Low intensity magnetic separation of vivianite induced by iron reduction on the surface layer of Fe(III)[Fe(0)] iron scrap

Phosphorus (P) recovery through vivianite, which can be found in activated sludge, surplus sludge and digested sludge in the wastewater treatment plants (WWTPs), is a cutting-edge and efficient technology in recent years. However, how to generate and separate vivianite in an effective and economical way with natural iron oxide mineral was still the bottleneck to limit its application. Therefore, in this study, the P recovery efficiency (E_P) and vivianite recovery efficiency (E_V) of three kinds of iron oxides were investigated. We found that the E_P of Akaganeite was 1.83 times and 4.88 times higher than that of Geothite and Hematite. Simultaneously, E_V of Akaganeite was 1.64 times and 2.88 times higher than that of Geothite and Hematite. As Akaganeite is main component of rust on the surface of iron scrap, we used Fe(III)[Fe(0)] iron scrap with Fe(0) inside and Akaganeite outside as iron source and electron acceptor for vivianite production and magnetic separation. At the terminal stage (60 day), the P recovery efficiency with 20 g/L Fe(III)[Fe(0)] iron scrap was 36%. Applying a magnetical separator with magnetic field intensity of 0.3 T, vivianite was separated from the solution efficiently and immediately. Low intensity magnetic separation with iron scrap would recover P resources economically with the total cost to be $2.23/kg P, which was much lower than recovery via iron salts. Besides, it provided a significant insights into the P recovery and vivianite separation by reusing Fe waste during wastewater treatment.