One-step chemical functionalization of polyethylene surfaces via diarylcarbene insertion

Zhen Hu; Shuyun Chng; Yijun Liu; Mark G. Moloney; Emily M. Parker; Linda Y.L. Wu

doi:10.1016/j.matlet.2018.01.166

One-step chemical functionalization of polyethylene surfaces via diarylcarbene insertion

Zhen Hu^*
, Shuyun Chng
, Yijun Liu
, Mark G. Moloney
, Emily M. Parker
, Linda Y.L. Wu

^*Corresponding author for this work

School of Chemistry and Chemical Engineering, Harbin Institute of Technology
University of Oxford
Agency for Science, Technology and Research, Singapore

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

Three diarylcarbene derivatives with reactive groups were synthesized and used to graft functional groups onto a plasma-modified polyethylene surface via one-step carbene insertion. The modification is observable spectroscopically, and this one-step strategy provides facile and efficient tool to modify the surface macroscopic properties of low surface energy materials.

Original language	English
Pages (from-to)	157-160
Number of pages	4
Journal	Materials Letters
Volume	218
DOIs	https://doi.org/10.1016/j.matlet.2018.01.166
State	Published - 1 May 2018
Externally published	Yes

Keywords

Diaryldiazomethane
Functionality
Hydrophobic
Post-polymerisation
Surface modification

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10.1016/j.matlet.2018.01.166

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title = "One-step chemical functionalization of polyethylene surfaces via diarylcarbene insertion",

abstract = "Three diarylcarbene derivatives with reactive groups were synthesized and used to graft functional groups onto a plasma-modified polyethylene surface via one-step carbene insertion. The modification is observable spectroscopically, and this one-step strategy provides facile and efficient tool to modify the surface macroscopic properties of low surface energy materials.",

keywords = "Diaryldiazomethane, Functionality, Hydrophobic, Post-polymerisation, Surface modification",

author = "Zhen Hu and Shuyun Chng and Yijun Liu and Moloney, \{Mark G.\} and Parker, \{Emily M.\} and Wu, \{Linda Y.L.\}",

note = "Publisher Copyright: {\textcopyright} 2018",

year = "2018",

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day = "1",

doi = "10.1016/j.matlet.2018.01.166",

language = "英语",

volume = "218",

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journal = "Materials Letters",

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T1 - One-step chemical functionalization of polyethylene surfaces via diarylcarbene insertion

AU - Hu, Zhen

AU - Chng, Shuyun

AU - Liu, Yijun

AU - Moloney, Mark G.

AU - Parker, Emily M.

AU - Wu, Linda Y.L.

PY - 2018/5/1

Y1 - 2018/5/1

N2 - Three diarylcarbene derivatives with reactive groups were synthesized and used to graft functional groups onto a plasma-modified polyethylene surface via one-step carbene insertion. The modification is observable spectroscopically, and this one-step strategy provides facile and efficient tool to modify the surface macroscopic properties of low surface energy materials.

AB - Three diarylcarbene derivatives with reactive groups were synthesized and used to graft functional groups onto a plasma-modified polyethylene surface via one-step carbene insertion. The modification is observable spectroscopically, and this one-step strategy provides facile and efficient tool to modify the surface macroscopic properties of low surface energy materials.

KW - Diaryldiazomethane

KW - Functionality

KW - Hydrophobic

KW - Post-polymerisation

KW - Surface modification

UR - https://www.scopus.com/pages/publications/85041465189

U2 - 10.1016/j.matlet.2018.01.166

DO - 10.1016/j.matlet.2018.01.166

M3 - 文章

AN - SCOPUS:85041465189

SN - 0167-577X

VL - 218

SP - 157

EP - 160

JO - Materials Letters

JF - Materials Letters

ER -

One-step chemical functionalization of polyethylene surfaces via diarylcarbene insertion

Abstract

Keywords

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