Hydrothermal synthesis and characterization of Bi2Pb2O7 with pyrochlore structure

Yachun Mao; Guangshe Li; Yinyong Sun; Shouhua Feng

doi:10.1006/jssc.1999.8532

Hydrothermal synthesis and characterization of Bi₂Pb₂O₇ with pyrochlore structure

Yachun Mao
, Guangshe Li
, Yinyong Sun
, Shouhua Feng^*

^*Corresponding author for this work

Jilin University

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

Pyrochlore Bi₂Pb₂O₇ was fabricatedi under low-temperature hydrothermal conditions and characterized by XRD, IR, SEM DTA-TG, and XPS. XRD analysis shows that the structure of Bi₂Pb₂O₇ is cubic, which is similar to that obtained from high-pressure reactions. XPS measurements suggest that the valences of Bi and Pb ions are +3 and +4, respectively. The cubic Bi₂Pb₂O₇ is a metastable phase; it decomposes into a new phase with liberation of O₂ at 450°C. (C) 2000 Academic Press.

Original language	English
Pages (from-to)	314-319
Number of pages	6
Journal	Journal of Solid State Chemistry
Volume	149
Issue number	2
DOIs	https://doi.org/10.1006/jssc.1999.8532
State	Published - 2000
Externally published	Yes

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title = "Hydrothermal synthesis and characterization of Bi2Pb2O7 with pyrochlore structure",

abstract = "Pyrochlore Bi2Pb2O7 was fabricatedi under low-temperature hydrothermal conditions and characterized by XRD, IR, SEM DTA-TG, and XPS. XRD analysis shows that the structure of Bi2Pb2O7 is cubic, which is similar to that obtained from high-pressure reactions. XPS measurements suggest that the valences of Bi and Pb ions are +3 and +4, respectively. The cubic Bi2Pb2O7 is a metastable phase; it decomposes into a new phase with liberation of O2 at 450°C. (C) 2000 Academic Press.",

author = "Yachun Mao and Guangshe Li and Yinyong Sun and Shouhua Feng",

year = "2000",

doi = "10.1006/jssc.1999.8532",

language = "英语",

volume = "149",

pages = "314--319",

journal = "Journal of Solid State Chemistry",

issn = "0022-4596",

publisher = "Academic Press Inc.",

number = "2",

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TY - JOUR

T1 - Hydrothermal synthesis and characterization of Bi2Pb2O7 with pyrochlore structure

AU - Mao, Yachun

AU - Li, Guangshe

AU - Sun, Yinyong

AU - Feng, Shouhua

PY - 2000

Y1 - 2000

N2 - Pyrochlore Bi2Pb2O7 was fabricatedi under low-temperature hydrothermal conditions and characterized by XRD, IR, SEM DTA-TG, and XPS. XRD analysis shows that the structure of Bi2Pb2O7 is cubic, which is similar to that obtained from high-pressure reactions. XPS measurements suggest that the valences of Bi and Pb ions are +3 and +4, respectively. The cubic Bi2Pb2O7 is a metastable phase; it decomposes into a new phase with liberation of O2 at 450°C. (C) 2000 Academic Press.

AB - Pyrochlore Bi2Pb2O7 was fabricatedi under low-temperature hydrothermal conditions and characterized by XRD, IR, SEM DTA-TG, and XPS. XRD analysis shows that the structure of Bi2Pb2O7 is cubic, which is similar to that obtained from high-pressure reactions. XPS measurements suggest that the valences of Bi and Pb ions are +3 and +4, respectively. The cubic Bi2Pb2O7 is a metastable phase; it decomposes into a new phase with liberation of O2 at 450°C. (C) 2000 Academic Press.

UR - https://www.scopus.com/pages/publications/0033658741

U2 - 10.1006/jssc.1999.8532

DO - 10.1006/jssc.1999.8532

M3 - 文章

AN - SCOPUS:0033658741

SN - 0022-4596

VL - 149

SP - 314

EP - 319

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

IS - 2

ER -

Hydrothermal synthesis and characterization of Bi₂Pb₂O₇ with pyrochlore structure

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