Multifunctional luminescence properties of co-doped lanthanide metal organic frameworks

Shanghua Xing; Guang Zeng; Xiaomin Liu; Fen Yang; Zhiqiang Hao; Wei Gao; Yulin Yang; Xiuru Wang; Guanghua Li; Zhan Shi; Shouhua Feng

doi:10.1039/c5dt00249d

Multifunctional luminescence properties of co-doped lanthanide metal organic frameworks

Shanghua Xing
, Guang Zeng
, Xiaomin Liu
, Fen Yang
, Zhiqiang Hao
, Wei Gao
, Yulin Yang
, Xiuru Wang
, Guanghua Li^*
, Zhan Shi
, Shouhua Feng

^*Corresponding author for this work

Jilin University
CAS - Changchun Institute of Optics Fine Mechanics and Physics

Research output: Contribution to journal › Article › peer-review

27 Scopus citations

Abstract

Two novel lanthanide metal organic frameworks [Eu₄(bpt)₄(DMF)₂(H₂O)₆]·(DMF)₅·(H₂O)₄ (1) and [Tb₄(bpt)₄(DMF)₂(H₂O)₈]·(DMF)₅·(H₂O)₃ (2) were synthesized under hydrothermal conditions, forming a three-dimensional structure (H₃bpt = biphenyl-3,4′,5-tricarboxylate). Single crystal X-ray diffraction reveals that compounds 1 and 2 are heteromorphic and have different topologies due to the change of metal ions with different radii and coordination steric hindrance. The unique luminescence properties of Eu³⁺ and Tb³⁺ ions motivated us to dope different amounts of Tb³⁺ into a single host to obtain light tunable materials. The tunable multicolor emissions, including red, red-orange, orange, yellow and green, can be readily achieved from the doped Ln-MOFs 3-6 by increasing the concentration of Tb³⁺. In addition, compounds 5 and 6 also exhibit different temperature-dependent luminescence behaviors when the concentration of Eu³⁺ is low, generating new Ln-MOF thermometers.

Original language	English
Pages (from-to)	9588-9595
Number of pages	8
Journal	Dalton Transactions
Volume	44
Issue number	20
DOIs	https://doi.org/10.1039/c5dt00249d
State	Published - 28 May 2015
Externally published	Yes

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@article{ddabdc7acb6c402b9978583d6d7ffce2,

title = "Multifunctional luminescence properties of co-doped lanthanide metal organic frameworks",

abstract = "Two novel lanthanide metal organic frameworks [Eu4(bpt)4(DMF)2(H2O)6]·(DMF)5·(H2O)4 (1) and [Tb4(bpt)4(DMF)2(H2O)8]·(DMF)5·(H2O)3 (2) were synthesized under hydrothermal conditions, forming a three-dimensional structure (H3bpt = biphenyl-3,4′,5-tricarboxylate). Single crystal X-ray diffraction reveals that compounds 1 and 2 are heteromorphic and have different topologies due to the change of metal ions with different radii and coordination steric hindrance. The unique luminescence properties of Eu3+ and Tb3+ ions motivated us to dope different amounts of Tb3+ into a single host to obtain light tunable materials. The tunable multicolor emissions, including red, red-orange, orange, yellow and green, can be readily achieved from the doped Ln-MOFs 3-6 by increasing the concentration of Tb3+. In addition, compounds 5 and 6 also exhibit different temperature-dependent luminescence behaviors when the concentration of Eu3+ is low, generating new Ln-MOF thermometers.",

author = "Shanghua Xing and Guang Zeng and Xiaomin Liu and Fen Yang and Zhiqiang Hao and Wei Gao and Yulin Yang and Xiuru Wang and Guanghua Li and Zhan Shi and Shouhua Feng",

note = "Publisher Copyright: {\textcopyright} 2015 Royal Society of Chemistry.",

year = "2015",

month = may,

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doi = "10.1039/c5dt00249d",

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T1 - Multifunctional luminescence properties of co-doped lanthanide metal organic frameworks

AU - Xing, Shanghua

AU - Zeng, Guang

AU - Liu, Xiaomin

AU - Yang, Fen

AU - Hao, Zhiqiang

AU - Gao, Wei

AU - Yang, Yulin

AU - Wang, Xiuru

AU - Li, Guanghua

AU - Shi, Zhan

AU - Feng, Shouhua

PY - 2015/5/28

Y1 - 2015/5/28

N2 - Two novel lanthanide metal organic frameworks [Eu4(bpt)4(DMF)2(H2O)6]·(DMF)5·(H2O)4 (1) and [Tb4(bpt)4(DMF)2(H2O)8]·(DMF)5·(H2O)3 (2) were synthesized under hydrothermal conditions, forming a three-dimensional structure (H3bpt = biphenyl-3,4′,5-tricarboxylate). Single crystal X-ray diffraction reveals that compounds 1 and 2 are heteromorphic and have different topologies due to the change of metal ions with different radii and coordination steric hindrance. The unique luminescence properties of Eu3+ and Tb3+ ions motivated us to dope different amounts of Tb3+ into a single host to obtain light tunable materials. The tunable multicolor emissions, including red, red-orange, orange, yellow and green, can be readily achieved from the doped Ln-MOFs 3-6 by increasing the concentration of Tb3+. In addition, compounds 5 and 6 also exhibit different temperature-dependent luminescence behaviors when the concentration of Eu3+ is low, generating new Ln-MOF thermometers.

AB - Two novel lanthanide metal organic frameworks [Eu4(bpt)4(DMF)2(H2O)6]·(DMF)5·(H2O)4 (1) and [Tb4(bpt)4(DMF)2(H2O)8]·(DMF)5·(H2O)3 (2) were synthesized under hydrothermal conditions, forming a three-dimensional structure (H3bpt = biphenyl-3,4′,5-tricarboxylate). Single crystal X-ray diffraction reveals that compounds 1 and 2 are heteromorphic and have different topologies due to the change of metal ions with different radii and coordination steric hindrance. The unique luminescence properties of Eu3+ and Tb3+ ions motivated us to dope different amounts of Tb3+ into a single host to obtain light tunable materials. The tunable multicolor emissions, including red, red-orange, orange, yellow and green, can be readily achieved from the doped Ln-MOFs 3-6 by increasing the concentration of Tb3+. In addition, compounds 5 and 6 also exhibit different temperature-dependent luminescence behaviors when the concentration of Eu3+ is low, generating new Ln-MOF thermometers.

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U2 - 10.1039/c5dt00249d

DO - 10.1039/c5dt00249d

M3 - 文章

AN - SCOPUS:84930617218

SN - 1477-9226

VL - 44

SP - 9588

EP - 9595

JO - Dalton Transactions

JF - Dalton Transactions

IS - 20

ER -

Multifunctional luminescence properties of co-doped lanthanide metal organic frameworks

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