Novel Multifunctional Zn Metal-Organic Framework Fluorescent Probe Demonstrating Unique Sensitivity and Selectivity for Detection of PA and Fe3 Ions in Water Solution

Xinrui Zhuang; Xiao Zhang; Nanxi Zhang; Yan Wang; Liyan Zhao; Qingfeng Yang

doi:10.1021/acs.cgd.9b00704

Novel Multifunctional Zn Metal-Organic Framework Fluorescent Probe Demonstrating Unique Sensitivity and Selectivity for Detection of PA and Fe³ Ions in Water Solution

Xinrui Zhuang
, Xiao Zhang^*
, Nanxi Zhang
, Yan Wang
, Liyan Zhao
, Qingfeng Yang

^*Corresponding author for this work

School of Chemistry and Chemical Engineering, Harbin Institute of Technology
School of Life Science and Technology, Harbin Institute of Technology
Ningxia University

Research output: Contribution to journal › Article › peer-review

76 Scopus citations

Abstract

A novel metal-organic framework {Zn₂(tpt)₂(tad)₂·H₂O} (tpt = 2,4,6-tri(pyridin-4-yl)-1,3,5-triazine, H₂tda = 2,5-thiophene dicarboxylic acid) with a 3-fold interpenetrating 3D framework was successfully synthesized under hydrothermal conditions. As expected, 1 displays excellent luminescence and can stably exist in different pure organic solvents and acid-base solution. 1 can be considered as an ultrasensitive sensor for detection of Fe³ ions and PA with high selectivity by fluorescence quenching behaviors. Meanwhile, the fluorescence test plates show the visible color change of Fe³ ions which can be easily observed by the naked eye in the detection process, which makes Fe³ ions more easily recognized than various metal ions. In addition, the mechanism of fluorescence quenching is also further discussed.

Original language	English
Pages (from-to)	5729-5736
Number of pages	8
Journal	Crystal Growth and Design
Volume	19
Issue number	10
DOIs	https://doi.org/10.1021/acs.cgd.9b00704
State	Published - 2 Oct 2019
Externally published	Yes

Access to Document

10.1021/acs.cgd.9b00704

Cite this

@article{4b8b6246a0a7427687b55794aade2c79,

title = "Novel Multifunctional Zn Metal-Organic Framework Fluorescent Probe Demonstrating Unique Sensitivity and Selectivity for Detection of PA and Fe3 Ions in Water Solution",

abstract = "A novel metal-organic framework \{Zn2(tpt)2(tad)2·H2O\} (tpt = 2,4,6-tri(pyridin-4-yl)-1,3,5-triazine, H2tda = 2,5-thiophene dicarboxylic acid) with a 3-fold interpenetrating 3D framework was successfully synthesized under hydrothermal conditions. As expected, 1 displays excellent luminescence and can stably exist in different pure organic solvents and acid-base solution. 1 can be considered as an ultrasensitive sensor for detection of Fe3 ions and PA with high selectivity by fluorescence quenching behaviors. Meanwhile, the fluorescence test plates show the visible color change of Fe3 ions which can be easily observed by the naked eye in the detection process, which makes Fe3 ions more easily recognized than various metal ions. In addition, the mechanism of fluorescence quenching is also further discussed.",

author = "Xinrui Zhuang and Xiao Zhang and Nanxi Zhang and Yan Wang and Liyan Zhao and Qingfeng Yang",

note = "Publisher Copyright: Copyright {\textcopyright} 2019 American Chemical Society.",

year = "2019",

month = oct,

day = "2",

doi = "10.1021/acs.cgd.9b00704",

language = "英语",

volume = "19",

pages = "5729--5736",

journal = "Crystal Growth and Design",

issn = "1528-7483",

publisher = "American Chemical Society",

number = "10",

}

TY - JOUR

T1 - Novel Multifunctional Zn Metal-Organic Framework Fluorescent Probe Demonstrating Unique Sensitivity and Selectivity for Detection of PA and Fe3 Ions in Water Solution

AU - Zhuang, Xinrui

AU - Zhang, Xiao

AU - Zhang, Nanxi

AU - Wang, Yan

AU - Zhao, Liyan

AU - Yang, Qingfeng

PY - 2019/10/2

Y1 - 2019/10/2

N2 - A novel metal-organic framework {Zn2(tpt)2(tad)2·H2O} (tpt = 2,4,6-tri(pyridin-4-yl)-1,3,5-triazine, H2tda = 2,5-thiophene dicarboxylic acid) with a 3-fold interpenetrating 3D framework was successfully synthesized under hydrothermal conditions. As expected, 1 displays excellent luminescence and can stably exist in different pure organic solvents and acid-base solution. 1 can be considered as an ultrasensitive sensor for detection of Fe3 ions and PA with high selectivity by fluorescence quenching behaviors. Meanwhile, the fluorescence test plates show the visible color change of Fe3 ions which can be easily observed by the naked eye in the detection process, which makes Fe3 ions more easily recognized than various metal ions. In addition, the mechanism of fluorescence quenching is also further discussed.

AB - A novel metal-organic framework {Zn2(tpt)2(tad)2·H2O} (tpt = 2,4,6-tri(pyridin-4-yl)-1,3,5-triazine, H2tda = 2,5-thiophene dicarboxylic acid) with a 3-fold interpenetrating 3D framework was successfully synthesized under hydrothermal conditions. As expected, 1 displays excellent luminescence and can stably exist in different pure organic solvents and acid-base solution. 1 can be considered as an ultrasensitive sensor for detection of Fe3 ions and PA with high selectivity by fluorescence quenching behaviors. Meanwhile, the fluorescence test plates show the visible color change of Fe3 ions which can be easily observed by the naked eye in the detection process, which makes Fe3 ions more easily recognized than various metal ions. In addition, the mechanism of fluorescence quenching is also further discussed.

UR - https://www.scopus.com/pages/publications/85072701667

U2 - 10.1021/acs.cgd.9b00704

DO - 10.1021/acs.cgd.9b00704

M3 - 文章

AN - SCOPUS:85072701667

SN - 1528-7483

VL - 19

SP - 5729

EP - 5736

JO - Crystal Growth and Design

JF - Crystal Growth and Design

IS - 10

ER -

Novel Multifunctional Zn Metal-Organic Framework Fluorescent Probe Demonstrating Unique Sensitivity and Selectivity for Detection of PA and Fe³ Ions in Water Solution

Abstract

Access to Document

Other files and links

Fingerprint

Cite this