Hydrothermal synthesis and characterization of a new organically templated three-dimensional open-framework gallium phosphate-phosphite (C6N2H18)2(C6N2H17)Ga15(OH)8(PO4)2(HPO4)12(HPO3)6·2H2O

Guangpeng Zhou; Yulin Yang; Ruiqing Fan; Xinrong Liu; Hengwu Hong; Fuping Wang

doi:10.1016/j.solidstatesciences.2010.04.013

Hydrothermal synthesis and characterization of a new organically templated three-dimensional open-framework gallium phosphate-phosphite (C₆N₂H₁₈)₂(C₆N₂H₁₇)Ga₁₅(OH)₈(PO₄)₂(HPO₄)₁₂(HPO₃)₆·2H₂O

Guangpeng Zhou
, Yulin Yang^*
, Ruiqing Fan
, Xinrong Liu
, Hengwu Hong
, Fuping Wang

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Harbin Institute of Technology
North Machinery Corporation Limited China

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

Using H₃PO₃ as a phosphorus source and oxalic acid as a reducing agent, the first three-dimensional open-framework gallium phosphate-phosphite formula as (C₆N₂H₁₈)₂(C₆N₂H₁₇)Ga₁₅(OH)₈(PO₄)₂(HPO₄)₁₂(HPO₃)₆·2H₂O (1), has been hydrothermally synthesized in the presence of N,N,N′,N′-tetramethylenediamine (TMEDA) as a structure-directing agent. Compound 1 crystallizes in trigonal system with space group P - 3, a = b = 19.046(3) Å, c = 8.3306(17) Å, γ = 120°, V = 2617.1(7) Å³, and Z = 1. Its 3-D network is based on alternated Ga-centered (GaO₄ tetrahedra, GaO₅ trigonal bipyramids, and GaO₆ octahedra) and P-centered (PO₄^3-, HPO₄^2-, and HPO₃^2-) units. Protonated organic amines and water molecules are located in the 12-membered ring channels.

Original language	English
Pages (from-to)	1103-1106
Number of pages	4
Journal	Solid State Sciences
Volume	12
Issue number	7
DOIs	https://doi.org/10.1016/j.solidstatesciences.2010.04.013
State	Published - Jul 2010

Keywords

Crystal structure
Gallium phosphate-phosphite
Hydrothermal synthesis

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10.1016/j.solidstatesciences.2010.04.013

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@article{7f91ffdb77e74ed294a1703e961e2b44,

title = "Hydrothermal synthesis and characterization of a new organically templated three-dimensional open-framework gallium phosphate-phosphite (C6N2H18)2(C6N2H17)Ga15(OH)8(PO4)2(HPO4)12(HPO3)6·2H2O",

abstract = "Using H3PO3 as a phosphorus source and oxalic acid as a reducing agent, the first three-dimensional open-framework gallium phosphate-phosphite formula as (C6N2H18)2(C6N2H17)Ga15(OH)8(PO4)2(HPO4)12(HPO3)6·2H2O (1), has been hydrothermally synthesized in the presence of N,N,N′,N′-tetramethylenediamine (TMEDA) as a structure-directing agent. Compound 1 crystallizes in trigonal system with space group P - 3, a = b = 19.046(3) {\AA}, c = 8.3306(17) {\AA}, γ = 120°, V = 2617.1(7) {\AA}3, and Z = 1. Its 3-D network is based on alternated Ga-centered (GaO4 tetrahedra, GaO5 trigonal bipyramids, and GaO6 octahedra) and P-centered (PO43-, HPO42-, and HPO32-) units. Protonated organic amines and water molecules are located in the 12-membered ring channels.",

keywords = "Crystal structure, Gallium phosphate-phosphite, Hydrothermal synthesis",

author = "Guangpeng Zhou and Yulin Yang and Ruiqing Fan and Xinrong Liu and Hengwu Hong and Fuping Wang",

year = "2010",

month = jul,

doi = "10.1016/j.solidstatesciences.2010.04.013",

language = "英语",

volume = "12",

pages = "1103--1106",

journal = "Solid State Sciences",

issn = "1293-2558",

publisher = "Elsevier Masson s.r.l.",

number = "7",

}

Hydrothermal synthesis and characterization of a new organically templated three-dimensional open-framework gallium phosphate-phosphite (C₆N₂H₁₈)₂(C₆N₂H₁₇)Ga₁₅(OH)₈(PO₄)₂(HPO₄)₁₂(HPO₃)₆·2H₂O. / Zhou, Guangpeng; Yang, Yulin; Fan, Ruiqing et al.
In: Solid State Sciences, Vol. 12, No. 7, 07.2010, p. 1103-1106.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Hydrothermal synthesis and characterization of a new organically templated three-dimensional open-framework gallium phosphate-phosphite (C6N2H18)2(C6N2H17)Ga15(OH)8(PO4)2(HPO4)12(HPO3)6·2H2O

AU - Zhou, Guangpeng

AU - Yang, Yulin

AU - Fan, Ruiqing

AU - Liu, Xinrong

AU - Hong, Hengwu

AU - Wang, Fuping

PY - 2010/7

Y1 - 2010/7

N2 - Using H3PO3 as a phosphorus source and oxalic acid as a reducing agent, the first three-dimensional open-framework gallium phosphate-phosphite formula as (C6N2H18)2(C6N2H17)Ga15(OH)8(PO4)2(HPO4)12(HPO3)6·2H2O (1), has been hydrothermally synthesized in the presence of N,N,N′,N′-tetramethylenediamine (TMEDA) as a structure-directing agent. Compound 1 crystallizes in trigonal system with space group P - 3, a = b = 19.046(3) Å, c = 8.3306(17) Å, γ = 120°, V = 2617.1(7) Å3, and Z = 1. Its 3-D network is based on alternated Ga-centered (GaO4 tetrahedra, GaO5 trigonal bipyramids, and GaO6 octahedra) and P-centered (PO43-, HPO42-, and HPO32-) units. Protonated organic amines and water molecules are located in the 12-membered ring channels.

AB - Using H3PO3 as a phosphorus source and oxalic acid as a reducing agent, the first three-dimensional open-framework gallium phosphate-phosphite formula as (C6N2H18)2(C6N2H17)Ga15(OH)8(PO4)2(HPO4)12(HPO3)6·2H2O (1), has been hydrothermally synthesized in the presence of N,N,N′,N′-tetramethylenediamine (TMEDA) as a structure-directing agent. Compound 1 crystallizes in trigonal system with space group P - 3, a = b = 19.046(3) Å, c = 8.3306(17) Å, γ = 120°, V = 2617.1(7) Å3, and Z = 1. Its 3-D network is based on alternated Ga-centered (GaO4 tetrahedra, GaO5 trigonal bipyramids, and GaO6 octahedra) and P-centered (PO43-, HPO42-, and HPO32-) units. Protonated organic amines and water molecules are located in the 12-membered ring channels.

KW - Crystal structure

KW - Gallium phosphate-phosphite

KW - Hydrothermal synthesis

UR - https://www.scopus.com/pages/publications/77953696897

U2 - 10.1016/j.solidstatesciences.2010.04.013

DO - 10.1016/j.solidstatesciences.2010.04.013

M3 - 文章

AN - SCOPUS:77953696897

SN - 1293-2558

VL - 12

SP - 1103

EP - 1106

JO - Solid State Sciences

JF - Solid State Sciences

IS - 7

ER -

Hydrothermal synthesis and characterization of a new organically templated three-dimensional open-framework gallium phosphate-phosphite (C₆N₂H₁₈)₂(C₆N₂H₁₇)Ga₁₅(OH)₈(PO₄)₂(HPO₄)₁₂(HPO₃)₆·2H₂O

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