Mott Schottky CoS_x-MoO_x@NF heterojunctions electrode for H₂ production and urea-rich wastewater purification

The sluggish kinetics of oxygen evolution reaction (OER) is the bottleneck of alkaline water electrolysis. The urea oxidation reaction (UOR) with much faster kinetics was to replace OER. To further promote UOR, a heterojunction structure assembled of CoS_x and MoO_x was established, and then its superior catalytic activity was predicted by DFT calculation. After that, an ultra-thin CoS_x-MoO_x@nickel foam (CoS_x-MoO_x@NF) electrode with a Mott-Schottky structure was prepared via a facile hydrothermal method, followed by a low-temperature vulcanization. Results highlighted CoS_x-MoO_x@NF electrode presented a superior performance toward UOR, OER, and H₂ evolution reaction (HER). Notably, it exhibited excellent electrocatalytic performance for OER (1.32 V vs. RHE, 10 mA cm⁻²), UOR (1.305 V vs. RHE, 10 mA cm⁻²), and urea-assisted overall water splitting with a low voltage (1.38 V, 10 mA cm⁻²) when CoS_x-MoO_x@NF electrode served as both anode and cathode. It is promising to use CoS_x-MoO_x@NF in an electrochemical system integrated with H₂ generation and urea-rich wastewater purification.