Novel cluster coordination polymers based on tetranuclear nest-shaped [WOS3Cu3] heterothiometallitic secondary building units and 4,4′-bipyridine ligand

Kai Liang; He Gen Zheng; Ying Lin Song; Yi Zhi Li; Xin Quan Xin

doi:10.1021/cg0606038

Novel cluster coordination polymers based on tetranuclear nest-shaped [WOS₃Cu₃] heterothiometallitic secondary building units and 4,4′-bipyridine ligand

Kai Liang^*
, He Gen Zheng
, Ying Lin Song
, Yi Zhi Li
, Xin Quan Xin

^*Corresponding author for this work

School of Physics

Fudan University
Nanjing University

Research output: Contribution to journal › Article › peer-review

42 Scopus citations

Abstract

Two novel cluster coordination polymers, {[W₄O₄S ₁₂Cu₁₂Cl₂(4,4′-bipy)₁₂]2Cl. 4H₂O}_n (1) and {[(n-Bu)₄N]₂[W ₂O2́S₆-Cu₆Br₄(4,4′-bipy) ₃]}_n (2) (4,4′-bipy = 4,4′-bipyridine), based on tetranuclear nest-shaped heterothiometallatillic secondary building units [WOS₃Cu₃] have been synthesized and characterized by X-ray diffraction. Compound 1 shows a 3D 3-fold interpenetrated cationic diamondoid structure, whereas compound 2 shows a 1D anionic zigzag pattern. Both of them exhibit excellent third-order nonlinear optical (NLO) properties.

Original language	English
Pages (from-to)	373-376
Number of pages	4
Journal	Crystal Growth and Design
Volume	7
Issue number	2
DOIs	https://doi.org/10.1021/cg0606038
State	Published - Feb 2007

Access to Document

10.1021/cg0606038

Cite this

@article{791146e733fe4f77b538aff353a64242,

title = "Novel cluster coordination polymers based on tetranuclear nest-shaped [WOS3Cu3] heterothiometallitic secondary building units and 4,4′-bipyridine ligand",

abstract = "Two novel cluster coordination polymers, \{[W4O4S 12Cu12Cl2(4,4′-bipy)12]2Cl. 4H2O\}n (1) and \{[(n-Bu)4N]2[W 2O{\'2}S6-Cu6Br4(4,4′-bipy) 3]\}n (2) (4,4′-bipy = 4,4′-bipyridine), based on tetranuclear nest-shaped heterothiometallatillic secondary building units [WOS3Cu3] have been synthesized and characterized by X-ray diffraction. Compound 1 shows a 3D 3-fold interpenetrated cationic diamondoid structure, whereas compound 2 shows a 1D anionic zigzag pattern. Both of them exhibit excellent third-order nonlinear optical (NLO) properties.",

author = "Kai Liang and Zheng, \{He Gen\} and Song, \{Ying Lin\} and Li, \{Yi Zhi\} and Xin, \{Xin Quan\}",

year = "2007",

month = feb,

doi = "10.1021/cg0606038",

language = "英语",

volume = "7",

pages = "373--376",

journal = "Crystal Growth and Design",

issn = "1528-7483",

publisher = "American Chemical Society",

number = "2",

}

TY - JOUR

T1 - Novel cluster coordination polymers based on tetranuclear nest-shaped [WOS3Cu3] heterothiometallitic secondary building units and 4,4′-bipyridine ligand

AU - Liang, Kai

AU - Zheng, He Gen

AU - Song, Ying Lin

AU - Li, Yi Zhi

AU - Xin, Xin Quan

PY - 2007/2

Y1 - 2007/2

N2 - Two novel cluster coordination polymers, {[W4O4S 12Cu12Cl2(4,4′-bipy)12]2Cl. 4H2O}n (1) and {[(n-Bu)4N]2[W 2O2́S6-Cu6Br4(4,4′-bipy) 3]}n (2) (4,4′-bipy = 4,4′-bipyridine), based on tetranuclear nest-shaped heterothiometallatillic secondary building units [WOS3Cu3] have been synthesized and characterized by X-ray diffraction. Compound 1 shows a 3D 3-fold interpenetrated cationic diamondoid structure, whereas compound 2 shows a 1D anionic zigzag pattern. Both of them exhibit excellent third-order nonlinear optical (NLO) properties.

AB - Two novel cluster coordination polymers, {[W4O4S 12Cu12Cl2(4,4′-bipy)12]2Cl. 4H2O}n (1) and {[(n-Bu)4N]2[W 2O2́S6-Cu6Br4(4,4′-bipy) 3]}n (2) (4,4′-bipy = 4,4′-bipyridine), based on tetranuclear nest-shaped heterothiometallatillic secondary building units [WOS3Cu3] have been synthesized and characterized by X-ray diffraction. Compound 1 shows a 3D 3-fold interpenetrated cationic diamondoid structure, whereas compound 2 shows a 1D anionic zigzag pattern. Both of them exhibit excellent third-order nonlinear optical (NLO) properties.

UR - https://www.scopus.com/pages/publications/33847294187

U2 - 10.1021/cg0606038

DO - 10.1021/cg0606038

M3 - 文章

AN - SCOPUS:33847294187

SN - 1528-7483

VL - 7

SP - 373

EP - 376

JO - Crystal Growth and Design

JF - Crystal Growth and Design

IS - 2

ER -

Novel cluster coordination polymers based on tetranuclear nest-shaped [WOS₃Cu₃] heterothiometallitic secondary building units and 4,4′-bipyridine ligand

Abstract

Access to Document

Other files and links

Fingerprint

Cite this