Iron carbide and nitride via a flexible route: Synthesis, structure and magnetic properties

Peng Zhang; Xiaobai Wang; Wei Wang; Xiang Lei; Hua Yang

doi:10.1039/c5ra00336a

Iron carbide and nitride via a flexible route: Synthesis, structure and magnetic properties

Peng Zhang
, Xiaobai Wang
, Wei Wang
, Xiang Lei
, Hua Yang^*

^*Corresponding author for this work

College of Chemistry

Research output: Contribution to journal › Article › peer-review

20 Scopus citations

Abstract

Single-phase Fe₄N and Fe₃C have been controllably synthesized from a coordination precursor by adjusting the molar ratio of hexamethylenetetramine to ferric chloride hexahydrate, both presenting good paramagnetic behavior, with maximum magnetizations that can reach 150.51 and 53.03 emu g^-1 up to 17.5 kOe, respectively. The magnetic properties of Fe₃C can be adjusted by the molar ratio of hexamethylenetetramine. Moreover, the structure, components and the possible mechanism were investigated carefully.

Original language	English
Pages (from-to)	21670-21674
Number of pages	5
Journal	RSC Advances
Volume	5
Issue number	28
DOIs	https://doi.org/10.1039/c5ra00336a
State	Published - 2015
Externally published	Yes

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title = "Iron carbide and nitride via a flexible route: Synthesis, structure and magnetic properties",

abstract = "Single-phase Fe4N and Fe3C have been controllably synthesized from a coordination precursor by adjusting the molar ratio of hexamethylenetetramine to ferric chloride hexahydrate, both presenting good paramagnetic behavior, with maximum magnetizations that can reach 150.51 and 53.03 emu g-1 up to 17.5 kOe, respectively. The magnetic properties of Fe3C can be adjusted by the molar ratio of hexamethylenetetramine. Moreover, the structure, components and the possible mechanism were investigated carefully.",

author = "Peng Zhang and Xiaobai Wang and Wei Wang and Xiang Lei and Hua Yang",

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year = "2015",

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T1 - Iron carbide and nitride via a flexible route

T2 - Synthesis, structure and magnetic properties

AU - Zhang, Peng

AU - Wang, Xiaobai

AU - Wang, Wei

AU - Lei, Xiang

AU - Yang, Hua

PY - 2015

Y1 - 2015

N2 - Single-phase Fe4N and Fe3C have been controllably synthesized from a coordination precursor by adjusting the molar ratio of hexamethylenetetramine to ferric chloride hexahydrate, both presenting good paramagnetic behavior, with maximum magnetizations that can reach 150.51 and 53.03 emu g-1 up to 17.5 kOe, respectively. The magnetic properties of Fe3C can be adjusted by the molar ratio of hexamethylenetetramine. Moreover, the structure, components and the possible mechanism were investigated carefully.

AB - Single-phase Fe4N and Fe3C have been controllably synthesized from a coordination precursor by adjusting the molar ratio of hexamethylenetetramine to ferric chloride hexahydrate, both presenting good paramagnetic behavior, with maximum magnetizations that can reach 150.51 and 53.03 emu g-1 up to 17.5 kOe, respectively. The magnetic properties of Fe3C can be adjusted by the molar ratio of hexamethylenetetramine. Moreover, the structure, components and the possible mechanism were investigated carefully.

UR - https://www.scopus.com/pages/publications/84923930757

U2 - 10.1039/c5ra00336a

DO - 10.1039/c5ra00336a

M3 - 文章

AN - SCOPUS:84923930757

SN - 2046-2069

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SP - 21670

EP - 21674

JO - RSC Advances

JF - RSC Advances

IS - 28

ER -

Iron carbide and nitride via a flexible route: Synthesis, structure and magnetic properties

Abstract

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