Hydrothermal synthesis and structure of the new three-dimensional fluorogallophosphate JGP-4 with a Ga/P ratio of 7/8

Yulin Yang; Zhongcheng Mu; Yan Xu; Chao Chen; Wei Wang; Zhuo Yi; Ling Ye; Yunlin Liu; Wenqin Pang

doi:10.1016/j.jssc.2004.02.028

Hydrothermal synthesis and structure of the new three-dimensional fluorogallophosphate JGP-4 with a Ga/P ratio of 7/8

Yulin Yang
, Zhongcheng Mu
, Yan Xu
, Chao Chen
, Wei Wang
, Zhuo Yi
, Ling Ye
, Yunlin Liu
, Wenqin Pang^*

^*Corresponding author for this work

College of Chemistry
The University of Tokyo

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

A new 3-D fluorogallophosphate Ga₇P₈O ₃₂F₄(C₆H₂₀N₄) ₂·3H₃O⁺·H₂O (denoted JGP-4) with a Ga/P ratio of 7/8 has been synthesized hydrothermally by using triethylenetetramine as the template. It crystallizes in the tetragonal, space group P4̄2₁c (no. 114), with a=15.461(2), b=15.461(2), c=9.3233(1)Å, V=2228.67(5)Å³ and Z=2. This is the first metal phosphate with a M/P ratio of 7/8. The 3-D anionic framework of JGP-4 is built up from the vertex linkage of the 1-D chains and Ga₅P ₄ building units, forming a 3-D open-framework with 8-membered and four square 4-membered rings along the c-axis direction.

Original language	English
Pages (from-to)	2183-2187
Number of pages	5
Journal	Journal of Solid State Chemistry
Volume	177
Issue number	6
DOIs	https://doi.org/10.1016/j.jssc.2004.02.028
State	Published - Jun 2004
Externally published	Yes

Keywords

Fluorogallophosphate
Ga/P ratio
Structure
Synthesis

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10.1016/j.jssc.2004.02.028

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@article{bb27d4c010bd4654aa5b9dea6205c22c,

title = "Hydrothermal synthesis and structure of the new three-dimensional fluorogallophosphate JGP-4 with a Ga/P ratio of 7/8",

abstract = "A new 3-D fluorogallophosphate Ga7P8O 32F4(C6H20N4) 2·3H3O+·H2O (denoted JGP-4) with a Ga/P ratio of 7/8 has been synthesized hydrothermally by using triethylenetetramine as the template. It crystallizes in the tetragonal, space group P{\=4}21c (no. 114), with a=15.461(2), b=15.461(2), c=9.3233(1){\AA}, V=2228.67(5){\AA}3 and Z=2. This is the first metal phosphate with a M/P ratio of 7/8. The 3-D anionic framework of JGP-4 is built up from the vertex linkage of the 1-D chains and Ga5P 4 building units, forming a 3-D open-framework with 8-membered and four square 4-membered rings along the c-axis direction.",

keywords = "Fluorogallophosphate, Ga/P ratio, Structure, Synthesis",

author = "Yulin Yang and Zhongcheng Mu and Yan Xu and Chao Chen and Wei Wang and Zhuo Yi and Ling Ye and Yunlin Liu and Wenqin Pang",

year = "2004",

month = jun,

doi = "10.1016/j.jssc.2004.02.028",

language = "英语",

volume = "177",

pages = "2183--2187",

journal = "Journal of Solid State Chemistry",

issn = "0022-4596",

publisher = "Academic Press Inc.",

number = "6",

}

TY - JOUR

T1 - Hydrothermal synthesis and structure of the new three-dimensional fluorogallophosphate JGP-4 with a Ga/P ratio of 7/8

AU - Yang, Yulin

AU - Mu, Zhongcheng

AU - Xu, Yan

AU - Chen, Chao

AU - Wang, Wei

AU - Yi, Zhuo

AU - Ye, Ling

AU - Liu, Yunlin

AU - Pang, Wenqin

PY - 2004/6

Y1 - 2004/6

N2 - A new 3-D fluorogallophosphate Ga7P8O 32F4(C6H20N4) 2·3H3O+·H2O (denoted JGP-4) with a Ga/P ratio of 7/8 has been synthesized hydrothermally by using triethylenetetramine as the template. It crystallizes in the tetragonal, space group P4̄21c (no. 114), with a=15.461(2), b=15.461(2), c=9.3233(1)Å, V=2228.67(5)Å3 and Z=2. This is the first metal phosphate with a M/P ratio of 7/8. The 3-D anionic framework of JGP-4 is built up from the vertex linkage of the 1-D chains and Ga5P 4 building units, forming a 3-D open-framework with 8-membered and four square 4-membered rings along the c-axis direction.

AB - A new 3-D fluorogallophosphate Ga7P8O 32F4(C6H20N4) 2·3H3O+·H2O (denoted JGP-4) with a Ga/P ratio of 7/8 has been synthesized hydrothermally by using triethylenetetramine as the template. It crystallizes in the tetragonal, space group P4̄21c (no. 114), with a=15.461(2), b=15.461(2), c=9.3233(1)Å, V=2228.67(5)Å3 and Z=2. This is the first metal phosphate with a M/P ratio of 7/8. The 3-D anionic framework of JGP-4 is built up from the vertex linkage of the 1-D chains and Ga5P 4 building units, forming a 3-D open-framework with 8-membered and four square 4-membered rings along the c-axis direction.

KW - Fluorogallophosphate

KW - Ga/P ratio

KW - Structure

KW - Synthesis

UR - https://www.scopus.com/pages/publications/3242690817

U2 - 10.1016/j.jssc.2004.02.028

DO - 10.1016/j.jssc.2004.02.028

M3 - 文章

AN - SCOPUS:3242690817

SN - 0022-4596

VL - 177

SP - 2183

EP - 2187

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

IS - 6

ER -

Hydrothermal synthesis and structure of the new three-dimensional fluorogallophosphate JGP-4 with a Ga/P ratio of 7/8

Abstract

Keywords

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