Novel 3D Nitrogen-Rich Metal Organic Framework for Highly Efficient CO2 Adsorption and Catalytic Conversion to Cyclic Carbonates under Ambient Temperature

Jianwen Lan; Mengshuai Liu; Xingyuan Lu; Xiao Zhang; Jianmin Sun

doi:10.1021/acssuschemeng.8b01055

Novel 3D Nitrogen-Rich Metal Organic Framework for Highly Efficient CO₂ Adsorption and Catalytic Conversion to Cyclic Carbonates under Ambient Temperature

Jianwen Lan
, Mengshuai Liu
, Xingyuan Lu
, Xiao Zhang^*
, Jianmin Sun

^*Corresponding author for this work

School of Chemistry and Chemical Engineering, Harbin Institute of Technology
Qingdao University of Science and Technology
Northeast Forestry University
Harbin Institute of Technology Shenzhen

Research output: Contribution to journal › Article › peer-review

132 Scopus citations

Abstract

A novel Lewis acid-base bifunctional Zn(II)-based MOF-Zn-1 [Zn₂L₂MA·2DMF] (MA = melamine, H₂L = 2,5-thiophenedicarboxylic acid), with abundant micropores and free -NH₂ groups was facilely assembled by incorporating zinc(II) ion with nitrogen-rich melamine and 2,5-thiophenedicarboxylic acid ligands. The constructed MOF-Zn-1 presented an excellent affinity toward CO₂ molecules due to the Lewis-base property together with abundant micropores. The Zn active sites could be used for epoxide activation. The acid-base synergistic effects facilitated CO₂ conversion into cyclic carbonates under ambient temperature using the porous MOF-Zn-1 as a heterogeneous catalyst. Moreover, the MOF-Zn-1 exhibited satisfied stability and versatility, and it was easy to recycle with no obvious decrease of catalytic activity. Then the feasible synergistic mechanism of MOF-Zn-1/Bu₄NBr catalysts for CO₂ conversion was proposed.

Original language	English
Pages (from-to)	8727-8735
Number of pages	9
Journal	ACS Sustainable Chemistry and Engineering
Volume	6
Issue number	7
DOIs	https://doi.org/10.1021/acssuschemeng.8b01055
State	Published - 2 Jul 2018
Externally published	Yes

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Keywords

Lewis acid-base
Zn-based MOF
carbon dioxide
cyclic carbonate
heterogeneous catalysis

Access to Document

10.1021/acssuschemeng.8b01055

Cite this

@article{ba50c3174a6345a69cc187f22c2b8127,

title = "Novel 3D Nitrogen-Rich Metal Organic Framework for Highly Efficient CO2 Adsorption and Catalytic Conversion to Cyclic Carbonates under Ambient Temperature",

abstract = "A novel Lewis acid-base bifunctional Zn(II)-based MOF-Zn-1 [Zn2L2MA·2DMF] (MA = melamine, H2L = 2,5-thiophenedicarboxylic acid), with abundant micropores and free -NH2 groups was facilely assembled by incorporating zinc(II) ion with nitrogen-rich melamine and 2,5-thiophenedicarboxylic acid ligands. The constructed MOF-Zn-1 presented an excellent affinity toward CO2 molecules due to the Lewis-base property together with abundant micropores. The Zn active sites could be used for epoxide activation. The acid-base synergistic effects facilitated CO2 conversion into cyclic carbonates under ambient temperature using the porous MOF-Zn-1 as a heterogeneous catalyst. Moreover, the MOF-Zn-1 exhibited satisfied stability and versatility, and it was easy to recycle with no obvious decrease of catalytic activity. Then the feasible synergistic mechanism of MOF-Zn-1/Bu4NBr catalysts for CO2 conversion was proposed.",

keywords = "Lewis acid-base, Zn-based MOF, carbon dioxide, cyclic carbonate, heterogeneous catalysis",

author = "Jianwen Lan and Mengshuai Liu and Xingyuan Lu and Xiao Zhang and Jianmin Sun",

note = "Publisher Copyright: {\textcopyright} 2018 American Chemical Society.",

year = "2018",

month = jul,

day = "2",

doi = "10.1021/acssuschemeng.8b01055",

language = "英语",

volume = "6",

pages = "8727--8735",

journal = "ACS Sustainable Chemistry and Engineering",

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TY - JOUR

T1 - Novel 3D Nitrogen-Rich Metal Organic Framework for Highly Efficient CO2 Adsorption and Catalytic Conversion to Cyclic Carbonates under Ambient Temperature

AU - Lan, Jianwen

AU - Liu, Mengshuai

AU - Lu, Xingyuan

AU - Zhang, Xiao

AU - Sun, Jianmin

PY - 2018/7/2

Y1 - 2018/7/2

N2 - A novel Lewis acid-base bifunctional Zn(II)-based MOF-Zn-1 [Zn2L2MA·2DMF] (MA = melamine, H2L = 2,5-thiophenedicarboxylic acid), with abundant micropores and free -NH2 groups was facilely assembled by incorporating zinc(II) ion with nitrogen-rich melamine and 2,5-thiophenedicarboxylic acid ligands. The constructed MOF-Zn-1 presented an excellent affinity toward CO2 molecules due to the Lewis-base property together with abundant micropores. The Zn active sites could be used for epoxide activation. The acid-base synergistic effects facilitated CO2 conversion into cyclic carbonates under ambient temperature using the porous MOF-Zn-1 as a heterogeneous catalyst. Moreover, the MOF-Zn-1 exhibited satisfied stability and versatility, and it was easy to recycle with no obvious decrease of catalytic activity. Then the feasible synergistic mechanism of MOF-Zn-1/Bu4NBr catalysts for CO2 conversion was proposed.

AB - A novel Lewis acid-base bifunctional Zn(II)-based MOF-Zn-1 [Zn2L2MA·2DMF] (MA = melamine, H2L = 2,5-thiophenedicarboxylic acid), with abundant micropores and free -NH2 groups was facilely assembled by incorporating zinc(II) ion with nitrogen-rich melamine and 2,5-thiophenedicarboxylic acid ligands. The constructed MOF-Zn-1 presented an excellent affinity toward CO2 molecules due to the Lewis-base property together with abundant micropores. The Zn active sites could be used for epoxide activation. The acid-base synergistic effects facilitated CO2 conversion into cyclic carbonates under ambient temperature using the porous MOF-Zn-1 as a heterogeneous catalyst. Moreover, the MOF-Zn-1 exhibited satisfied stability and versatility, and it was easy to recycle with no obvious decrease of catalytic activity. Then the feasible synergistic mechanism of MOF-Zn-1/Bu4NBr catalysts for CO2 conversion was proposed.

KW - Lewis acid-base

KW - Zn-based MOF

KW - carbon dioxide

KW - cyclic carbonate

KW - heterogeneous catalysis

UR - https://www.scopus.com/pages/publications/85049497216

U2 - 10.1021/acssuschemeng.8b01055

DO - 10.1021/acssuschemeng.8b01055

M3 - 文章

AN - SCOPUS:85049497216

SN - 2168-0485

VL - 6

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JO - ACS Sustainable Chemistry and Engineering

JF - ACS Sustainable Chemistry and Engineering

IS - 7

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