Inorganic anion-dependent assembly of zero-, one-, two- and three-dimensional Cu(II)/Ag(I) complexes under the guidance of the HSAB theory: Synthesis, structure, and magnetic property

Yaru Liu; Zhiyan Xing; Xiao Zhang; Guorui Liang

doi:10.1016/j.jssc.2016.10.030

Inorganic anion-dependent assembly of zero-, one-, two- and three-dimensional Cu(II)/Ag(I) complexes under the guidance of the HSAB theory: Synthesis, structure, and magnetic property

Yaru Liu^*
, Zhiyan Xing
, Xiao Zhang
, Guorui Liang

^*Corresponding author for this work

North University of China
School of Chemistry and Chemical Engineering, Harbin Institute of Technology
Heilongjiang University

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

To systematically explore the influence of inorganic anions on building coordination complexes, five novel complexes based on 1-(benzotriazole-1-methyl)−2-propylimidazole (bpmi), [Cu(bpmi)₂(Ac)₂]·H₂O (1), [Cu(bpmi)₂(H₂O)₂]·2NO₃·2H₂O (2), [Cu(bpmi)(N₃)₂] (3), [Ag(bpmi)(NO₃)] (4) and [Cu₃(bpmi)₂(SCN)₄(DMF)] (5) (Ac⁻=CH₃COO⁻, DMF=N,N-Dimethylformamide) are synthesized through rationally introducing Cu(II) salts and Ag(I) salt with different inorganic anions. X-ray single-crystal analyses reveal that these complexes show interesting structural features from mononuclear (1), one-dimensional (2 and 3), two-dimensional (4) to three-dimensional (5) under the influence of inorganic anions with different basicities. The structural variation can be explained by the hard-soft-acid-base (HSAB) theory. Magnetic susceptibility measurement indicates that complex 3 exhibits an antiferromagnetic coupling between adjacent Cu(II) ions.

Original language	English
Pages (from-to)	48-56
Number of pages	9
Journal	Journal of Solid State Chemistry
Volume	246
DOIs	https://doi.org/10.1016/j.jssc.2016.10.030
State	Published - 1 Feb 2017
Externally published	Yes

Keywords

1-(benzotriazole-1-methyl)−2-propylimidazole
Coordination complexes
Inorganic anions
Magnetism
The hard-soft-acid-base (HSAB) theory

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10.1016/j.jssc.2016.10.030

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@article{55946d29edd7426bb11e5e44dd228310,

title = "Inorganic anion-dependent assembly of zero-, one-, two- and three-dimensional Cu(II)/Ag(I) complexes under the guidance of the HSAB theory: Synthesis, structure, and magnetic property",

abstract = "To systematically explore the influence of inorganic anions on building coordination complexes, five novel complexes based on 1-(benzotriazole-1-methyl)−2-propylimidazole (bpmi), [Cu(bpmi)2(Ac)2]·H2O (1), [Cu(bpmi)2(H2O)2]·2NO3·2H2O (2), [Cu(bpmi)(N3)2] (3), [Ag(bpmi)(NO3)] (4) and [Cu3(bpmi)2(SCN)4(DMF)] (5) (Ac−=CH3COO−, DMF=N,N-Dimethylformamide) are synthesized through rationally introducing Cu(II) salts and Ag(I) salt with different inorganic anions. X-ray single-crystal analyses reveal that these complexes show interesting structural features from mononuclear (1), one-dimensional (2 and 3), two-dimensional (4) to three-dimensional (5) under the influence of inorganic anions with different basicities. The structural variation can be explained by the hard-soft-acid-base (HSAB) theory. Magnetic susceptibility measurement indicates that complex 3 exhibits an antiferromagnetic coupling between adjacent Cu(II) ions.",

keywords = "1-(benzotriazole-1-methyl)−2-propylimidazole, Coordination complexes, Inorganic anions, Magnetism, The hard-soft-acid-base (HSAB) theory",

author = "Yaru Liu and Zhiyan Xing and Xiao Zhang and Guorui Liang",

note = "Publisher Copyright: {\textcopyright} 2016",

year = "2017",

month = feb,

day = "1",

doi = "10.1016/j.jssc.2016.10.030",

language = "英语",

volume = "246",

pages = "48--56",

journal = "Journal of Solid State Chemistry",

issn = "0022-4596",

publisher = "Academic Press Inc.",

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TY - JOUR

T1 - Inorganic anion-dependent assembly of zero-, one-, two- and three-dimensional Cu(II)/Ag(I) complexes under the guidance of the HSAB theory

T2 - Synthesis, structure, and magnetic property

AU - Liu, Yaru

AU - Xing, Zhiyan

AU - Zhang, Xiao

AU - Liang, Guorui

PY - 2017/2/1

Y1 - 2017/2/1

N2 - To systematically explore the influence of inorganic anions on building coordination complexes, five novel complexes based on 1-(benzotriazole-1-methyl)−2-propylimidazole (bpmi), [Cu(bpmi)2(Ac)2]·H2O (1), [Cu(bpmi)2(H2O)2]·2NO3·2H2O (2), [Cu(bpmi)(N3)2] (3), [Ag(bpmi)(NO3)] (4) and [Cu3(bpmi)2(SCN)4(DMF)] (5) (Ac−=CH3COO−, DMF=N,N-Dimethylformamide) are synthesized through rationally introducing Cu(II) salts and Ag(I) salt with different inorganic anions. X-ray single-crystal analyses reveal that these complexes show interesting structural features from mononuclear (1), one-dimensional (2 and 3), two-dimensional (4) to three-dimensional (5) under the influence of inorganic anions with different basicities. The structural variation can be explained by the hard-soft-acid-base (HSAB) theory. Magnetic susceptibility measurement indicates that complex 3 exhibits an antiferromagnetic coupling between adjacent Cu(II) ions.

AB - To systematically explore the influence of inorganic anions on building coordination complexes, five novel complexes based on 1-(benzotriazole-1-methyl)−2-propylimidazole (bpmi), [Cu(bpmi)2(Ac)2]·H2O (1), [Cu(bpmi)2(H2O)2]·2NO3·2H2O (2), [Cu(bpmi)(N3)2] (3), [Ag(bpmi)(NO3)] (4) and [Cu3(bpmi)2(SCN)4(DMF)] (5) (Ac−=CH3COO−, DMF=N,N-Dimethylformamide) are synthesized through rationally introducing Cu(II) salts and Ag(I) salt with different inorganic anions. X-ray single-crystal analyses reveal that these complexes show interesting structural features from mononuclear (1), one-dimensional (2 and 3), two-dimensional (4) to three-dimensional (5) under the influence of inorganic anions with different basicities. The structural variation can be explained by the hard-soft-acid-base (HSAB) theory. Magnetic susceptibility measurement indicates that complex 3 exhibits an antiferromagnetic coupling between adjacent Cu(II) ions.

KW - 1-(benzotriazole-1-methyl)−2-propylimidazole

KW - Coordination complexes

KW - Inorganic anions

KW - Magnetism

KW - The hard-soft-acid-base (HSAB) theory

UR - https://www.scopus.com/pages/publications/84994558686

U2 - 10.1016/j.jssc.2016.10.030

DO - 10.1016/j.jssc.2016.10.030

M3 - 文章

AN - SCOPUS:84994558686

SN - 0022-4596

VL - 246

SP - 48

EP - 56

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

ER -

Inorganic anion-dependent assembly of zero-, one-, two- and three-dimensional Cu(II)/Ag(I) complexes under the guidance of the HSAB theory: Synthesis, structure, and magnetic property

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