Influence of the temperature and duration of the annealing on the lattice structure and growth of the Mg-Al spinel layer

Hailiang Zhang; Mingfu Zhang; Jiecai Han; Guobing Ying; Huaixin Guo; Chenghai Xu; Haitao Shen; Ningning Song

doi:10.1016/j.apsusc.2011.01.012

Influence of the temperature and duration of the annealing on the lattice structure and growth of the Mg-Al spinel layer

Hailiang Zhang
, Mingfu Zhang^*
, Jiecai Han
, Guobing Ying
, Huaixin Guo
, Chenghai Xu
, Haitao Shen
, Ningning Song

^*Corresponding author for this work

School of Astronautics

Harbin Institute of Technology

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

In this paper, MgO film is successfully grown on polycrystalline and monocrystalline alumina substrates using sol-gel method, and polycrystalline and monocrystalline Mg-Al spinels are fabricated by solid state reaction, respectively. The influence of annealing temperature and time on the lattice structure and growth of the formed Mg-Al spinel layer has been investigated. It is indicated that the annealing temperature and time on the as-synthesized polycrystalline Mg-Al spinel has more significant influence than that of single crystal Mg-Al spinel. The thickness of the Mg-Al spinel layer increases with the annealing temperature, both for polycrystalline and for monocrystalline alumina substrates. And the significantly intercrystalline diffusion of Mg ²⁺ ions and Al ³⁺ ions results in a quicker growth velocity of the Mg-Al spinel layer than that of intracrystalline diffusion.

Original language	English
Pages (from-to)	5012-5016
Number of pages	5
Journal	Applied Surface Science
Volume	257
Issue number	11
DOIs	https://doi.org/10.1016/j.apsusc.2011.01.012
State	Published - 15 Mar 2011

Keywords

Alumina
Diffusion
Mg-Al spinel
Solid state reaction

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10.1016/j.apsusc.2011.01.012

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title = "Influence of the temperature and duration of the annealing on the lattice structure and growth of the Mg-Al spinel layer",

abstract = " In this paper, MgO film is successfully grown on polycrystalline and monocrystalline alumina substrates using sol-gel method, and polycrystalline and monocrystalline Mg-Al spinels are fabricated by solid state reaction, respectively. The influence of annealing temperature and time on the lattice structure and growth of the formed Mg-Al spinel layer has been investigated. It is indicated that the annealing temperature and time on the as-synthesized polycrystalline Mg-Al spinel has more significant influence than that of single crystal Mg-Al spinel. The thickness of the Mg-Al spinel layer increases with the annealing temperature, both for polycrystalline and for monocrystalline alumina substrates. And the significantly intercrystalline diffusion of Mg 2+ ions and Al 3+ ions results in a quicker growth velocity of the Mg-Al spinel layer than that of intracrystalline diffusion.",

keywords = "Alumina, Diffusion, Mg-Al spinel, Solid state reaction",

author = "Hailiang Zhang and Mingfu Zhang and Jiecai Han and Guobing Ying and Huaixin Guo and Chenghai Xu and Haitao Shen and Ningning Song",

year = "2011",

month = mar,

day = "15",

doi = "10.1016/j.apsusc.2011.01.012",

language = "英语",

volume = "257",

pages = "5012--5016",

journal = "Applied Surface Science",

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}

TY - JOUR

T1 - Influence of the temperature and duration of the annealing on the lattice structure and growth of the Mg-Al spinel layer

AU - Zhang, Hailiang

AU - Zhang, Mingfu

AU - Han, Jiecai

AU - Ying, Guobing

AU - Guo, Huaixin

AU - Xu, Chenghai

AU - Shen, Haitao

AU - Song, Ningning

PY - 2011/3/15

Y1 - 2011/3/15

N2 - In this paper, MgO film is successfully grown on polycrystalline and monocrystalline alumina substrates using sol-gel method, and polycrystalline and monocrystalline Mg-Al spinels are fabricated by solid state reaction, respectively. The influence of annealing temperature and time on the lattice structure and growth of the formed Mg-Al spinel layer has been investigated. It is indicated that the annealing temperature and time on the as-synthesized polycrystalline Mg-Al spinel has more significant influence than that of single crystal Mg-Al spinel. The thickness of the Mg-Al spinel layer increases with the annealing temperature, both for polycrystalline and for monocrystalline alumina substrates. And the significantly intercrystalline diffusion of Mg 2+ ions and Al 3+ ions results in a quicker growth velocity of the Mg-Al spinel layer than that of intracrystalline diffusion.

AB - In this paper, MgO film is successfully grown on polycrystalline and monocrystalline alumina substrates using sol-gel method, and polycrystalline and monocrystalline Mg-Al spinels are fabricated by solid state reaction, respectively. The influence of annealing temperature and time on the lattice structure and growth of the formed Mg-Al spinel layer has been investigated. It is indicated that the annealing temperature and time on the as-synthesized polycrystalline Mg-Al spinel has more significant influence than that of single crystal Mg-Al spinel. The thickness of the Mg-Al spinel layer increases with the annealing temperature, both for polycrystalline and for monocrystalline alumina substrates. And the significantly intercrystalline diffusion of Mg 2+ ions and Al 3+ ions results in a quicker growth velocity of the Mg-Al spinel layer than that of intracrystalline diffusion.

KW - Alumina

KW - Diffusion

KW - Mg-Al spinel

KW - Solid state reaction

UR - https://www.scopus.com/pages/publications/79951678535

U2 - 10.1016/j.apsusc.2011.01.012

DO - 10.1016/j.apsusc.2011.01.012

M3 - 文章

AN - SCOPUS:79951678535

SN - 0169-4332

VL - 257

SP - 5012

EP - 5016

JO - Applied Surface Science

JF - Applied Surface Science

IS - 11

ER -

Influence of the temperature and duration of the annealing on the lattice structure and growth of the Mg-Al spinel layer

Abstract

Keywords

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