NASICON-structure Na3+xMnVxTi1-x(PO4)3/C cathode for sodium-ion battery with excellent cycling performance and high specific capacity

Mingxuan Zong; Yanjiang Zhang; Jianquan Liang; Xinghai Li; Qi Qi; Kangyi Chen; Li Zhao; Changsong Dai

doi:10.1016/j.matchemphys.2024.129401

NASICON-structure Na_3+xMnV_xTi_1-x(PO₄)₃/C cathode for sodium-ion battery with excellent cycling performance and high specific capacity

Mingxuan Zong
, Yanjiang Zhang
, Jianquan Liang
, Xinghai Li
, Qi Qi
, Kangyi Chen
, Li Zhao^*
, Changsong Dai

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Harbin Institute of Technology
Ltd
Research Institute

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

The recently discovered Na₃MnTi(PO₄)₃ cathode material has an extremely high theoretical capacity, but its poor cycling performance makes it challenging to apply. In this work, a series of NASICON-type Na_3+xMnV_xTi_1-x(PO₄)₃/C (x = 0, 0.1, 0.2, 0.3, 0.4, 0.5, 0.6, 0.8, 1) cathode materials were prepared by sol-gel method for sodium-ion batteries. X-ray diffraction (XRD) indicates that vanadium doping has increased the cell spacing within the material and the cell volume. From the results of X-ray photoelectron spectroscopy (XPS) and Energy dispersive X-ray spectroscopy (EDS) mapping images, it is shown that vanadium has been successfully doped into the material. Among them, the Na_3·3MnV_0·3Ti_0·7(PO₄)₃/C delivers an outstanding specific capacity (121.7 mAh g⁻¹ at 0.1C, C = 135 mA g⁻¹) and Na_3·4MnV_0·4Ti_0·6(PO₄)₃/C shows an excellent capacity retention (80.88 % after 1500 cycles at 1C). Notably, the coulombic efficiency of both materials during cycling is close to 100 %, indicating that these materials have great practical application value.

Original language	English
Article number	129401
Journal	Materials Chemistry and Physics
Volume	320
DOIs	https://doi.org/10.1016/j.matchemphys.2024.129401
State	Published - 1 Jul 2024

Keywords

Cathode material
NASICON
NaMnTi(PO)/C
Sodium-ion batteries

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10.1016/j.matchemphys.2024.129401

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@article{56d1bc49190c4703827465bdd8c1eb12,

title = "NASICON-structure Na3+xMnVxTi1-x(PO4)3/C cathode for sodium-ion battery with excellent cycling performance and high specific capacity",

abstract = "The recently discovered Na3MnTi(PO4)3 cathode material has an extremely high theoretical capacity, but its poor cycling performance makes it challenging to apply. In this work, a series of NASICON-type Na3+xMnVxTi1-x(PO4)3/C (x = 0, 0.1, 0.2, 0.3, 0.4, 0.5, 0.6, 0.8, 1) cathode materials were prepared by sol-gel method for sodium-ion batteries. X-ray diffraction (XRD) indicates that vanadium doping has increased the cell spacing within the material and the cell volume. From the results of X-ray photoelectron spectroscopy (XPS) and Energy dispersive X-ray spectroscopy (EDS) mapping images, it is shown that vanadium has been successfully doped into the material. Among them, the Na3·3MnV0·3Ti0·7(PO4)3/C delivers an outstanding specific capacity (121.7 mAh g−1 at 0.1C, C = 135 mA g−1) and Na3·4MnV0·4Ti0·6(PO4)3/C shows an excellent capacity retention (80.88 \% after 1500 cycles at 1C). Notably, the coulombic efficiency of both materials during cycling is close to 100 \%, indicating that these materials have great practical application value.",

keywords = "Cathode material, NASICON, NaMnTi(PO)/C, Sodium-ion batteries",

author = "Mingxuan Zong and Yanjiang Zhang and Jianquan Liang and Xinghai Li and Qi Qi and Kangyi Chen and Li Zhao and Changsong Dai",

note = "Publisher Copyright: {\textcopyright} 2024 Elsevier B.V.",

year = "2024",

month = jul,

day = "1",

doi = "10.1016/j.matchemphys.2024.129401",

language = "英语",

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journal = "Materials Chemistry and Physics",

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TY - JOUR

T1 - NASICON-structure Na3+xMnVxTi1-x(PO4)3/C cathode for sodium-ion battery with excellent cycling performance and high specific capacity

AU - Zong, Mingxuan

AU - Zhang, Yanjiang

AU - Liang, Jianquan

AU - Li, Xinghai

AU - Qi, Qi

AU - Chen, Kangyi

AU - Zhao, Li

AU - Dai, Changsong

PY - 2024/7/1

Y1 - 2024/7/1

N2 - The recently discovered Na3MnTi(PO4)3 cathode material has an extremely high theoretical capacity, but its poor cycling performance makes it challenging to apply. In this work, a series of NASICON-type Na3+xMnVxTi1-x(PO4)3/C (x = 0, 0.1, 0.2, 0.3, 0.4, 0.5, 0.6, 0.8, 1) cathode materials were prepared by sol-gel method for sodium-ion batteries. X-ray diffraction (XRD) indicates that vanadium doping has increased the cell spacing within the material and the cell volume. From the results of X-ray photoelectron spectroscopy (XPS) and Energy dispersive X-ray spectroscopy (EDS) mapping images, it is shown that vanadium has been successfully doped into the material. Among them, the Na3·3MnV0·3Ti0·7(PO4)3/C delivers an outstanding specific capacity (121.7 mAh g−1 at 0.1C, C = 135 mA g−1) and Na3·4MnV0·4Ti0·6(PO4)3/C shows an excellent capacity retention (80.88 % after 1500 cycles at 1C). Notably, the coulombic efficiency of both materials during cycling is close to 100 %, indicating that these materials have great practical application value.

AB - The recently discovered Na3MnTi(PO4)3 cathode material has an extremely high theoretical capacity, but its poor cycling performance makes it challenging to apply. In this work, a series of NASICON-type Na3+xMnVxTi1-x(PO4)3/C (x = 0, 0.1, 0.2, 0.3, 0.4, 0.5, 0.6, 0.8, 1) cathode materials were prepared by sol-gel method for sodium-ion batteries. X-ray diffraction (XRD) indicates that vanadium doping has increased the cell spacing within the material and the cell volume. From the results of X-ray photoelectron spectroscopy (XPS) and Energy dispersive X-ray spectroscopy (EDS) mapping images, it is shown that vanadium has been successfully doped into the material. Among them, the Na3·3MnV0·3Ti0·7(PO4)3/C delivers an outstanding specific capacity (121.7 mAh g−1 at 0.1C, C = 135 mA g−1) and Na3·4MnV0·4Ti0·6(PO4)3/C shows an excellent capacity retention (80.88 % after 1500 cycles at 1C). Notably, the coulombic efficiency of both materials during cycling is close to 100 %, indicating that these materials have great practical application value.

KW - Cathode material

KW - NASICON

KW - NaMnTi(PO)/C

KW - Sodium-ion batteries

UR - https://www.scopus.com/pages/publications/85192140903

U2 - 10.1016/j.matchemphys.2024.129401

DO - 10.1016/j.matchemphys.2024.129401

M3 - 文章

AN - SCOPUS:85192140903

SN - 0254-0584

VL - 320

JO - Materials Chemistry and Physics

JF - Materials Chemistry and Physics

M1 - 129401

ER -

NASICON-structure Na_3+xMnV_xTi_1-x(PO₄)₃/C cathode for sodium-ion battery with excellent cycling performance and high specific capacity

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Keywords

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