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Low temperature direct metal bonding by self assembled monolayers

  • Xiaofang Ang*
  • , Li Cheong Chin
  • , Guo Ge Zhang
  • , Jun Wei
  • , Zhong Chen
  • , Chee Cheong Wong
  • *Corresponding author for this work

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

Abstract

Elevated bonding temperature for interconnection deteriorates the reliability of both the device and the interconnect; hence the imperative for developing low temperature bonding methods. This study investigates the feasibility of using self-assembled monolayers (SAMs) to assist direct gold-gold (Au-Au) thermocompression bonding. This involves a simple molecular self-assembly process whereby a monolayer of alkyl chains with a sulfur end group is attached to the gold surface prior to bonding. Using this method, we have achieved Au-Au bonding at a bonding temperature below 100°C, a significant reduction compared to the conventional bonding temperatures of above 150°C We attribute this temperature reduction to two properties of SAMs - (1) surface passivation of the Au surface that precludes adsorption of surface contaminants, and (2) the easy displacement of SAMs through thermal desorption just before bonding occurs. This SAMs-assisted bonding mechanism is supported by X-ray photoelectron spectroscopy (XPS) and surface plasmon resonance (SPR) results.

Original languageEnglish
Title of host publicationMaterials, Processes, Integration and Reliability in Advanced Interconnects for Micro- and Nanoelectronics
PublisherMaterials Research Society
Pages287-293
Number of pages7
ISBN (Print)9781558999503
DOIs
StatePublished - 2007
Externally publishedYes
Event2007 MRS Spring Meeting - San Francisco, CA, United States
Duration: 10 Apr 200712 Apr 2007

Publication series

NameMaterials Research Society Symposium Proceedings
Volume990
ISSN (Print)0272-9172

Conference

Conference2007 MRS Spring Meeting
Country/TerritoryUnited States
CitySan Francisco, CA
Period10/04/0712/04/07

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