Investigations on a new 2-D Co(II) framework with reversed triangular-prism shaped units

Qing Chang; Xiang Ru Meng; Ying Lin Song; Hong Wei Hou

doi:10.1002/cjoc.200590725

Investigations on a new 2-D Co(II) framework with reversed triangular-prism shaped units

Qing Chang^*
, Xiang Ru Meng
, Ying Lin Song
, Hong Wei Hou

^*Corresponding author for this work

School of Physics

Heilongjiang University
Harbin Institute of Technology
Zhengzhou University

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

Treatment of 1,1′-(1,4-butylene)bis-1H-benzimidazole) (bbbi) with CoSO₄·7H₂O afforded a novel metal-organic polymer [Co(bbbi)_1.5(SO₄)]_n (1), where the central Co(II) ions are bridged by bbbi ligands, leading to a two-dimensional layer with reversed triangular-prism shaped units. Each reversed triangular-prism shaped unit is made up of six bbbi ligands and six cobalt atoms. Thermal analysis revealed that polymer 1 was stable below 147 °C, and oxidized and decomposed to Co₂O₃ at about 787 °C, and to CoO at about 914 °C.

Original language	English
Pages (from-to)	725-728
Number of pages	4
Journal	Chinese Journal of Chemistry
Volume	23
Issue number	6
DOIs	https://doi.org/10.1002/cjoc.200590725
State	Published - Jun 2005

Keywords

Cobalt(II)
Crystal structure
Metal-organic polymer
Thermal analysis

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10.1002/cjoc.200590725

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title = "Investigations on a new 2-D Co(II) framework with reversed triangular-prism shaped units",

abstract = "Treatment of 1,1′-(1,4-butylene)bis-1H-benzimidazole) (bbbi) with CoSO4·7H2O afforded a novel metal-organic polymer [Co(bbbi)1.5(SO4)]n (1), where the central Co(II) ions are bridged by bbbi ligands, leading to a two-dimensional layer with reversed triangular-prism shaped units. Each reversed triangular-prism shaped unit is made up of six bbbi ligands and six cobalt atoms. Thermal analysis revealed that polymer 1 was stable below 147 °C, and oxidized and decomposed to Co2O3 at about 787 °C, and to CoO at about 914 °C.",

keywords = "Cobalt(II), Crystal structure, Metal-organic polymer, Thermal analysis",

author = "Qing Chang and Meng, \{Xiang Ru\} and Song, \{Ying Lin\} and Hou, \{Hong Wei\}",

year = "2005",

month = jun,

doi = "10.1002/cjoc.200590725",

language = "英语",

volume = "23",

pages = "725--728",

journal = "Chinese Journal of Chemistry",

issn = "1001-604X",

publisher = "John Wiley and Sons Inc",

number = "6",

}

TY - JOUR

T1 - Investigations on a new 2-D Co(II) framework with reversed triangular-prism shaped units

AU - Chang, Qing

AU - Meng, Xiang Ru

AU - Song, Ying Lin

AU - Hou, Hong Wei

PY - 2005/6

Y1 - 2005/6

N2 - Treatment of 1,1′-(1,4-butylene)bis-1H-benzimidazole) (bbbi) with CoSO4·7H2O afforded a novel metal-organic polymer [Co(bbbi)1.5(SO4)]n (1), where the central Co(II) ions are bridged by bbbi ligands, leading to a two-dimensional layer with reversed triangular-prism shaped units. Each reversed triangular-prism shaped unit is made up of six bbbi ligands and six cobalt atoms. Thermal analysis revealed that polymer 1 was stable below 147 °C, and oxidized and decomposed to Co2O3 at about 787 °C, and to CoO at about 914 °C.

AB - Treatment of 1,1′-(1,4-butylene)bis-1H-benzimidazole) (bbbi) with CoSO4·7H2O afforded a novel metal-organic polymer [Co(bbbi)1.5(SO4)]n (1), where the central Co(II) ions are bridged by bbbi ligands, leading to a two-dimensional layer with reversed triangular-prism shaped units. Each reversed triangular-prism shaped unit is made up of six bbbi ligands and six cobalt atoms. Thermal analysis revealed that polymer 1 was stable below 147 °C, and oxidized and decomposed to Co2O3 at about 787 °C, and to CoO at about 914 °C.

KW - Cobalt(II)

KW - Crystal structure

KW - Metal-organic polymer

KW - Thermal analysis

UR - https://www.scopus.com/pages/publications/20044394754

U2 - 10.1002/cjoc.200590725

DO - 10.1002/cjoc.200590725

M3 - 文章

AN - SCOPUS:20044394754

SN - 1001-604X

VL - 23

SP - 725

EP - 728

JO - Chinese Journal of Chemistry

JF - Chinese Journal of Chemistry

IS - 6

ER -

Investigations on a new 2-D Co(II) framework with reversed triangular-prism shaped units

Abstract

Keywords

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