Molecular growth of a core-shell polyoxometalate

Xikui Fang; Paul Kögerler; Yuji Furukawa; Manfred Speldrich; Marshall Luban

doi:10.1002/anie.201008225

Molecular growth of a core-shell polyoxometalate

Xikui Fang^*
, Paul Kögerler
, Yuji Furukawa
, Manfred Speldrich
, Marshall Luban

^*Corresponding author for this work

Ames Laboratory
RWTH Aachen University

Research output: Contribution to journal › Article › peer-review

145 Scopus citations

Abstract

In a nutshell: A 4.3 nm core-shell aggregate of 16 polyoxotungstate building units (see picture of the W/Mn skeleton) delineates the upper limit for structural complexity in molecular metal oxide cluster chemistry to date. This structure is defined by a backbone network of dual Mn-O=W bridges; a retroanalysis of their formation suggests the importance of templation and kinetic control in the self-assembly of the {Mn^III₄₀W ^VI₂₂₄} polyanion.

Original language	English
Pages (from-to)	5212-5216
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	50
Issue number	22
DOIs	https://doi.org/10.1002/anie.201008225
State	Published - 23 May 2011
Externally published	Yes

Keywords

cluster compounds
magnetic properties
polyoxometalates
template synthesis

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10.1002/anie.201008225

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title = "Molecular growth of a core-shell polyoxometalate",

abstract = "In a nutshell: A 4.3 nm core-shell aggregate of 16 polyoxotungstate building units (see picture of the W/Mn skeleton) delineates the upper limit for structural complexity in molecular metal oxide cluster chemistry to date. This structure is defined by a backbone network of dual Mn-O=W bridges; a retroanalysis of their formation suggests the importance of templation and kinetic control in the self-assembly of the \{MnIII40W VI224\} polyanion.",

keywords = "cluster compounds, magnetic properties, polyoxometalates, template synthesis",

author = "Xikui Fang and Paul K{\"o}gerler and Yuji Furukawa and Manfred Speldrich and Marshall Luban",

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doi = "10.1002/anie.201008225",

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AU - Fang, Xikui

AU - Kögerler, Paul

AU - Furukawa, Yuji

AU - Speldrich, Manfred

AU - Luban, Marshall

PY - 2011/5/23

Y1 - 2011/5/23

N2 - In a nutshell: A 4.3 nm core-shell aggregate of 16 polyoxotungstate building units (see picture of the W/Mn skeleton) delineates the upper limit for structural complexity in molecular metal oxide cluster chemistry to date. This structure is defined by a backbone network of dual Mn-O=W bridges; a retroanalysis of their formation suggests the importance of templation and kinetic control in the self-assembly of the {MnIII40W VI224} polyanion.

AB - In a nutshell: A 4.3 nm core-shell aggregate of 16 polyoxotungstate building units (see picture of the W/Mn skeleton) delineates the upper limit for structural complexity in molecular metal oxide cluster chemistry to date. This structure is defined by a backbone network of dual Mn-O=W bridges; a retroanalysis of their formation suggests the importance of templation and kinetic control in the self-assembly of the {MnIII40W VI224} polyanion.

KW - cluster compounds

KW - magnetic properties

KW - polyoxometalates

KW - template synthesis

UR - https://www.scopus.com/pages/publications/79956126807

U2 - 10.1002/anie.201008225

DO - 10.1002/anie.201008225

M3 - 文章

AN - SCOPUS:79956126807

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 22

ER -

Molecular growth of a core-shell polyoxometalate

Abstract

Keywords

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