(Mn14W48) aggregate: The perspective of isopolyanions as ligands

Xikui Fang; Marshall Luban

doi:10.1039/c0cc04403b

(Mn₁₄W₄₈) aggregate: The perspective of isopolyanions as ligands

Xikui Fang^*
, Marshall Luban

^*Corresponding author for this work

Ames Laboratory

Research output: Contribution to journal › Article › peer-review

38 Scopus citations

Abstract

The assembly of a tetradeca-manganese magnetic cluster [Mn₁₄W₄₈O₁₉₂H₂₀]²⁶⁻, containing two high spin Mn₇ cores and supported exclusively by isopolytungstate ligands, demonstrates the promising perspective of using “defect” isopolyanions as ligands/synthons to construct large aggregated structures and model the surface deposition of molecular magnets.

Original language	English
Pages (from-to)	3066-3068
Number of pages	3
Journal	Chemical Communications
Volume	47
Issue number	11
DOIs	https://doi.org/10.1039/c0cc04403b
State	Published - 1 Mar 2011
Externally published	Yes

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title = "(Mn14W48) aggregate: The perspective of isopolyanions as ligands",

abstract = "The assembly of a tetradeca-manganese magnetic cluster [Mn14W48O192H20]26−, containing two high spin Mn7 cores and supported exclusively by isopolytungstate ligands, demonstrates the promising perspective of using “defect” isopolyanions as ligands/synthons to construct large aggregated structures and model the surface deposition of molecular magnets.",

author = "Xikui Fang and Marshall Luban",

year = "2011",

month = mar,

day = "1",

doi = "10.1039/c0cc04403b",

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volume = "47",

pages = "3066--3068",

journal = "Chemical Communications",

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T1 - (Mn14W48) aggregate

T2 - The perspective of isopolyanions as ligands

AU - Fang, Xikui

AU - Luban, Marshall

PY - 2011/3/1

Y1 - 2011/3/1

N2 - The assembly of a tetradeca-manganese magnetic cluster [Mn14W48O192H20]26−, containing two high spin Mn7 cores and supported exclusively by isopolytungstate ligands, demonstrates the promising perspective of using “defect” isopolyanions as ligands/synthons to construct large aggregated structures and model the surface deposition of molecular magnets.

AB - The assembly of a tetradeca-manganese magnetic cluster [Mn14W48O192H20]26−, containing two high spin Mn7 cores and supported exclusively by isopolytungstate ligands, demonstrates the promising perspective of using “defect” isopolyanions as ligands/synthons to construct large aggregated structures and model the surface deposition of molecular magnets.

UR - https://www.scopus.com/pages/publications/79952826862

U2 - 10.1039/c0cc04403b

DO - 10.1039/c0cc04403b

M3 - 文章

AN - SCOPUS:79952826862

SN - 1359-7345

VL - 47

SP - 3066

EP - 3068

JO - Chemical Communications

JF - Chemical Communications

IS - 11

ER -

(Mn₁₄W₄₈) aggregate: The perspective of isopolyanions as ligands

Abstract

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