Multiresidue method for determination of 88 pesticides in berry fruits using solid-phase extraction and gas chromatography-mass spectrometry: Determination of 88 pesticides in berries using SPE and GC-MS

X. Yang; H. Zhang; Y. Liu; J. Wang; Y. C. Zhang; A. J. Dong; H. T. Zhao; C. H. Sun; J. Cui

doi:10.1016/j.foodchem.2011.01.024

Multiresidue method for determination of 88 pesticides in berry fruits using solid-phase extraction and gas chromatography-mass spectrometry: Determination of 88 pesticides in berries using SPE and GC-MS

X. Yang^*
, H. Zhang
, Y. Liu
, J. Wang
, Y. C. Zhang
, A. J. Dong
, H. T. Zhao
, C. H. Sun
, J. Cui

^*Corresponding author for this work

Harbin Institute of Technology
Chinese Academy of Agricultural Sciences
Heilongjiang Entry-Exit Inspection and Quarantine Bureau
The Academy of Quality Supervision and Inspection in Heilongjiang Province

Research output: Contribution to journal › Article › peer-review

157 Scopus citations

Abstract

A method using solid phase extraction (SPE) cleanup followed by gas chromatography-mass spectrometry (GC-MS) has been established for quantitative determination of 88 pesticide residues in berry fruits including raspberry, strawberry, blueberry and grape. Based on an appraisal of the characteristics of GC-MS, validation experiments were conducted for 88 pesticides. In the method, solid-phase extraction was carried out using Envi-Carb cartridge coupled with NH₂-LC cartridge with acetonitrile-toluene (3:1, v/v) as the eluted solvent. In the linear range of each pesticide, the correlation coefficient was R² ≥ 0.99. At the low, medium and high three fortification levels of 0.05-0.5 mg kg^-1, recoveries fell within 63-137%. The relative standard deviation was between 1% and 19% for all 88 pesticides. Low limits of detection (0.006-0.05 mg kg^-1) and quantification (0.02-0.15 mg kg^-1) were readily achieved with this method for all tested pesticides.

Original language	English
Pages (from-to)	855-865
Number of pages	11
Journal	Food Chemistry
Volume	127
Issue number	2
DOIs	https://doi.org/10.1016/j.foodchem.2011.01.024
State	Published - 15 Jul 2011

Keywords

Berry fruits
GC-MS
Multi-residue analysis
Pesticides
SPE
Validation

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10.1016/j.foodchem.2011.01.024

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Yang, X., Zhang, H., Liu, Y., Wang, J., Zhang, Y. C., Dong, A. J., Zhao, H. T., Sun, C. H., & Cui, J. (2011). Multiresidue method for determination of 88 pesticides in berry fruits using solid-phase extraction and gas chromatography-mass spectrometry: Determination of 88 pesticides in berries using SPE and GC-MS. Food Chemistry, 127(2), 855-865. https://doi.org/10.1016/j.foodchem.2011.01.024

@article{7909743721fb46d3afa86f3fb286ed87,

title = "Multiresidue method for determination of 88 pesticides in berry fruits using solid-phase extraction and gas chromatography-mass spectrometry: Determination of 88 pesticides in berries using SPE and GC-MS",

abstract = "A method using solid phase extraction (SPE) cleanup followed by gas chromatography-mass spectrometry (GC-MS) has been established for quantitative determination of 88 pesticide residues in berry fruits including raspberry, strawberry, blueberry and grape. Based on an appraisal of the characteristics of GC-MS, validation experiments were conducted for 88 pesticides. In the method, solid-phase extraction was carried out using Envi-Carb cartridge coupled with NH2-LC cartridge with acetonitrile-toluene (3:1, v/v) as the eluted solvent. In the linear range of each pesticide, the correlation coefficient was R2 ≥ 0.99. At the low, medium and high three fortification levels of 0.05-0.5 mg kg-1, recoveries fell within 63-137\%. The relative standard deviation was between 1\% and 19\% for all 88 pesticides. Low limits of detection (0.006-0.05 mg kg-1) and quantification (0.02-0.15 mg kg-1) were readily achieved with this method for all tested pesticides.",

keywords = "Berry fruits, GC-MS, Multi-residue analysis, Pesticides, SPE, Validation",

author = "X. Yang and H. Zhang and Y. Liu and J. Wang and Zhang, \{Y. C.\} and Dong, \{A. J.\} and Zhao, \{H. T.\} and Sun, \{C. H.\} and J. Cui",

year = "2011",

month = jul,

day = "15",

doi = "10.1016/j.foodchem.2011.01.024",

language = "英语",

volume = "127",

pages = "855--865",

journal = "Food Chemistry",

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number = "2",

}

Yang, X, Zhang, H, Liu, Y, Wang, J, Zhang, YC, Dong, AJ, Zhao, HT, Sun, CH & Cui, J 2011, 'Multiresidue method for determination of 88 pesticides in berry fruits using solid-phase extraction and gas chromatography-mass spectrometry: Determination of 88 pesticides in berries using SPE and GC-MS', Food Chemistry, vol. 127, no. 2, pp. 855-865. https://doi.org/10.1016/j.foodchem.2011.01.024

Multiresidue method for determination of 88 pesticides in berry fruits using solid-phase extraction and gas chromatography-mass spectrometry: Determination of 88 pesticides in berries using SPE and GC-MS. / Yang, X.; Zhang, H.; Liu, Y. et al.
In: Food Chemistry, Vol. 127, No. 2, 15.07.2011, p. 855-865.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Multiresidue method for determination of 88 pesticides in berry fruits using solid-phase extraction and gas chromatography-mass spectrometry

T2 - Determination of 88 pesticides in berries using SPE and GC-MS

AU - Yang, X.

AU - Zhang, H.

AU - Liu, Y.

AU - Wang, J.

AU - Zhang, Y. C.

AU - Dong, A. J.

AU - Zhao, H. T.

AU - Sun, C. H.

AU - Cui, J.

PY - 2011/7/15

Y1 - 2011/7/15

N2 - A method using solid phase extraction (SPE) cleanup followed by gas chromatography-mass spectrometry (GC-MS) has been established for quantitative determination of 88 pesticide residues in berry fruits including raspberry, strawberry, blueberry and grape. Based on an appraisal of the characteristics of GC-MS, validation experiments were conducted for 88 pesticides. In the method, solid-phase extraction was carried out using Envi-Carb cartridge coupled with NH2-LC cartridge with acetonitrile-toluene (3:1, v/v) as the eluted solvent. In the linear range of each pesticide, the correlation coefficient was R2 ≥ 0.99. At the low, medium and high three fortification levels of 0.05-0.5 mg kg-1, recoveries fell within 63-137%. The relative standard deviation was between 1% and 19% for all 88 pesticides. Low limits of detection (0.006-0.05 mg kg-1) and quantification (0.02-0.15 mg kg-1) were readily achieved with this method for all tested pesticides.

AB - A method using solid phase extraction (SPE) cleanup followed by gas chromatography-mass spectrometry (GC-MS) has been established for quantitative determination of 88 pesticide residues in berry fruits including raspberry, strawberry, blueberry and grape. Based on an appraisal of the characteristics of GC-MS, validation experiments were conducted for 88 pesticides. In the method, solid-phase extraction was carried out using Envi-Carb cartridge coupled with NH2-LC cartridge with acetonitrile-toluene (3:1, v/v) as the eluted solvent. In the linear range of each pesticide, the correlation coefficient was R2 ≥ 0.99. At the low, medium and high three fortification levels of 0.05-0.5 mg kg-1, recoveries fell within 63-137%. The relative standard deviation was between 1% and 19% for all 88 pesticides. Low limits of detection (0.006-0.05 mg kg-1) and quantification (0.02-0.15 mg kg-1) were readily achieved with this method for all tested pesticides.

KW - Berry fruits

KW - GC-MS

KW - Multi-residue analysis

KW - Pesticides

KW - SPE

KW - Validation

UR - https://www.scopus.com/pages/publications/79952316201

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DO - 10.1016/j.foodchem.2011.01.024

M3 - 文章

AN - SCOPUS:79952316201

SN - 0308-8146

VL - 127

SP - 855

EP - 865

JO - Food Chemistry

JF - Food Chemistry

IS - 2

ER -

Multiresidue method for determination of 88 pesticides in berry fruits using solid-phase extraction and gas chromatography-mass spectrometry: Determination of 88 pesticides in berries using SPE and GC-MS

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