In situ construction of a flexible interlayer for durable solid-state lithium metal batteries

Naixuan Ci; Lin Zhang; Jianwei Li; Deping Li; Jun Cheng; Qing Sun; Zhenjie Xi; Zhou Xu; Guoqing Zhao; Lijie Ci

doi:10.1016/j.carbon.2021.10.070

In situ construction of a flexible interlayer for durable solid-state lithium metal batteries

Naixuan Ci
, Lin Zhang^*
, Jianwei Li
, Deping Li
, Jun Cheng
, Qing Sun
, Zhenjie Xi
, Zhou Xu
, Guoqing Zhao
, Lijie Ci^*

^*Corresponding author for this work

Shandong University
Harbin Institute of Technology

Research output: Contribution to journal › Article › peer-review

31 Scopus citations

Abstract

The development of solid-state lithium-metal batteries (SSLMBs) is severely constrained by the poor physical and (electro)chemical stability of the interface between solid-state electrolytes (SSEs) and lithium (Li) metal anode. Here, a flexible rGO film with uniformly distributed ZnO is in situ constructed at the interface between NASICON-type Li_1.5Al_0.5Ge_0.5(PO₄)₃ (LAGP) and Li metal anode. Such a buffer layer realizes a good interfacial contact, and prevents the side reaction between the Li metal anode and LAGP. As a result, the symmetric cells with the designed structure present a high critical current density of 3.0 mA cm^˗2 and stable cycling for over 800 h at 0.15 mA cm^˗2. In addition, LiFePO₄ (LFP)/Li full batteries deliver excellent capacity retention and long cycling performance.

Original language	English
Pages (from-to)	13-21
Number of pages	9
Journal	Carbon
Volume	187
DOIs	https://doi.org/10.1016/j.carbon.2021.10.070
State	Published - Feb 2022
Externally published	Yes

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Keywords

Flexible interface
In situ conversion reaction
LiAlGe(PO) (LAGP)
Solid electrolytes
Solid-state lithium-ion batteries

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10.1016/j.carbon.2021.10.070

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@article{4f4870cc301d4a709e72d4225ac5969c,

title = "In situ construction of a flexible interlayer for durable solid-state lithium metal batteries",

abstract = "The development of solid-state lithium-metal batteries (SSLMBs) is severely constrained by the poor physical and (electro)chemical stability of the interface between solid-state electrolytes (SSEs) and lithium (Li) metal anode. Here, a flexible rGO film with uniformly distributed ZnO is in situ constructed at the interface between NASICON-type Li1.5Al0.5Ge0.5(PO4)3 (LAGP) and Li metal anode. Such a buffer layer realizes a good interfacial contact, and prevents the side reaction between the Li metal anode and LAGP. As a result, the symmetric cells with the designed structure present a high critical current density of 3.0 mA cm˗2 and stable cycling for over 800 h at 0.15 mA cm˗2. In addition, LiFePO4 (LFP)/Li full batteries deliver excellent capacity retention and long cycling performance.",

keywords = "Flexible interface, In situ conversion reaction, LiAlGe(PO) (LAGP), Solid electrolytes, Solid-state lithium-ion batteries",

author = "Naixuan Ci and Lin Zhang and Jianwei Li and Deping Li and Jun Cheng and Qing Sun and Zhenjie Xi and Zhou Xu and Guoqing Zhao and Lijie Ci",

note = "Publisher Copyright: {\textcopyright} 2021 Elsevier Ltd",

year = "2022",

month = feb,

doi = "10.1016/j.carbon.2021.10.070",

language = "英语",

volume = "187",

pages = "13--21",

journal = "Carbon",

issn = "0008-6223",

publisher = "Elsevier Ltd",

}

TY - JOUR

T1 - In situ construction of a flexible interlayer for durable solid-state lithium metal batteries

AU - Ci, Naixuan

AU - Zhang, Lin

AU - Li, Jianwei

AU - Li, Deping

AU - Cheng, Jun

AU - Sun, Qing

AU - Xi, Zhenjie

AU - Xu, Zhou

AU - Zhao, Guoqing

AU - Ci, Lijie

PY - 2022/2

Y1 - 2022/2

N2 - The development of solid-state lithium-metal batteries (SSLMBs) is severely constrained by the poor physical and (electro)chemical stability of the interface between solid-state electrolytes (SSEs) and lithium (Li) metal anode. Here, a flexible rGO film with uniformly distributed ZnO is in situ constructed at the interface between NASICON-type Li1.5Al0.5Ge0.5(PO4)3 (LAGP) and Li metal anode. Such a buffer layer realizes a good interfacial contact, and prevents the side reaction between the Li metal anode and LAGP. As a result, the symmetric cells with the designed structure present a high critical current density of 3.0 mA cm˗2 and stable cycling for over 800 h at 0.15 mA cm˗2. In addition, LiFePO4 (LFP)/Li full batteries deliver excellent capacity retention and long cycling performance.

AB - The development of solid-state lithium-metal batteries (SSLMBs) is severely constrained by the poor physical and (electro)chemical stability of the interface between solid-state electrolytes (SSEs) and lithium (Li) metal anode. Here, a flexible rGO film with uniformly distributed ZnO is in situ constructed at the interface between NASICON-type Li1.5Al0.5Ge0.5(PO4)3 (LAGP) and Li metal anode. Such a buffer layer realizes a good interfacial contact, and prevents the side reaction between the Li metal anode and LAGP. As a result, the symmetric cells with the designed structure present a high critical current density of 3.0 mA cm˗2 and stable cycling for over 800 h at 0.15 mA cm˗2. In addition, LiFePO4 (LFP)/Li full batteries deliver excellent capacity retention and long cycling performance.

KW - Flexible interface

KW - In situ conversion reaction

KW - LiAlGe(PO) (LAGP)

KW - Solid electrolytes

KW - Solid-state lithium-ion batteries

UR - https://www.scopus.com/pages/publications/85118569243

U2 - 10.1016/j.carbon.2021.10.070

DO - 10.1016/j.carbon.2021.10.070

M3 - 文章

AN - SCOPUS:85118569243

SN - 0008-6223

VL - 187

SP - 13

EP - 21

JO - Carbon

JF - Carbon

ER -

In situ construction of a flexible interlayer for durable solid-state lithium metal batteries

Abstract

UN SDGs

Keywords

Access to Document

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