Observation of Ferromagnetism in Dilute Magnetic Halide Perovskite Semiconductors

Zhongwei Chen; Chunmei Wang; Jie Xue; Jian Chen; Lingling Mao; Haoliang Liu; Haipeng Lu

doi:10.1021/acs.nanolett.3c04982

Observation of Ferromagnetism in Dilute Magnetic Halide Perovskite Semiconductors

Zhongwei Chen
, Chunmei Wang
, Jie Xue
, Jian Chen
, Lingling Mao
, Haoliang Liu^*
, Haipeng Lu^*

^*Corresponding author for this work

Hong Kong University of Science and Technology
Harbin Institute of Technology
Southern University of Science and Technology

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

Dilute magnetic semiconductors (DMSs) have attracted much attention because of their potential use in spintronic devices. Here, we demonstrate the observation of robust ferromagnetism in a solution-processable halide perovskite semiconductor with dilute magnetic ions. By codoping of magnetic (Fe²⁺) and aliovalent (Bi³⁺) metal ions into CH₃NH₃PbCl₃ (MAPbCl₃) perovskite, ferromagnetism with well-saturated magnetic hysteresis loops and a maximum coercivity field of 1280 Oe was observed below 12 K. The ferromagnetic resonance measurements revealed that the incorporation of aliovalent ions modulates the carrier concentration and plays an essential role in realizing the ferromagnetism in dilute magnetic halide perovskites. Magnetic ions are proposed to interact through itinerant charge carriers to achieve ferromagnetic coupling. Our work provides a new avenue for the development of solution-processable magnetic semiconductors.

Original language	English
Pages (from-to)	3125-3132
Number of pages	8
Journal	Nano Letters
Volume	24
Issue number	10
DOIs	https://doi.org/10.1021/acs.nanolett.3c04982
State	Published - 13 Mar 2024
Externally published	Yes

Keywords

dilute magnetic semiconductor
ferromagnetism
halide perovskite
magnetic polaron

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10.1021/acs.nanolett.3c04982

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title = "Observation of Ferromagnetism in Dilute Magnetic Halide Perovskite Semiconductors",

abstract = "Dilute magnetic semiconductors (DMSs) have attracted much attention because of their potential use in spintronic devices. Here, we demonstrate the observation of robust ferromagnetism in a solution-processable halide perovskite semiconductor with dilute magnetic ions. By codoping of magnetic (Fe2+) and aliovalent (Bi3+) metal ions into CH3NH3PbCl3 (MAPbCl3) perovskite, ferromagnetism with well-saturated magnetic hysteresis loops and a maximum coercivity field of 1280 Oe was observed below 12 K. The ferromagnetic resonance measurements revealed that the incorporation of aliovalent ions modulates the carrier concentration and plays an essential role in realizing the ferromagnetism in dilute magnetic halide perovskites. Magnetic ions are proposed to interact through itinerant charge carriers to achieve ferromagnetic coupling. Our work provides a new avenue for the development of solution-processable magnetic semiconductors.",

keywords = "dilute magnetic semiconductor, ferromagnetism, halide perovskite, magnetic polaron",

author = "Zhongwei Chen and Chunmei Wang and Jie Xue and Jian Chen and Lingling Mao and Haoliang Liu and Haipeng Lu",

note = "Publisher Copyright: {\textcopyright} 2024 American Chemical Society",

year = "2024",

month = mar,

day = "13",

doi = "10.1021/acs.nanolett.3c04982",

language = "英语",

volume = "24",

pages = "3125--3132",

journal = "Nano Letters",

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TY - JOUR

T1 - Observation of Ferromagnetism in Dilute Magnetic Halide Perovskite Semiconductors

AU - Chen, Zhongwei

AU - Wang, Chunmei

AU - Xue, Jie

AU - Chen, Jian

AU - Mao, Lingling

AU - Liu, Haoliang

AU - Lu, Haipeng

PY - 2024/3/13

Y1 - 2024/3/13

N2 - Dilute magnetic semiconductors (DMSs) have attracted much attention because of their potential use in spintronic devices. Here, we demonstrate the observation of robust ferromagnetism in a solution-processable halide perovskite semiconductor with dilute magnetic ions. By codoping of magnetic (Fe2+) and aliovalent (Bi3+) metal ions into CH3NH3PbCl3 (MAPbCl3) perovskite, ferromagnetism with well-saturated magnetic hysteresis loops and a maximum coercivity field of 1280 Oe was observed below 12 K. The ferromagnetic resonance measurements revealed that the incorporation of aliovalent ions modulates the carrier concentration and plays an essential role in realizing the ferromagnetism in dilute magnetic halide perovskites. Magnetic ions are proposed to interact through itinerant charge carriers to achieve ferromagnetic coupling. Our work provides a new avenue for the development of solution-processable magnetic semiconductors.

AB - Dilute magnetic semiconductors (DMSs) have attracted much attention because of their potential use in spintronic devices. Here, we demonstrate the observation of robust ferromagnetism in a solution-processable halide perovskite semiconductor with dilute magnetic ions. By codoping of magnetic (Fe2+) and aliovalent (Bi3+) metal ions into CH3NH3PbCl3 (MAPbCl3) perovskite, ferromagnetism with well-saturated magnetic hysteresis loops and a maximum coercivity field of 1280 Oe was observed below 12 K. The ferromagnetic resonance measurements revealed that the incorporation of aliovalent ions modulates the carrier concentration and plays an essential role in realizing the ferromagnetism in dilute magnetic halide perovskites. Magnetic ions are proposed to interact through itinerant charge carriers to achieve ferromagnetic coupling. Our work provides a new avenue for the development of solution-processable magnetic semiconductors.

KW - dilute magnetic semiconductor

KW - ferromagnetism

KW - halide perovskite

KW - magnetic polaron

UR - https://www.scopus.com/pages/publications/85186370528

U2 - 10.1021/acs.nanolett.3c04982

DO - 10.1021/acs.nanolett.3c04982

M3 - 文章

C2 - 38421805

AN - SCOPUS:85186370528

SN - 1530-6984

VL - 24

SP - 3125

EP - 3132

JO - Nano Letters

JF - Nano Letters

IS - 10

ER -

Observation of Ferromagnetism in Dilute Magnetic Halide Perovskite Semiconductors

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Keywords

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