Hydrothermal synthesis and structural characterization of a novel 2-D supramolecular compound [CoIII(aea)(2,2′-bipy)]Cl·H 2O

Feng Tong Xie; Li Mei Duan; Ji Qing Xu; Ya Bing Liu; Xiao Zhang; Jing Lu

Hydrothermal synthesis and structural characterization of a novel 2-D supramolecular compound [Co^III(aea)(2,2′-bipy)]Cl·H ₂O

Feng Tong Xie^*
, Li Mei Duan
, Ji Qing Xu
, Ya Bing Liu
, Xiao Zhang
, Jing Lu

^*Corresponding author for this work

College of Chemistry
Inspection Inst. Prod. Qual. M.

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

A new compound [Co^III(aea)(2,2′-bipy)]Cl·H ₂O (aea=N-(2-aminoethyl)aspartate, 2,2′-bipy=2,2′- bipyridine) was hydrothermally synthesized and structurally characterized, which contains a new quadridentate ligand (aea) came from malic acid and ethylenediamine via in-situ reaction. The asymmetric molecules are interconnected through N-H⋯O hydrogen bond to form helical chains that are further hold together into a two-dimensional network via the N-H⋯Cl hydrogen bond. The formation of aea can be considered as the substitution of hydroxyl group in malate by ethylenediamino group, which presents a type of new in-situ ligand reaction. CCDC: 222018.

Original language	English
Article number	1001-4861(2005)01-0123-05
Pages (from-to)	123-127
Number of pages	5
Journal	Chinese Journal of Inorganic Chemistry
Volume	21
Issue number	1
State	Published - 1 Jan 2005
Externally published	Yes

Keywords

Cobalt(III) complex
Quadridentate
Supramolecular network
in-situ reaction

Cite this

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title = "Hydrothermal synthesis and structural characterization of a novel 2-D supramolecular compound [CoIII(aea)(2,2′-bipy)]Cl·H 2O",

abstract = "A new compound [CoIII(aea)(2,2′-bipy)]Cl·H 2O (aea=N-(2-aminoethyl)aspartate, 2,2′-bipy=2,2′- bipyridine) was hydrothermally synthesized and structurally characterized, which contains a new quadridentate ligand (aea) came from malic acid and ethylenediamine via in-situ reaction. The asymmetric molecules are interconnected through N-H⋯O hydrogen bond to form helical chains that are further hold together into a two-dimensional network via the N-H⋯Cl hydrogen bond. The formation of aea can be considered as the substitution of hydroxyl group in malate by ethylenediamino group, which presents a type of new in-situ ligand reaction. CCDC: 222018.",

keywords = "Cobalt(III) complex, Quadridentate, Supramolecular network, in-situ reaction",

author = "Xie, \{Feng Tong\} and Duan, \{Li Mei\} and Xu, \{Ji Qing\} and Liu, \{Ya Bing\} and Xiao Zhang and Jing Lu",

year = "2005",

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language = "英语",

volume = "21",

pages = "123--127",

journal = "Chinese Journal of Inorganic Chemistry",

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TY - JOUR

T1 - Hydrothermal synthesis and structural characterization of a novel 2-D supramolecular compound [CoIII(aea)(2,2′-bipy)]Cl·H 2O

AU - Xie, Feng Tong

AU - Duan, Li Mei

AU - Xu, Ji Qing

AU - Liu, Ya Bing

AU - Zhang, Xiao

AU - Lu, Jing

PY - 2005/1/1

Y1 - 2005/1/1

N2 - A new compound [CoIII(aea)(2,2′-bipy)]Cl·H 2O (aea=N-(2-aminoethyl)aspartate, 2,2′-bipy=2,2′- bipyridine) was hydrothermally synthesized and structurally characterized, which contains a new quadridentate ligand (aea) came from malic acid and ethylenediamine via in-situ reaction. The asymmetric molecules are interconnected through N-H⋯O hydrogen bond to form helical chains that are further hold together into a two-dimensional network via the N-H⋯Cl hydrogen bond. The formation of aea can be considered as the substitution of hydroxyl group in malate by ethylenediamino group, which presents a type of new in-situ ligand reaction. CCDC: 222018.

AB - A new compound [CoIII(aea)(2,2′-bipy)]Cl·H 2O (aea=N-(2-aminoethyl)aspartate, 2,2′-bipy=2,2′- bipyridine) was hydrothermally synthesized and structurally characterized, which contains a new quadridentate ligand (aea) came from malic acid and ethylenediamine via in-situ reaction. The asymmetric molecules are interconnected through N-H⋯O hydrogen bond to form helical chains that are further hold together into a two-dimensional network via the N-H⋯Cl hydrogen bond. The formation of aea can be considered as the substitution of hydroxyl group in malate by ethylenediamino group, which presents a type of new in-situ ligand reaction. CCDC: 222018.

KW - Cobalt(III) complex

KW - Quadridentate

KW - Supramolecular network

KW - in-situ reaction

UR - https://www.scopus.com/pages/publications/12344314135

M3 - 文章

AN - SCOPUS:12344314135

SN - 1001-4861

VL - 21

SP - 123

EP - 127

JO - Chinese Journal of Inorganic Chemistry

JF - Chinese Journal of Inorganic Chemistry

IS - 1

M1 - 1001-4861(2005)01-0123-05

ER -

Hydrothermal synthesis and structural characterization of a novel 2-D supramolecular compound [Co^III(aea)(2,2′-bipy)]Cl·H ₂O

Abstract

Keywords

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