Inserting CO2 into Aryl C-H Bonds of Metal-Organic Frameworks: CO2 Utilization for Direct Heterogeneous C-H Activation

Wen Yang Gao; Haifan Wu; Kunyue Leng; Yinyong Sun; Shengqian Ma

doi:10.1002/anie.201511484

Inserting CO₂ into Aryl C-H Bonds of Metal-Organic Frameworks: CO₂ Utilization for Direct Heterogeneous C-H Activation

Wen Yang Gao
, Haifan Wu
, Kunyue Leng
, Yinyong Sun
, Shengqian Ma^*

^*Corresponding author for this work

University of South Florida
School of Chemistry and Chemical Engineering, Harbin Institute of Technology

Research output: Contribution to journal › Article › peer-review

131 Scopus citations

Abstract

Described for the first time is that carbon dioxide (CO₂) can be successfully inserted into aryl C-H bonds of the backbone of a metal-organic framework (MOF) to generate free carboxylate groups, which serve as Brønsted acid sites for efficiently catalyzing the methanolysis of epoxides. The work delineates the very first example of utilizing CO₂ for heterogeneous C-H activation and carboxylation reactions on MOFs, and opens a new avenue for CO₂ chemical transformations under mild.

Original language	English
Pages (from-to)	5472-5476
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	55
Issue number	18
DOIs	https://doi.org/10.1002/anie.201511484
State	Published - 25 Apr 2016
Externally published	Yes

Keywords

C-H activation
X-ray diffraction
carbon dioxide fixation
heterogeneous catalysis
metal-organic frameworks

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10.1002/anie.201511484

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title = "Inserting CO2 into Aryl C-H Bonds of Metal-Organic Frameworks: CO2 Utilization for Direct Heterogeneous C-H Activation",

abstract = "Described for the first time is that carbon dioxide (CO2) can be successfully inserted into aryl C-H bonds of the backbone of a metal-organic framework (MOF) to generate free carboxylate groups, which serve as Br{\o}nsted acid sites for efficiently catalyzing the methanolysis of epoxides. The work delineates the very first example of utilizing CO2 for heterogeneous C-H activation and carboxylation reactions on MOFs, and opens a new avenue for CO2 chemical transformations under mild.",

keywords = "C-H activation, X-ray diffraction, carbon dioxide fixation, heterogeneous catalysis, metal-organic frameworks",

author = "Gao, \{Wen Yang\} and Haifan Wu and Kunyue Leng and Yinyong Sun and Shengqian Ma",

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T1 - Inserting CO2 into Aryl C-H Bonds of Metal-Organic Frameworks

T2 - CO2 Utilization for Direct Heterogeneous C-H Activation

AU - Gao, Wen Yang

AU - Wu, Haifan

AU - Leng, Kunyue

AU - Sun, Yinyong

AU - Ma, Shengqian

PY - 2016/4/25

Y1 - 2016/4/25

N2 - Described for the first time is that carbon dioxide (CO2) can be successfully inserted into aryl C-H bonds of the backbone of a metal-organic framework (MOF) to generate free carboxylate groups, which serve as Brønsted acid sites for efficiently catalyzing the methanolysis of epoxides. The work delineates the very first example of utilizing CO2 for heterogeneous C-H activation and carboxylation reactions on MOFs, and opens a new avenue for CO2 chemical transformations under mild.

AB - Described for the first time is that carbon dioxide (CO2) can be successfully inserted into aryl C-H bonds of the backbone of a metal-organic framework (MOF) to generate free carboxylate groups, which serve as Brønsted acid sites for efficiently catalyzing the methanolysis of epoxides. The work delineates the very first example of utilizing CO2 for heterogeneous C-H activation and carboxylation reactions on MOFs, and opens a new avenue for CO2 chemical transformations under mild.

KW - C-H activation

KW - X-ray diffraction

KW - carbon dioxide fixation

KW - heterogeneous catalysis

KW - metal-organic frameworks

UR - https://www.scopus.com/pages/publications/84963507374

U2 - 10.1002/anie.201511484

DO - 10.1002/anie.201511484

M3 - 文章

AN - SCOPUS:84963507374

SN - 1433-7851

VL - 55

SP - 5472

EP - 5476

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 18

ER -

Inserting CO₂ into Aryl C-H Bonds of Metal-Organic Frameworks: CO₂ Utilization for Direct Heterogeneous C-H Activation

Abstract

Keywords

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