Mutual activation between ferrate and calcium sulfite for surface water pre-treatment and ultrafiltration membrane fouling control

In this work, ferrate (Fe(VI)) and calcium sulfite (CaSO₃) were combined to treat surface water for improving ultrafiltration (UF) performance. During the pre-treatment process, the Fe(VI) and CaSO₃ activated each other and a variety of active species (Fe(V), Fe(IV), [rad]OH, SO₄[rad]⁻, ¹O₂, etc.) were generated. All of the five fluorescent components were effectively eliminated to different extents. With Fe(VI)/CaSO₃ = 0.05/0.15 mM, the dissolved organic carbon and UV₂₅₄ reduced by 44.33 % and 50.56 %, respectively. After UF, these values were further decreased with the removal rate of 50.27 % and 70.79 %. In the UF stage, the terminal J/J₀ increased to 0.42 from 0.17, with the reversible and irreversible fouling decreased by 67.08 % and 79.45 % at most. The membrane pore blocking was significantly mitigated, as well as the foulants deposition on membrane surfaces was decreased to some extent. The complete blocking was altered to standard blocking and intermediate blocking, the volume when entering cake filtration was also delayed slightly. The extended Derjaguin-Landau-Verwey-Overbeek theory was employed to judge the interface fouling behavior, and the results indicated that the foulants became more hydrophilic, as well as the adhesion trend between foulants and membrane surface was weakened. Overall, these results provide a theoretical foundation for the practical application of the combined Fe(VI)/CaSO₃-UF process in surface water purification.