{Mo24Fe12} macrocycles: Anion templation with large polyoxometalate guests

Xikui Fang; Laura Hansen; Fadi Haso; Panchao Yin; Abhishek Pandey; Larry Engelhardt; Igor Slowing; Tao Li; Tianbo Liu; Marshall Luban; David C. Johnston

doi:10.1002/anie.201304887

{Mo₂₄Fe₁₂} macrocycles: Anion templation with large polyoxometalate guests

Xikui Fang^*
, Laura Hansen
, Fadi Haso
, Panchao Yin
, Abhishek Pandey
, Larry Engelhardt
, Igor Slowing
, Tao Li
, Tianbo Liu
, Marshall Luban
, David C. Johnston

^*Corresponding author for this work

Ames Laboratory
University of Akron
Francis Marion University
United States Department of Energy

Research output: Contribution to journal › Article › peer-review

51 Scopus citations

Abstract

POM and circumstance: Nanometer-sized polyoxometalates (POMs) bring a new direction to anion-templated supramolecular chemistry. The Keggin (left) and Dawson-type (right) polyoxoanions direct the assembly of giant metallomacrocycles through an array of weak hydrogen-bonding interactions. The concerted action of multiple hydrogen bonds keeps the templating guests embedded within the hosts, even in the solution state.

Original language	English
Pages (from-to)	10500-10504
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	52
Issue number	40
DOIs	https://doi.org/10.1002/anie.201304887
State	Published - 27 Sep 2013
Externally published	Yes

Keywords

anion templation
hydrogen bonds
magnetism
polyoxometalates
supramolecular chemistry

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10.1002/anie.201304887

Cite this

@article{3896200021064ab782f55381e878b530,

title = "\{Mo24Fe12\} macrocycles: Anion templation with large polyoxometalate guests",

abstract = "POM and circumstance: Nanometer-sized polyoxometalates (POMs) bring a new direction to anion-templated supramolecular chemistry. The Keggin (left) and Dawson-type (right) polyoxoanions direct the assembly of giant metallomacrocycles through an array of weak hydrogen-bonding interactions. The concerted action of multiple hydrogen bonds keeps the templating guests embedded within the hosts, even in the solution state.",

keywords = "anion templation, hydrogen bonds, magnetism, polyoxometalates, supramolecular chemistry",

author = "Xikui Fang and Laura Hansen and Fadi Haso and Panchao Yin and Abhishek Pandey and Larry Engelhardt and Igor Slowing and Tao Li and Tianbo Liu and Marshall Luban and Johnston, \{David C.\}",

year = "2013",

month = sep,

day = "27",

doi = "10.1002/anie.201304887",

language = "英语",

volume = "52",

pages = "10500--10504",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

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}

TY - JOUR

T1 - {Mo24Fe12} macrocycles

T2 - Anion templation with large polyoxometalate guests

AU - Fang, Xikui

AU - Hansen, Laura

AU - Haso, Fadi

AU - Yin, Panchao

AU - Pandey, Abhishek

AU - Engelhardt, Larry

AU - Slowing, Igor

AU - Li, Tao

AU - Liu, Tianbo

AU - Luban, Marshall

AU - Johnston, David C.

PY - 2013/9/27

Y1 - 2013/9/27

N2 - POM and circumstance: Nanometer-sized polyoxometalates (POMs) bring a new direction to anion-templated supramolecular chemistry. The Keggin (left) and Dawson-type (right) polyoxoanions direct the assembly of giant metallomacrocycles through an array of weak hydrogen-bonding interactions. The concerted action of multiple hydrogen bonds keeps the templating guests embedded within the hosts, even in the solution state.

AB - POM and circumstance: Nanometer-sized polyoxometalates (POMs) bring a new direction to anion-templated supramolecular chemistry. The Keggin (left) and Dawson-type (right) polyoxoanions direct the assembly of giant metallomacrocycles through an array of weak hydrogen-bonding interactions. The concerted action of multiple hydrogen bonds keeps the templating guests embedded within the hosts, even in the solution state.

KW - anion templation

KW - hydrogen bonds

KW - magnetism

KW - polyoxometalates

KW - supramolecular chemistry

UR - https://www.scopus.com/pages/publications/84884874909

U2 - 10.1002/anie.201304887

DO - 10.1002/anie.201304887

M3 - 文章

AN - SCOPUS:84884874909

SN - 1433-7851

VL - 52

SP - 10500

EP - 10504

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 40

ER -

{Mo₂₄Fe₁₂} macrocycles: Anion templation with large polyoxometalate guests

Abstract

Keywords

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