Hydrothermal synthesis and structural characterization of the first indium phosphite In 2(HPO 3) 3(H 2O)

Zhuo Yi; Chao Chen; Shougui Li; Guanghua Li; He Meng; Yanjie Cui; Yulin Yang; Wenqin Pang

doi:10.1016/j.inoche.2004.11.029

Hydrothermal synthesis and structural characterization of the first indium phosphite In ₂(HPO ₃) ₃(H ₂O)

Zhuo Yi
, Chao Chen
, Shougui Li
, Guanghua Li
, He Meng
, Yanjie Cui
, Yulin Yang
, Wenqin Pang

College of Chemistry

Research output: Contribution to journal › Article › peer-review

24 Scopus citations

Abstract

A novel indium phosphite, In ₂(HPO ₃) ₃(H ₂O) was hydrothermally prepared and characterized by single-crystal X-ray diffraction. The structure of the compound consists of In ₂O ₁₀ dimer and pseudo pyramidal HPO ₃, which are connected by sharing vertexes to form the 3D inorganic framework with a In/P ratio of 2/3. In ₂(HPO ₃) ₃(H ₂O) is the first indium phosphite synthesized by hydrothermal technique. Presence of the In-O-In linkage leading to a In ₂O ₁₀ dimer in the framework is a noteworthy feature. It was characterized by powder X-ray diffraction, ICP, elemental analysis and IR spectra.

Original language	English
Pages (from-to)	166-169
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	8
Issue number	2
DOIs	https://doi.org/10.1016/j.inoche.2004.11.029
State	Published - Feb 2005
Externally published	Yes

Keywords

Characterization
Hydrothermal synthesis
Indium phosphite
Structure

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10.1016/j.inoche.2004.11.029

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title = "Hydrothermal synthesis and structural characterization of the first indium phosphite In 2(HPO 3) 3(H 2O)",

abstract = "A novel indium phosphite, In 2(HPO 3) 3(H 2O) was hydrothermally prepared and characterized by single-crystal X-ray diffraction. The structure of the compound consists of In 2O 10 dimer and pseudo pyramidal HPO 3, which are connected by sharing vertexes to form the 3D inorganic framework with a In/P ratio of 2/3. In 2(HPO 3) 3(H 2O) is the first indium phosphite synthesized by hydrothermal technique. Presence of the In-O-In linkage leading to a In 2O 10 dimer in the framework is a noteworthy feature. It was characterized by powder X-ray diffraction, ICP, elemental analysis and IR spectra.",

keywords = "Characterization, Hydrothermal synthesis, Indium phosphite, Structure",

author = "Zhuo Yi and Chao Chen and Shougui Li and Guanghua Li and He Meng and Yanjie Cui and Yulin Yang and Wenqin Pang",

year = "2005",

month = feb,

doi = "10.1016/j.inoche.2004.11.029",

language = "英语",

volume = "8",

pages = "166--169",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

number = "2",

}

TY - JOUR

T1 - Hydrothermal synthesis and structural characterization of the first indium phosphite In 2(HPO 3) 3(H 2O)

AU - Yi, Zhuo

AU - Chen, Chao

AU - Li, Shougui

AU - Li, Guanghua

AU - Meng, He

AU - Cui, Yanjie

AU - Yang, Yulin

AU - Pang, Wenqin

PY - 2005/2

Y1 - 2005/2

N2 - A novel indium phosphite, In 2(HPO 3) 3(H 2O) was hydrothermally prepared and characterized by single-crystal X-ray diffraction. The structure of the compound consists of In 2O 10 dimer and pseudo pyramidal HPO 3, which are connected by sharing vertexes to form the 3D inorganic framework with a In/P ratio of 2/3. In 2(HPO 3) 3(H 2O) is the first indium phosphite synthesized by hydrothermal technique. Presence of the In-O-In linkage leading to a In 2O 10 dimer in the framework is a noteworthy feature. It was characterized by powder X-ray diffraction, ICP, elemental analysis and IR spectra.

AB - A novel indium phosphite, In 2(HPO 3) 3(H 2O) was hydrothermally prepared and characterized by single-crystal X-ray diffraction. The structure of the compound consists of In 2O 10 dimer and pseudo pyramidal HPO 3, which are connected by sharing vertexes to form the 3D inorganic framework with a In/P ratio of 2/3. In 2(HPO 3) 3(H 2O) is the first indium phosphite synthesized by hydrothermal technique. Presence of the In-O-In linkage leading to a In 2O 10 dimer in the framework is a noteworthy feature. It was characterized by powder X-ray diffraction, ICP, elemental analysis and IR spectra.

KW - Characterization

KW - Hydrothermal synthesis

KW - Indium phosphite

KW - Structure

UR - https://www.scopus.com/pages/publications/11844278283

U2 - 10.1016/j.inoche.2004.11.029

DO - 10.1016/j.inoche.2004.11.029

M3 - 文章

AN - SCOPUS:11844278283

SN - 1387-7003

VL - 8

SP - 166

EP - 169

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 2

ER -

Hydrothermal synthesis and structural characterization of the first indium phosphite In ₂(HPO ₃) ₃(H ₂O)

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Keywords

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