is because the scattering degree of solutions is stronger than that of the corresponding solid polymers due to large density perturbations for solution samples.",

keywords = "Hexagonal prism metal cluster, Optical limiting, Polymers, Stimulated scattering",

author = "Qing Chang and Yan Wang and Hegen Zheng and Yinglin Song",

year = "2010",

month = sep,

day = "1",

doi = "10.1016/j.physb.2010.05.076",

language = "英语",

volume = "405",

pages = "3732--3734",

journal = "Physica B: Condensed Matter",

issn = "0921-4526",

publisher = "Elsevier B.V.",

number = "17",

}

TY - JOUR

T1 - Optical limiting properties of W2Ag4S 8(PPh3)4 and Mo2Ag4S 8(PPh3)4

AU - Chang, Qing

AU - Wang, Yan

AU - Zheng, Hegen

AU - Song, Yinglin

PY - 2010/9/1

Y1 - 2010/9/1

N2 - Optical limiting (OL) properties of two hexagonal prism metal clusters, W2Ag4S8(PPh3)4 and Mo2Ag4S8(PPh3)4 doped in polymethyl methacrylate (PMMA) polymer and DMF solutions, respectively, were contrastively investigated by using nanosecond laser pulses at 532 nm with a repetition rate of 1 Hz. Experimental results show that the output fluence of DMF solutions for the two samples are both lower than that of their PMMA polymers at a given input fluence; this means DMF solutions of W 2Ag4S8(PPh3)4 and Mo 2Ag4S8(PPh3)4 have better OL properties than that of solid PMMA polymers. The reason is explained by a stimulated scattering theory. That is because the scattering degree of solutions is stronger than that of the corresponding solid polymers due to large density perturbations for solution samples.

AB - Optical limiting (OL) properties of two hexagonal prism metal clusters, W2Ag4S8(PPh3)4 and Mo2Ag4S8(PPh3)4 doped in polymethyl methacrylate (PMMA) polymer and DMF solutions, respectively, were contrastively investigated by using nanosecond laser pulses at 532 nm with a repetition rate of 1 Hz. Experimental results show that the output fluence of DMF solutions for the two samples are both lower than that of their PMMA polymers at a given input fluence; this means DMF solutions of W 2Ag4S8(PPh3)4 and Mo 2Ag4S8(PPh3)4 have better OL properties than that of solid PMMA polymers. The reason is explained by a stimulated scattering theory. That is because the scattering degree of solutions is stronger than that of the corresponding solid polymers due to large density perturbations for solution samples.

KW - Hexagonal prism metal cluster

KW - Optical limiting

KW - Polymers

KW - Stimulated scattering

UR - https://www.scopus.com/pages/publications/77955550945

U2 - 10.1016/j.physb.2010.05.076

DO - 10.1016/j.physb.2010.05.076

M3 - 文章

AN - SCOPUS:77955550945

SN - 0921-4526

VL - 405

SP - 3732

EP - 3734

JO - Physica B: Condensed Matter

JF - Physica B: Condensed Matter

IS - 17

ER -

Optical limiting properties of W₂Ag₄S ₈(PPh₃)₄ and Mo₂Ag₄S ₈(PPh₃)₄

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this