Novel oxalate coordination mode and roles: Synthesis, structure and fluorescence property of [Cd 2(μ 5-ox)(μ 3- OH) 2] with 3-D structure

Jing Lu; Yong Li; Kui Zhao; Ji Qing Xu; Jie Hui Yu; Guang Hua Li; Xiao Zhang; Hai Ying Bie; Tie Gang Wang

doi:10.1016/j.inoche.2004.08.019

Novel oxalate coordination mode and roles: Synthesis, structure and fluorescence property of [Cd ₂(μ ₅-ox)(μ ₃- OH) ₂] with 3-D structure

Jing Lu
, Yong Li
, Kui Zhao
, Ji Qing Xu
, Jie Hui Yu
, Guang Hua Li
, Xiao Zhang
, Hai Ying Bie
, Tie Gang Wang

Jilin University

Research output: Contribution to journal › Article › peer-review

39 Scopus citations

Abstract

Coordination compound [Cd ₂(μ ₅-C ₂O ₄)(μ ₃-OH) ₂] displays a 3-D framework with two kinds of channels: 10-membered and helical 8-membered, in which the ox ligands adopt the μ ₅-bridging novel coordination mode and play a dual role simultaneously. A coordination compound [Cd ₂(μ ₅-C ₂O ₄)(μ ₃-OH) ₂] 1, which was synthesized from hydrothermal reactions, possesses some attractive structural features: (a) oxalate unit exhibits a five-bridging novel coordination mode and plays a dual role simultaneously; (b) [Cd(OH)] _∞ corrugated sheet and 3-D [Cd ₂(ox)] _∞ network are intercrossed with each other in the vertical direction. Compound 1 exhibits strong fluorescent emission.

Original language	English
Pages (from-to)	1154-1156
Number of pages	3
Journal	Inorganic Chemistry Communications
Volume	7
Issue number	10
DOIs	https://doi.org/10.1016/j.inoche.2004.08.019
State	Published - Oct 2004
Externally published	Yes

Keywords

Coordination mode
Fluorescence
Hydrothermal synthesis
Oxalate

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10.1016/j.inoche.2004.08.019

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@article{9ad50361238b42269c1d5fd34ba226a3,

title = "Novel oxalate coordination mode and roles: Synthesis, structure and fluorescence property of [Cd 2(μ 5-ox)(μ 3- OH) 2] with 3-D structure",

abstract = "Coordination compound [Cd 2(μ 5-C 2O 4)(μ 3-OH) 2] displays a 3-D framework with two kinds of channels: 10-membered and helical 8-membered, in which the ox ligands adopt the μ 5-bridging novel coordination mode and play a dual role simultaneously. A coordination compound [Cd 2(μ 5-C 2O 4)(μ 3-OH) 2] 1, which was synthesized from hydrothermal reactions, possesses some attractive structural features: (a) oxalate unit exhibits a five-bridging novel coordination mode and plays a dual role simultaneously; (b) [Cd(OH)] ∞ corrugated sheet and 3-D [Cd 2(ox)] ∞ network are intercrossed with each other in the vertical direction. Compound 1 exhibits strong fluorescent emission.",

keywords = "Coordination mode, Fluorescence, Hydrothermal synthesis, Oxalate",

author = "Jing Lu and Yong Li and Kui Zhao and Xu, \{Ji Qing\} and Yu, \{Jie Hui\} and Li, \{Guang Hua\} and Xiao Zhang and Bie, \{Hai Ying\} and Wang, \{Tie Gang\}",

year = "2004",

month = oct,

doi = "10.1016/j.inoche.2004.08.019",

language = "英语",

volume = "7",

pages = "1154--1156",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

number = "10",

}

TY - JOUR

T1 - Novel oxalate coordination mode and roles

T2 - Synthesis, structure and fluorescence property of [Cd 2(μ 5-ox)(μ 3- OH) 2] with 3-D structure

AU - Lu, Jing

AU - Li, Yong

AU - Zhao, Kui

AU - Xu, Ji Qing

AU - Yu, Jie Hui

AU - Li, Guang Hua

AU - Zhang, Xiao

AU - Bie, Hai Ying

AU - Wang, Tie Gang

PY - 2004/10

Y1 - 2004/10

N2 - Coordination compound [Cd 2(μ 5-C 2O 4)(μ 3-OH) 2] displays a 3-D framework with two kinds of channels: 10-membered and helical 8-membered, in which the ox ligands adopt the μ 5-bridging novel coordination mode and play a dual role simultaneously. A coordination compound [Cd 2(μ 5-C 2O 4)(μ 3-OH) 2] 1, which was synthesized from hydrothermal reactions, possesses some attractive structural features: (a) oxalate unit exhibits a five-bridging novel coordination mode and plays a dual role simultaneously; (b) [Cd(OH)] ∞ corrugated sheet and 3-D [Cd 2(ox)] ∞ network are intercrossed with each other in the vertical direction. Compound 1 exhibits strong fluorescent emission.

AB - Coordination compound [Cd 2(μ 5-C 2O 4)(μ 3-OH) 2] displays a 3-D framework with two kinds of channels: 10-membered and helical 8-membered, in which the ox ligands adopt the μ 5-bridging novel coordination mode and play a dual role simultaneously. A coordination compound [Cd 2(μ 5-C 2O 4)(μ 3-OH) 2] 1, which was synthesized from hydrothermal reactions, possesses some attractive structural features: (a) oxalate unit exhibits a five-bridging novel coordination mode and plays a dual role simultaneously; (b) [Cd(OH)] ∞ corrugated sheet and 3-D [Cd 2(ox)] ∞ network are intercrossed with each other in the vertical direction. Compound 1 exhibits strong fluorescent emission.

KW - Coordination mode

KW - Fluorescence

KW - Hydrothermal synthesis

KW - Oxalate

UR - https://www.scopus.com/pages/publications/4744351523

U2 - 10.1016/j.inoche.2004.08.019

DO - 10.1016/j.inoche.2004.08.019

M3 - 文章

AN - SCOPUS:4744351523

SN - 1387-7003

VL - 7

SP - 1154

EP - 1156

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 10

ER -

Novel oxalate coordination mode and roles: Synthesis, structure and fluorescence property of [Cd ₂(μ ₅-ox)(μ ₃- OH) ₂] with 3-D structure

Abstract

Keywords

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