Li4Cs3B7O14: Synthesis, crystal structure, and optical properties

Yun Yang; Shilie Pan; Hongyi Li; Jian Han; Zhaohui Chen; Wenwu Zhao; Zhongxiang Zhou

doi:10.1021/ic102214q

Li₄Cs₃B₇O₁₄: Synthesis, crystal structure, and optical properties

Yun Yang
, Shilie Pan^*
, Hongyi Li
, Jian Han
, Zhaohui Chen
, Wenwu Zhao
, Zhongxiang Zhou

^*Corresponding author for this work

Xinjiang Technical Institute of Physics and Chemistry
University of Chinese Academy of Sciences

Research output: Contribution to journal › Article › peer-review

82 Scopus citations

Abstract

A new noncentrosymmetric polyborate, Li₄Cs₃B ₇ O₁₄, has been synthesized using the conventional solid state reaction method. It crystallizes in the trigonal space group P3 ₁21 (No 152) with unit cell parameters of a = 6.9313(6) Å, c = 26.799(3) Å and Z = 3. The new structure contains an infinite three-dimensional matrix that is built from B₇O₁₄ building blocks rarely found in anhydrous borate compounds and LiO_n (n = 4, 5), CsO_n (n = 9, 10) polyhedra. The optical characterization of the compound indicates that the compound is phase matchable, and the UV cutoff edge is below 190 nm. IR spectroscopy, thermal analysis, and second-harmonic generation were also performed on the reported material.

Original language	English
Pages (from-to)	2415-2419
Number of pages	5
Journal	Inorganic Chemistry
Volume	50
Issue number	6
DOIs	https://doi.org/10.1021/ic102214q
State	Published - 21 Mar 2011
Externally published	Yes

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@article{e6434d6d236d4cd69e353734bba132e4,

title = "Li4Cs3B7O14: Synthesis, crystal structure, and optical properties",

abstract = "A new noncentrosymmetric polyborate, Li4Cs3B 7 O14, has been synthesized using the conventional solid state reaction method. It crystallizes in the trigonal space group P3 121 (No 152) with unit cell parameters of a = 6.9313(6) {\AA}, c = 26.799(3) {\AA} and Z = 3. The new structure contains an infinite three-dimensional matrix that is built from B7O14 building blocks rarely found in anhydrous borate compounds and LiOn (n = 4, 5), CsOn (n = 9, 10) polyhedra. The optical characterization of the compound indicates that the compound is phase matchable, and the UV cutoff edge is below 190 nm. IR spectroscopy, thermal analysis, and second-harmonic generation were also performed on the reported material.",

author = "Yun Yang and Shilie Pan and Hongyi Li and Jian Han and Zhaohui Chen and Wenwu Zhao and Zhongxiang Zhou",

year = "2011",

month = mar,

day = "21",

doi = "10.1021/ic102214q",

language = "英语",

volume = "50",

pages = "2415--2419",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

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TY - JOUR

T1 - Li4Cs3B7O14

T2 - Synthesis, crystal structure, and optical properties

AU - Yang, Yun

AU - Pan, Shilie

AU - Li, Hongyi

AU - Han, Jian

AU - Chen, Zhaohui

AU - Zhao, Wenwu

AU - Zhou, Zhongxiang

PY - 2011/3/21

Y1 - 2011/3/21

N2 - A new noncentrosymmetric polyborate, Li4Cs3B 7 O14, has been synthesized using the conventional solid state reaction method. It crystallizes in the trigonal space group P3 121 (No 152) with unit cell parameters of a = 6.9313(6) Å, c = 26.799(3) Å and Z = 3. The new structure contains an infinite three-dimensional matrix that is built from B7O14 building blocks rarely found in anhydrous borate compounds and LiOn (n = 4, 5), CsOn (n = 9, 10) polyhedra. The optical characterization of the compound indicates that the compound is phase matchable, and the UV cutoff edge is below 190 nm. IR spectroscopy, thermal analysis, and second-harmonic generation were also performed on the reported material.

AB - A new noncentrosymmetric polyborate, Li4Cs3B 7 O14, has been synthesized using the conventional solid state reaction method. It crystallizes in the trigonal space group P3 121 (No 152) with unit cell parameters of a = 6.9313(6) Å, c = 26.799(3) Å and Z = 3. The new structure contains an infinite three-dimensional matrix that is built from B7O14 building blocks rarely found in anhydrous borate compounds and LiOn (n = 4, 5), CsOn (n = 9, 10) polyhedra. The optical characterization of the compound indicates that the compound is phase matchable, and the UV cutoff edge is below 190 nm. IR spectroscopy, thermal analysis, and second-harmonic generation were also performed on the reported material.

UR - https://www.scopus.com/pages/publications/79954451623

U2 - 10.1021/ic102214q

DO - 10.1021/ic102214q

M3 - 文章

AN - SCOPUS:79954451623

SN - 0020-1669

VL - 50

SP - 2415

EP - 2419

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 6

ER -

Li₄Cs₃B₇O₁₄: Synthesis, crystal structure, and optical properties

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