Interfacial enhancement of carbon fiber composites by growing TiO                         2                          nanowires onto amine-based functionalized carbon fiber surface in supercritical water

Lichun Ma; Nan Li; Guangshun Wu; Guojun Song; Xiaoru Li; Ping Han; Gang Wang; Yudong Huang

doi:10.1016/j.apsusc.2017.10.036

Interfacial enhancement of carbon fiber composites by growing TiO ₂ nanowires onto amine-based functionalized carbon fiber surface in supercritical water

Lichun Ma^*
, Nan Li
, Guangshun Wu
, Guojun Song
, Xiaoru Li
, Ping Han
, Gang Wang
, Yudong Huang

^*Corresponding author for this work

Qingdao University
Dalian University of Technology
Ludong University
School of Chemistry and Chemical Engineering, Harbin Institute of Technology

Research output: Contribution to journal › Article › peer-review

180 Scopus citations

Abstract

A novel amine-based functionalization method was developed to improve the interfacial adhesion between TiO ₂ NWs and CFs in supercritical water. The microstructure, morphology and mechanical properties of CFs were investigated. It was found that introducing hexamethylenetetramine (HMTA) dendrimers and branched polyethyleneimine (PEI) on CF could increase significantly the adhesion strength between CF and TiO ₂ NWs and their interfacial shear strength with epoxy resin, and the order is CF-PEI-TiO ₂ NWs > CF-HMTA-TiO ₂ NWs > CF-COOH-TiO ₂ NWs > CF-TiO ₂ NW. Meanwhile, the reinforcing mechanisms and interfacial failure modes have also been discussed. We believe that these effective methods may provide theoretical foundation for the preparation of high performance composite materials.

Original language	English
Pages (from-to)	560-567
Number of pages	8
Journal	Applied Surface Science
Volume	433
DOIs	https://doi.org/10.1016/j.apsusc.2017.10.036
State	Published - 1 Mar 2018
Externally published	Yes

Keywords

Carbon fiber
Interface
Mechanical properties
Nanowires
Polymer-matrix composites (PMCs)

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10.1016/j.apsusc.2017.10.036

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Ma, L., Li, N., Wu, G., Song, G., Li, X., Han, P., Wang, G., & Huang, Y. (2018). Interfacial enhancement of carbon fiber composites by growing TiO ₂ nanowires onto amine-based functionalized carbon fiber surface in supercritical water Applied Surface Science, 433, 560-567. https://doi.org/10.1016/j.apsusc.2017.10.036

@article{62eed755f4694c9883f593dbbb25f789,

title = " Interfacial enhancement of carbon fiber composites by growing TiO 2 nanowires onto amine-based functionalized carbon fiber surface in supercritical water ",

abstract = " A novel amine-based functionalization method was developed to improve the interfacial adhesion between TiO 2 NWs and CFs in supercritical water. The microstructure, morphology and mechanical properties of CFs were investigated. It was found that introducing hexamethylenetetramine (HMTA) dendrimers and branched polyethyleneimine (PEI) on CF could increase significantly the adhesion strength between CF and TiO 2 NWs and their interfacial shear strength with epoxy resin, and the order is CF-PEI-TiO 2 NWs > CF-HMTA-TiO 2 NWs > CF-COOH-TiO 2 NWs > CF-TiO 2 NW. Meanwhile, the reinforcing mechanisms and interfacial failure modes have also been discussed. We believe that these effective methods may provide theoretical foundation for the preparation of high performance composite materials.",

keywords = "Carbon fiber, Interface, Mechanical properties, Nanowires, Polymer-matrix composites (PMCs)",

author = "Lichun Ma and Nan Li and Guangshun Wu and Guojun Song and Xiaoru Li and Ping Han and Gang Wang and Yudong Huang",

note = "Publisher Copyright: {\textcopyright} 2017",

year = "2018",

month = mar,

day = "1",

doi = "10.1016/j.apsusc.2017.10.036",

language = "英语",

volume = "433",

pages = "560--567",

journal = "Applied Surface Science",

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publisher = "Elsevier B.V.",

}

Ma, L, Li, N, Wu, G, Song, G, Li, X, Han, P, Wang, G & Huang, Y 2018, ' Interfacial enhancement of carbon fiber composites by growing TiO ₂ nanowires onto amine-based functionalized carbon fiber surface in supercritical water ', Applied Surface Science, vol. 433, pp. 560-567. https://doi.org/10.1016/j.apsusc.2017.10.036

Interfacial enhancement of carbon fiber composites by growing TiO ₂ nanowires onto amine-based functionalized carbon fiber surface in supercritical water . / Ma, Lichun; Li, Nan; Wu, Guangshun et al.
In: Applied Surface Science, Vol. 433, 01.03.2018, p. 560-567.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Interfacial enhancement of carbon fiber composites by growing TiO 2 nanowires onto amine-based functionalized carbon fiber surface in supercritical water

AU - Ma, Lichun

AU - Li, Nan

AU - Wu, Guangshun

AU - Song, Guojun

AU - Li, Xiaoru

AU - Han, Ping

AU - Wang, Gang

AU - Huang, Yudong

PY - 2018/3/1

Y1 - 2018/3/1

N2 - A novel amine-based functionalization method was developed to improve the interfacial adhesion between TiO 2 NWs and CFs in supercritical water. The microstructure, morphology and mechanical properties of CFs were investigated. It was found that introducing hexamethylenetetramine (HMTA) dendrimers and branched polyethyleneimine (PEI) on CF could increase significantly the adhesion strength between CF and TiO 2 NWs and their interfacial shear strength with epoxy resin, and the order is CF-PEI-TiO 2 NWs > CF-HMTA-TiO 2 NWs > CF-COOH-TiO 2 NWs > CF-TiO 2 NW. Meanwhile, the reinforcing mechanisms and interfacial failure modes have also been discussed. We believe that these effective methods may provide theoretical foundation for the preparation of high performance composite materials.

AB - A novel amine-based functionalization method was developed to improve the interfacial adhesion between TiO 2 NWs and CFs in supercritical water. The microstructure, morphology and mechanical properties of CFs were investigated. It was found that introducing hexamethylenetetramine (HMTA) dendrimers and branched polyethyleneimine (PEI) on CF could increase significantly the adhesion strength between CF and TiO 2 NWs and their interfacial shear strength with epoxy resin, and the order is CF-PEI-TiO 2 NWs > CF-HMTA-TiO 2 NWs > CF-COOH-TiO 2 NWs > CF-TiO 2 NW. Meanwhile, the reinforcing mechanisms and interfacial failure modes have also been discussed. We believe that these effective methods may provide theoretical foundation for the preparation of high performance composite materials.

KW - Carbon fiber

KW - Interface

KW - Mechanical properties

KW - Nanowires

KW - Polymer-matrix composites (PMCs)

UR - https://www.scopus.com/pages/publications/85031506974

U2 - 10.1016/j.apsusc.2017.10.036

DO - 10.1016/j.apsusc.2017.10.036

M3 - 文章

AN - SCOPUS:85031506974

SN - 0169-4332

VL - 433

SP - 560

EP - 567

JO - Applied Surface Science

JF - Applied Surface Science

ER -

Ma L, Li N, Wu G, Song G, Li X, Han P et al. Interfacial enhancement of carbon fiber composites by growing TiO ₂ nanowires onto amine-based functionalized carbon fiber surface in supercritical water Applied Surface Science. 2018 Mar 1;433:560-567. doi: 10.1016/j.apsusc.2017.10.036

Interfacial enhancement of carbon fiber composites by growing TiO ₂ nanowires onto amine-based functionalized carbon fiber surface in supercritical water

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