Hydrothermal synthesis, crystal structure and properties of a new cyanide-containing supramolecular compound

H. Y. Bie; J. H. Yu; D. Q. Chu; J. Q. Xu; J. Lu; Y. H. Sun; X. B. Cui; Y. Li; X. Zhang

Hydrothermal synthesis, crystal structure and properties of a new cyanide-containing supramolecular compound

H. Y. Bie
, J. H. Yu
, D. Q. Chu
, J. Q. Xu^*
, J. Lu
, Y. H. Sun
, X. B. Cui
, Y. Li
, X. Zhang

^*Corresponding author for this work

College of Chemistry

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

Under hydrothermal conditions, reaction of Na₄[Fe(CN) ₆], NiCl₂ and dien results in the formation of a cyanide-containing heterometallic compound [Ni(dien)₂][Fe(CN) ₄] 1. The structure consists of one octahedral [Ni(dien) ₂]²⁺ cation, square [Fe(CN)₄]^2- anion, which are held together by N-H⋯N hydrogen bond to form one-dimensional supramolecular chains. Its magnetic property was measured from 5 to 300 K, showing very weak ferromagnetic interactions. This compound in DMF solutions has a strong third-order non-linear optical (NLO) behavior with absorption coefficient and refractive index α₂ = 2.10×10^-11 m w^-1, n₂ = -2.05×10^-18 m² w^-1, respectively, and third-order NLO susceptibility χ⁽³⁾ 2.73×10^-10 esu.

Original language	English
Pages (from-to)	1969-1978
Number of pages	10
Journal	Polish Journal of Chemistry
Volume	78
Issue number	11-12
State	Published - Nov 2004
Externally published	Yes

Keywords

Crystal structure
Cyanide complex
Hydrothermal reaction
Magnetic property
NLO property

Cite this

@article{e812a328e7d74fe7b6fe0df1a193f2bc,

title = "Hydrothermal synthesis, crystal structure and properties of a new cyanide-containing supramolecular compound",

abstract = "Under hydrothermal conditions, reaction of Na4[Fe(CN) 6], NiCl2 and dien results in the formation of a cyanide-containing heterometallic compound [Ni(dien)2][Fe(CN) 4] 1. The structure consists of one octahedral [Ni(dien) 2]2+ cation, square [Fe(CN)4]2- anion, which are held together by N-H⋯N hydrogen bond to form one-dimensional supramolecular chains. Its magnetic property was measured from 5 to 300 K, showing very weak ferromagnetic interactions. This compound in DMF solutions has a strong third-order non-linear optical (NLO) behavior with absorption coefficient and refractive index α2 = 2.10×10-11 m w-1, n2 = -2.05×10-18 m2 w-1, respectively, and third-order NLO susceptibility χ(3) 2.73×10-10 esu.",

keywords = "Crystal structure, Cyanide complex, Hydrothermal reaction, Magnetic property, NLO property",

author = "Bie, \{H. Y.\} and Yu, \{J. H.\} and Chu, \{D. Q.\} and Xu, \{J. Q.\} and J. Lu and Sun, \{Y. H.\} and Cui, \{X. B.\} and Y. Li and X. Zhang",

year = "2004",

month = nov,

language = "英语",

volume = "78",

pages = "1969--1978",

journal = "Polish Journal of Chemistry",

issn = "0137-5083",

publisher = "Polish Chemical Society",

number = "11-12",

}

TY - JOUR

T1 - Hydrothermal synthesis, crystal structure and properties of a new cyanide-containing supramolecular compound

AU - Bie, H. Y.

AU - Yu, J. H.

AU - Chu, D. Q.

AU - Xu, J. Q.

AU - Lu, J.

AU - Sun, Y. H.

AU - Cui, X. B.

AU - Li, Y.

AU - Zhang, X.

PY - 2004/11

Y1 - 2004/11

N2 - Under hydrothermal conditions, reaction of Na4[Fe(CN) 6], NiCl2 and dien results in the formation of a cyanide-containing heterometallic compound [Ni(dien)2][Fe(CN) 4] 1. The structure consists of one octahedral [Ni(dien) 2]2+ cation, square [Fe(CN)4]2- anion, which are held together by N-H⋯N hydrogen bond to form one-dimensional supramolecular chains. Its magnetic property was measured from 5 to 300 K, showing very weak ferromagnetic interactions. This compound in DMF solutions has a strong third-order non-linear optical (NLO) behavior with absorption coefficient and refractive index α2 = 2.10×10-11 m w-1, n2 = -2.05×10-18 m2 w-1, respectively, and third-order NLO susceptibility χ(3) 2.73×10-10 esu.

AB - Under hydrothermal conditions, reaction of Na4[Fe(CN) 6], NiCl2 and dien results in the formation of a cyanide-containing heterometallic compound [Ni(dien)2][Fe(CN) 4] 1. The structure consists of one octahedral [Ni(dien) 2]2+ cation, square [Fe(CN)4]2- anion, which are held together by N-H⋯N hydrogen bond to form one-dimensional supramolecular chains. Its magnetic property was measured from 5 to 300 K, showing very weak ferromagnetic interactions. This compound in DMF solutions has a strong third-order non-linear optical (NLO) behavior with absorption coefficient and refractive index α2 = 2.10×10-11 m w-1, n2 = -2.05×10-18 m2 w-1, respectively, and third-order NLO susceptibility χ(3) 2.73×10-10 esu.

KW - Crystal structure

KW - Cyanide complex

KW - Hydrothermal reaction

KW - Magnetic property

KW - NLO property

UR - https://www.scopus.com/pages/publications/10944244150

M3 - 文章

AN - SCOPUS:10944244150

SN - 0137-5083

VL - 78

SP - 1969

EP - 1978

JO - Polish Journal of Chemistry

JF - Polish Journal of Chemistry

IS - 11-12

ER -

Hydrothermal synthesis, crystal structure and properties of a new cyanide-containing supramolecular compound

Abstract

Keywords

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