Hydrothermal synthesis and characterization of a new layered gallophosphate JGP-L1 with a Ga/P ratio of non-unity

Yulin Yang; Yunling Liu; Zhongcheng Mu; Ling Ye; Tao Hu; Chao Chen; Wenqin Pang

doi:10.1016/j.jssc.2003.08.034

Hydrothermal synthesis and characterization of a new layered gallophosphate JGP-L1 with a Ga/P ratio of non-unity

Yulin Yang
, Yunling Liu
, Zhongcheng Mu
, Ling Ye
, Tao Hu
, Chao Chen
, Wenqin Pang^*

^*Corresponding author for this work

College of Chemistry

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

A new compound, Ga₆(OH)₄(HPO₄) ₂(PO₄)₅·C₈H ₂₈N₅·3H₂O (denoted JGP-L1), with a gallophosphate layer and a Ga/P ratio of 6/7 has been synthesized hydrothermally by using tetraethylenepentamine as template. It is characterized by powder X-ray diffraction (XRD), elemental analysis, inductively coupled plasma, and TGA analysis and structurally determined by single-crystal XRD analysis. JGP-L1 crystallizes in the orthorhombic, space group Pna2₁ (no. 33), with a=16.422(3), b=11.898(2), c=18.730(4)Å, V=3659.6(13)Å³ and Z=4. The structure of JGP-L1 is built up by alternating of Ga(OH)₂O₄ octahedra, Ga(OH)O₄ trigonal bipyramids and PO₄ (or HPO₄) tetrahedra to form inorganic sheets. It is noteworthy that JGP-L1 was synthesized with extremely low reactant concentration, where the reaction mixture exhibits a H ₂O:Ga₂O₃ molar ratio of 2220:1.

Original language	English
Pages (from-to)	696-700
Number of pages	5
Journal	Journal of Solid State Chemistry
Volume	177
Issue number	3
DOIs	https://doi.org/10.1016/j.jssc.2003.08.034
State	Published - Mar 2004
Externally published	Yes

Keywords

Characterization
Extremely low reactional concentration
Layered gallophosphate
Synthesis
Tetraethylenepentamine

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10.1016/j.jssc.2003.08.034

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@article{60bdfcb5552f4bcb97e89e0b95669659,

title = "Hydrothermal synthesis and characterization of a new layered gallophosphate JGP-L1 with a Ga/P ratio of non-unity",

abstract = "A new compound, Ga6(OH)4(HPO4) 2(PO4)5·C8H 28N5·3H2O (denoted JGP-L1), with a gallophosphate layer and a Ga/P ratio of 6/7 has been synthesized hydrothermally by using tetraethylenepentamine as template. It is characterized by powder X-ray diffraction (XRD), elemental analysis, inductively coupled plasma, and TGA analysis and structurally determined by single-crystal XRD analysis. JGP-L1 crystallizes in the orthorhombic, space group Pna21 (no. 33), with a=16.422(3), b=11.898(2), c=18.730(4){\AA}, V=3659.6(13){\AA}3 and Z=4. The structure of JGP-L1 is built up by alternating of Ga(OH)2O4 octahedra, Ga(OH)O4 trigonal bipyramids and PO4 (or HPO4) tetrahedra to form inorganic sheets. It is noteworthy that JGP-L1 was synthesized with extremely low reactant concentration, where the reaction mixture exhibits a H 2O:Ga2O3 molar ratio of 2220:1.",

keywords = "Characterization, Extremely low reactional concentration, Layered gallophosphate, Synthesis, Tetraethylenepentamine",

author = "Yulin Yang and Yunling Liu and Zhongcheng Mu and Ling Ye and Tao Hu and Chao Chen and Wenqin Pang",

year = "2004",

month = mar,

doi = "10.1016/j.jssc.2003.08.034",

language = "英语",

volume = "177",

pages = "696--700",

journal = "Journal of Solid State Chemistry",

issn = "0022-4596",

publisher = "Academic Press Inc.",

number = "3",

}

TY - JOUR

T1 - Hydrothermal synthesis and characterization of a new layered gallophosphate JGP-L1 with a Ga/P ratio of non-unity

AU - Yang, Yulin

AU - Liu, Yunling

AU - Mu, Zhongcheng

AU - Ye, Ling

AU - Hu, Tao

AU - Chen, Chao

AU - Pang, Wenqin

PY - 2004/3

Y1 - 2004/3

N2 - A new compound, Ga6(OH)4(HPO4) 2(PO4)5·C8H 28N5·3H2O (denoted JGP-L1), with a gallophosphate layer and a Ga/P ratio of 6/7 has been synthesized hydrothermally by using tetraethylenepentamine as template. It is characterized by powder X-ray diffraction (XRD), elemental analysis, inductively coupled plasma, and TGA analysis and structurally determined by single-crystal XRD analysis. JGP-L1 crystallizes in the orthorhombic, space group Pna21 (no. 33), with a=16.422(3), b=11.898(2), c=18.730(4)Å, V=3659.6(13)Å3 and Z=4. The structure of JGP-L1 is built up by alternating of Ga(OH)2O4 octahedra, Ga(OH)O4 trigonal bipyramids and PO4 (or HPO4) tetrahedra to form inorganic sheets. It is noteworthy that JGP-L1 was synthesized with extremely low reactant concentration, where the reaction mixture exhibits a H 2O:Ga2O3 molar ratio of 2220:1.

AB - A new compound, Ga6(OH)4(HPO4) 2(PO4)5·C8H 28N5·3H2O (denoted JGP-L1), with a gallophosphate layer and a Ga/P ratio of 6/7 has been synthesized hydrothermally by using tetraethylenepentamine as template. It is characterized by powder X-ray diffraction (XRD), elemental analysis, inductively coupled plasma, and TGA analysis and structurally determined by single-crystal XRD analysis. JGP-L1 crystallizes in the orthorhombic, space group Pna21 (no. 33), with a=16.422(3), b=11.898(2), c=18.730(4)Å, V=3659.6(13)Å3 and Z=4. The structure of JGP-L1 is built up by alternating of Ga(OH)2O4 octahedra, Ga(OH)O4 trigonal bipyramids and PO4 (or HPO4) tetrahedra to form inorganic sheets. It is noteworthy that JGP-L1 was synthesized with extremely low reactant concentration, where the reaction mixture exhibits a H 2O:Ga2O3 molar ratio of 2220:1.

KW - Characterization

KW - Extremely low reactional concentration

KW - Layered gallophosphate

KW - Synthesis

KW - Tetraethylenepentamine

UR - https://www.scopus.com/pages/publications/1642377997

U2 - 10.1016/j.jssc.2003.08.034

DO - 10.1016/j.jssc.2003.08.034

M3 - 文章

AN - SCOPUS:1642377997

SN - 0022-4596

VL - 177

SP - 696

EP - 700

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

IS - 3

ER -

Hydrothermal synthesis and characterization of a new layered gallophosphate JGP-L1 with a Ga/P ratio of non-unity

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Keywords

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