Large Electro-Optic Coefficient in Single-Domain PIN-PMN-PT Single Crystal

Xin Liu; Fangbing Li; Jingwei Li; Peng Tan; Jing Lei; Weigang Zhao; Kexin Song; Huaibin Zheng; Hao Tian; Fei Li; Xiaoyong Wei; Zhuo Xu

doi:10.1002/adom.202400885

Large Electro-Optic Coefficient in Single-Domain PIN-PMN-PT Single Crystal

Xin Liu
, Fangbing Li
, Jingwei Li
, Peng Tan
, Jing Lei
, Weigang Zhao
, Kexin Song
, Huaibin Zheng
, Hao Tian
, Fei Li^*
, Xiaoyong Wei^*
, Zhuo Xu^*

^*Corresponding author for this work

Xi'an Jiaotong University
School of Physics, Harbin Institute of Technology
China Aerospace Science and Technology Corporation

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

Due to the excellent shear-mode piezoelectric properties, single-domain tetragonal Pb(In_1/2Nb_1/2)O₃-Pb(Mg_1/3Nb_2/3)O₃-PbTiO₃ (PIN-PMN-PT) crystals are believed to possess giant electro-optic (EO) coefficients as well. However, the EO properties of single-domain PIN-PMN-PT crystals have not been systematically studied because of the difficulties in the single-domain sample preparation. Here, by this newly developed orthogonal poling method, single-domain tetragonal PIN-PMN-39PT crystals are successfully obtained by poling the sample along the non-spontaneous polarization direction at room temperature. Optical grade crystal with good transparency and high EO coefficient component γ₅₁ (≈2800 pm V⁻¹) is achieved. The orientation dependence of the EO coefficient is analyzed based on the measured full matrix of the EO coefficients. This work confirms the giant EO performance of domain-engineered PIN-PMN-PT single crystals mainly comes from the contribution of EO coefficient component γ₅₁ of single domain crystal other than the domain wall or domain switching related mechanisms.

Original language	English
Article number	2400885
Journal	Advanced Optical Materials
Volume	12
Issue number	33
DOIs	https://doi.org/10.1002/adom.202400885
State	Published - 25 Nov 2024
Externally published	Yes

Keywords

domain engineering
electro-optic
ferroelectrics
single crystal

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10.1002/adom.202400885

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title = "Large Electro-Optic Coefficient in Single-Domain PIN-PMN-PT Single Crystal",

abstract = "Due to the excellent shear-mode piezoelectric properties, single-domain tetragonal Pb(In1/2Nb1/2)O3-Pb(Mg1/3Nb2/3)O3-PbTiO3 (PIN-PMN-PT) crystals are believed to possess giant electro-optic (EO) coefficients as well. However, the EO properties of single-domain PIN-PMN-PT crystals have not been systematically studied because of the difficulties in the single-domain sample preparation. Here, by this newly developed orthogonal poling method, single-domain tetragonal PIN-PMN-39PT crystals are successfully obtained by poling the sample along the non-spontaneous polarization direction at room temperature. Optical grade crystal with good transparency and high EO coefficient component γ51 (≈2800 pm V−1) is achieved. The orientation dependence of the EO coefficient is analyzed based on the measured full matrix of the EO coefficients. This work confirms the giant EO performance of domain-engineered PIN-PMN-PT single crystals mainly comes from the contribution of EO coefficient component γ51 of single domain crystal other than the domain wall or domain switching related mechanisms.",

keywords = "domain engineering, electro-optic, ferroelectrics, single crystal",

author = "Xin Liu and Fangbing Li and Jingwei Li and Peng Tan and Jing Lei and Weigang Zhao and Kexin Song and Huaibin Zheng and Hao Tian and Fei Li and Xiaoyong Wei and Zhuo Xu",

note = "Publisher Copyright: {\textcopyright} 2024 Wiley-VCH GmbH.",

year = "2024",

month = nov,

day = "25",

doi = "10.1002/adom.202400885",

language = "英语",

volume = "12",

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issn = "2195-1071",

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TY - JOUR

T1 - Large Electro-Optic Coefficient in Single-Domain PIN-PMN-PT Single Crystal

AU - Liu, Xin

AU - Li, Fangbing

AU - Li, Jingwei

AU - Tan, Peng

AU - Lei, Jing

AU - Zhao, Weigang

AU - Song, Kexin

AU - Zheng, Huaibin

AU - Tian, Hao

AU - Li, Fei

AU - Wei, Xiaoyong

AU - Xu, Zhuo

PY - 2024/11/25

Y1 - 2024/11/25

N2 - Due to the excellent shear-mode piezoelectric properties, single-domain tetragonal Pb(In1/2Nb1/2)O3-Pb(Mg1/3Nb2/3)O3-PbTiO3 (PIN-PMN-PT) crystals are believed to possess giant electro-optic (EO) coefficients as well. However, the EO properties of single-domain PIN-PMN-PT crystals have not been systematically studied because of the difficulties in the single-domain sample preparation. Here, by this newly developed orthogonal poling method, single-domain tetragonal PIN-PMN-39PT crystals are successfully obtained by poling the sample along the non-spontaneous polarization direction at room temperature. Optical grade crystal with good transparency and high EO coefficient component γ51 (≈2800 pm V−1) is achieved. The orientation dependence of the EO coefficient is analyzed based on the measured full matrix of the EO coefficients. This work confirms the giant EO performance of domain-engineered PIN-PMN-PT single crystals mainly comes from the contribution of EO coefficient component γ51 of single domain crystal other than the domain wall or domain switching related mechanisms.

AB - Due to the excellent shear-mode piezoelectric properties, single-domain tetragonal Pb(In1/2Nb1/2)O3-Pb(Mg1/3Nb2/3)O3-PbTiO3 (PIN-PMN-PT) crystals are believed to possess giant electro-optic (EO) coefficients as well. However, the EO properties of single-domain PIN-PMN-PT crystals have not been systematically studied because of the difficulties in the single-domain sample preparation. Here, by this newly developed orthogonal poling method, single-domain tetragonal PIN-PMN-39PT crystals are successfully obtained by poling the sample along the non-spontaneous polarization direction at room temperature. Optical grade crystal with good transparency and high EO coefficient component γ51 (≈2800 pm V−1) is achieved. The orientation dependence of the EO coefficient is analyzed based on the measured full matrix of the EO coefficients. This work confirms the giant EO performance of domain-engineered PIN-PMN-PT single crystals mainly comes from the contribution of EO coefficient component γ51 of single domain crystal other than the domain wall or domain switching related mechanisms.

KW - domain engineering

KW - electro-optic

KW - ferroelectrics

KW - single crystal

UR - https://www.scopus.com/pages/publications/85198415536

U2 - 10.1002/adom.202400885

DO - 10.1002/adom.202400885

M3 - 文章

AN - SCOPUS:85198415536

SN - 2195-1071

VL - 12

JO - Advanced Optical Materials

JF - Advanced Optical Materials

IS - 33

M1 - 2400885

ER -

Large Electro-Optic Coefficient in Single-Domain PIN-PMN-PT Single Crystal

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